Citation: Zhi Yong Guo, Pan Pan Gai, Jing Duan, Hui Na Zhang, Sui Wang. Tetracycline selective electrode based on molecularly imprinted polymer particles[J]. Chinese Chemical Letters, ;2010, 21(10): 1235-1238. doi: 10.1016/j.cclet.2010.04.007 shu

Tetracycline selective electrode based on molecularly imprinted polymer particles

Faculty of Materials Science and Chemical Engineering, The State Key Laboratory Base of Novel Functional Materials and Preparation Science, Ningbo University, Ningbo 315211, China

Received Date: 27 January 2010

Fund Project: Financial supports from Ningbo Science and Technology Bureau (No.2007C10061),Department of Education of Zhejiang Province (No.20070963) and Science and Technology Department of Zhejiang Province of China (No.2008R40G2070056) are gratefully acknowledged.This work was also sponsored by K.C.Wong Magna Fund in Ningbo University.

Tetracycline selective electrode using molecularly imprinted polymer particles as quasi-ionophore was constructed the first time, and its performance was carefully characterized. Due to the specific recognition of tetracycline by the particles, the selectivity coefficients for routine interferences were less than 10^-4. Benefited from the absence of tetracycline in the sensitive membrane and the optimized composition of the inner filling solution, the limit of detection of the electrode was reduced to about 2.5×10^-8 mol/L. It exhibited a good electrode slope 57.6 mV/decade near the theoretical Nernstian one, with a wide linear working range from 6.0×10^-8 to 1.0×10^-3 mol/L. The fabricated electrode should be used in pH 2-4, response time of which was less than 200 s when the concentration of tetracycline was higher than 1.0×10^-6 mol/L and no more than 30 min at the concentration of 1.0×10^-8 mol/L.
- Ion selective electrode,
- Molecular imprinting polymer,
- Quasi-ionophore,
- Tetracycline
1. [1]
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2. [2]
  Dan-Ying Xing , Xiao-Dan Zhao , Chuan-Shu He , Bo Lai . Kinetic study and DFT calculation on the tetracycline abatement by peracetic acid. Chinese Chemical Letters, 2024, 35(9): 109436-. doi: 10.1016/j.cclet.2023.109436
3. [3]
  Xin Li , Wanting Fu , Ruiqing Guan , Yue Yuan , Qinmei Zhong , Gang Yao , Sheng-Tao Yang , Liandong Jing , Song Bai . Nucleophiles promotes the decomposition of electrophilic functional groups of tetracycline in ZVI/H₂O₂ system: Efficiency and mechanism. Chinese Chemical Letters, 2024, 35(10): 109625-. doi: 10.1016/j.cclet.2024.109625
4. [4]
  Fengrui Yang , Debing Wang , Xinying Zhang , Jie Zhang , Zhichao Wu , Qiaoying Wang . Synergistic effects of peroxydisulfate on UV/O₃ process for tetracycline degradation: Mechanism and pathways. Chinese Chemical Letters, 2024, 35(10): 109599-. doi: 10.1016/j.cclet.2024.109599
5. [5]
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6. [6]
  Qinghong Pan , Huafang Zhang , Qiaoling Liu , Donghong Huang , Da-Peng Yang , Tianjia Jiang , Shuyang Sun , Xiangrong Chen . A self-powered cathodic molecular imprinting ultrasensitive photoelectrochemical tetracycline sensor via ZnO/C photoanode signal amplification. Chinese Chemical Letters, 2025, 36(1): 110169-. doi: 10.1016/j.cclet.2024.110169
7. [7]
  Yuxia Luo , Xiaoyu Xie , Fangfang Chen . 药物递送魔法师——分子印迹聚合物. University Chemistry, 2025, 40(8): 202-210. doi: 10.12461/PKU.DXHX202409129
8. [8]
  Junjie Zhang , Yue Wang , Qiuhan Wu , Ruquan Shen , Han Liu , Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084
9. [9]
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10. [10]
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11. [11]
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12. [12]
  Futao Yi , Ying Liu , Yao Chen , Jiahao Zhu , Quanguo He , Chun Yang , Dongge Ma , Jun Liu . Dual S-Scheme g-C₃N₄/Ag₃PO₄/g-C₃N₅ photocatalysts for removal of tetracycline pollutants through enhanced molecular oxygen activation. Chinese Chemical Letters, 2025, 36(8): 110544-. doi: 10.1016/j.cclet.2024.110544
13. [13]
  Cheng-Da Zhao , Huan Yao , Shi-Yao Li , Fangfang Du , Li-Li Wang , Liu-Pan Yang . Amide naphthotubes: Biomimetic macrocycles for selective molecular recognition. Chinese Chemical Letters, 2024, 35(4): 108879-. doi: 10.1016/j.cclet.2023.108879
14. [14]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
15. [15]
  Jian Peng , Yue Jiang , Shuangyu Wu , Yanran Cheng , Jingyu Liang , Yixin Wang , Zhuo Li , Sijie Lin . A nonradical oxidation process initiated by Ti-peroxo complex showed high specificity toward the degradation of tetracycline antibiotics. Chinese Chemical Letters, 2024, 35(5): 108903-. doi: 10.1016/j.cclet.2023.108903
16. [16]
  Min ZHU , Yuxin WANG , Xiao LI , Yaxu XU , Junwen ZHU , Zihao WANG , Yu ZHU , Xiaochen HUANG , Dan XU , Monsur Showkot Hossain Abul . Construction of AgVO₃/ZIF-8 composites for enhanced degradation of tetracycline. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 994-1006. doi: 10.11862/CJIC.20240392
17. [17]
  Liangbo Zhang , Jun Cheng , Yahui Shi , Kunjie Hou , Qi An , Jingyi Li , Baohui Cui , Fei Chen . Efficient removal of tetracycline hydrochloride by ZnO/HNTs composites under visible light: Kinetics, degradation pathways and mechanism. Chinese Chemical Letters, 2025, 36(7): 110400-. doi: 10.1016/j.cclet.2024.110400
18. [18]
  Qi HUANG , Youyi WANG , Zhujian MAO , Zhonghui YE , Weihan CHEN , Jui-yeh RAU , Jian HUANG . Enhanced photocatalytic tetracycline degradation via 2D CdS/Ti₃AlC₂ MAX heterostructure. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2385-2398. doi: 10.11862/CJIC.20250159
19. [19]
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20. [20]
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