Citation: Mei Hong, Chun Cai, Wen Bin Yi. Hafnium (IV) bis(perfluorooctanesulfonyl)imide complex catalyzed direct amidomethylation for the synthesis of l-(arylamido)-methyl-2-naphthols in fluorous medium[J]. Chinese Chemical Letters, ;2011, 22(3): 322-325. doi: 10.1016/j.cclet.2010.10.046 shu

Hafnium (IV) bis(perfluorooctanesulfonyl)imide complex catalyzed direct amidomethylation for the synthesis of l-(arylamido)-methyl-2-naphthols in fluorous medium

School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China

Received Date: 1 July 2010

Fund Project: We thank the project of "Excellence Initiative" and "Zijin Star" in NJUST for financial support.

Hafnium (IV) bis(perfluorooctanesulfonyl) imide complex is found to be an efficient catalyst for the multicomponent condensation of β-naphthol, aromatic aldehydes and urea or amides in perfluorodecalin to afford the corresponding substituted amidomethyl naphthols in good yields. The remarkable features of this new procedure are high yields, shorter reaction times, reusability of catalyst and simple work-up procedures.
- Hafnium(TV)bis(perfluorooctanesulfonyl)imide complex,
- Perfluorodecalin,
- Substituted amidomethyl naphthol,
- Multicomponet reaction
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