Citation: Ling Ling Bai, Yong Hao Zhou, Xiu Li Wang, Si Guo Yuan, Xian Li Wu. Facile synthesis of hypercrosslinked resin via photochlorination of p-xylene and succedent alkylation polymerization[J]. Chinese Chemical Letters, ;2011, 22(9): 1115-1118. doi: 10.1016/j.cclet.2011.03.011 shu

Facile synthesis of hypercrosslinked resin via photochlorination of p-xylene and succedent alkylation polymerization

School of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou 450001, China

Received Date: 10 December 2010

Fund Project: The authors are grateful for the support of the National Natural Science Foundation of China (Nos.20574063 and 21004055).

A combination of photochlorination of p-xylene and succedent Friedel-Crafts alkylation polymerization was firstly used in the preparation of the hypercrosslinked adsorptive resin. The data of GC-MS and GC showed that a series of chlorizates were produced when p-xylene was photochlorinated. Hypercrosslinked resins could be synthesized by copolymerization, self-polymerization of chlorizates or post crosslinking reaction. The chemical structure and micromorphology of the porous resins were characterized by BET, FT-IR, SEM and elementary analysis (EA). The results showed that the novel adsorptive resins possess high BET surface near to 1038 m²/g and large pore volumes range from 0.5 to 1.2 cm³/g.
- Hypercrosslinked resin,
- Synthesis,
- p-Xylene,
- Photochlorination,
- Polymerization
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