Citation: Zhi Yong Guo, Pan Pan Gai, Jing Duan, Hui Na Zhang, Sui Wang. Tetracycline selective electrode based on molecularly imprinted polymer particles[J]. Chinese Chemical Letters, ;2010, 21(10): 1235-1238. doi: 10.1016/j.cclet.2010.04.007 shu

Tetracycline selective electrode based on molecularly imprinted polymer particles

Faculty of Materials Science and Chemical Engineering, The State Key Laboratory Base of Novel Functional Materials and Preparation Science, Ningbo University, Ningbo 315211, China

Received Date: 27 January 2010

Fund Project: Financial supports from Ningbo Science and Technology Bureau (No.2007C10061),Department of Education of Zhejiang Province (No.20070963) and Science and Technology Department of Zhejiang Province of China (No.2008R40G2070056) are gratefully acknowledged.This work was also sponsored by K.C.Wong Magna Fund in Ningbo University.

Tetracycline selective electrode using molecularly imprinted polymer particles as quasi-ionophore was constructed the first time, and its performance was carefully characterized. Due to the specific recognition of tetracycline by the particles, the selectivity coefficients for routine interferences were less than 10^-4. Benefited from the absence of tetracycline in the sensitive membrane and the optimized composition of the inner filling solution, the limit of detection of the electrode was reduced to about 2.5×10^-8 mol/L. It exhibited a good electrode slope 57.6 mV/decade near the theoretical Nernstian one, with a wide linear working range from 6.0×10^-8 to 1.0×10^-3 mol/L. The fabricated electrode should be used in pH 2-4, response time of which was less than 200 s when the concentration of tetracycline was higher than 1.0×10^-6 mol/L and no more than 30 min at the concentration of 1.0×10^-8 mol/L.
- Ion selective electrode,
- Molecular imprinting polymer,
- Quasi-ionophore,
- Tetracycline
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