Citation: Hui Jin, Zhen Dong Huang, Chun Xiang Kuang, Xiao Kun Wang. Iron-catalyzed bromination of aryl azides by N-bromosuccinimide:Efficient method for the synthesis of brominated aryl azides[J]. Chinese Chemical Letters, ;2011, 22(3): 310-313. doi: 10.1016/j.cclet.2010.10.024 shu

Iron-catalyzed bromination of aryl azides by N-bromosuccinimide:Efficient method for the synthesis of brominated aryl azides

a Department of Chemistry, Tongji University, Siping Road 1239, Shanghai 200092, China;
b Zhejiang Citrus Research Institute, Taizhou 318020, China

Received Date: 29 June 2010

Fund Project: The work was supported by National Natural Science Foundation of China (No. 30873153), the Key Projects of Shanghai in Biomedical (No. 08431902700) and the Scientific Research Foundation of State Education Ministry for the Returned Overseas Chinese Scholars. We would like to thank the Center for Instrumental Analysis, Tongji University, China.

An efficient and mild protocol for bromination of aryl azides with N-bromosuccinimide (NBS) under FeCl₃ catalysis in 1,2-dichloroethane was developed. It is proved to be an efficient method for obtaining brominated aryl azides.
- Iron-catalyzed,
- Aryl azides,
- N-Bromosuccinimide,
- Bromination
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