Citation: Zhi Hao Cui, Zi Hui Meng, Yan Qing Mi, Peng Wang, Qi Wang, Lin Man Zhao, Ke Jian Cui, Fang Yu, Zhi Bin Xu. Amination of electron deficient aryl chlorides promoted by nano sized Mg(OH)₂ under transition metals free condition[J]. Chinese Chemical Letters, ;2012, 23(2): 137-140. doi: 10.1016/j.cclet.2011.11.009 shu

Amination of electron deficient aryl chlorides promoted by nano sized Mg(OH)₂ under transition metals free condition

Department of Applied Chemistry and Pharmaceuticals, Beijing Institute of Technology, Beijing 100081, China

Received Date: 7 July 2011

This paper presents the amination reactions of electron deficient aryl chlorides promoted by Mg(OH)₂ without transition metals. Only using stoichiometric amount of nano sized Mg(OH)₂, good to moderate isolated yields could be achieved in N-methylpyrrolidone (NMP) after 24h at 150℃.
- Amination,
- Electron deficient aryl chloride,
- Cyclic secondary amines,
- Nano sized,
- Magnesium hydroxide
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