Citation: Yi Bo Huang, Wen Bin Yi, Chun Cai. An efficient, recoverable fluorous organocatalyst for accelerating the DABCO-promoted Morita-Baylis-Hillman reaction[J]. Chinese Chemical Letters, ;2011, 22(9): 1055-1058. doi: 10.1016/j.cclet.2011.03.010 shu

An efficient, recoverable fluorous organocatalyst for accelerating the DABCO-promoted Morita-Baylis-Hillman reaction

Yi Bo Huang ^a,b, ,
Wen Bin Yi ^a ,
Chun Cai ^a

a School of Chemical Engineering, Nanjing University of Science & Technology, Nanjing 210094, China;
b Department of Pharmacy, Changzhou Institute of Engineering Technology, Changzhou 213164, China

Received Date: 7 December 2010

Fund Project: We thank the project of "Excellence Initiative" and "Zijin Star" in NJUST, "Doctoral Fund of Ministry of Education of China" (No.200802881024), and "National Natural Science Foundation of China" (No.20902047) for financial support.

A convenient method for Morita-Baylis-Hillman reaction of arylaldehydes with methyl acrylate has been developed by using fluorous-tag organocatalyst l-[4- (perfluorooctyl)phenyll-3-phenylthiourea and DABCO at room temperature. The fluorous organocatalyst could be recovered from the reaction mixture by fluorous solid-phase extraction (F-SPE) with excellent purity for direct reuse.
- Organocatalyst,
- Morita-Baylis-Hillman reaction,
- Fluorous solid phase extraction (F-SPE)
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