Citation: Maryam Gorjizadeh, Soheil Sayyahi. A novel and efficient synthesis of alkyl thiocyanates from alkyl halides in water using phase transfer catalysts[J]. Chinese Chemical Letters, ;2011, 22(6): 659-662. doi: 10.1016/j.cclet.2010.11.025 shu

A novel and efficient synthesis of alkyl thiocyanates from alkyl halides in water using phase transfer catalysts

Maryam Gorjizadeh ^a, ,
Soheil Sayyahi ^b

a Department of Chemistry, Islamic Azad University, Shushtar Branch, 147-64516 Shushtar, Iran;
b Department of Chemistry, Islamic Azad University, Mahshahr Branch, Iran

Received Date: 21 September 2010

1,4-Bis(triphenylphosphonium)-2-butene dichloride(BTPBDC)and 1,4-bis(triphenyl phosphonium)-2-butene dithiocyanate(BTPBDT)were prepared and used as phase-transfer catalysts.Alkyl halides were converted efficiently to the corresponding alkyl thiocyanates under mild reaction conditions in water.No evidence for the formation of isothiocy anates as by-product of the reaction was observed.
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