Citation: Hong Sheng Li, Yi Qun Li. Potassium iodide catalyzed reductive dehalogenation of α-halo-ketones using Hantzsch ester diethyl 1,4-dihydro-2,6-dimethylpyridine-3,5-dicarboxylate as reductant[J]. Chinese Chemical Letters, ;2010, 21(8): 931-934. doi: 10.1016/j.cclet.2010.03.027 shu

Potassium iodide catalyzed reductive dehalogenation of α-halo-ketones using Hantzsch ester diethyl 1,4-dihydro-2,6-dimethylpyridine-3,5-dicarboxylate as reductant

Hong Sheng Li ,
Yi Qun Li

Department of Chemistry, Jinan University, Guangzhou 510632, China

Received Date: 18 December 2009

Fund Project: We are grateful to the Guangdong Natural Science Foundation (No. 8151063201000016) and the National Natural Science Foundation of China (No. 20672046) for financial support.

In the presence of diethyl 1,4-dihydro-2,6-dimethylpyridine-3,5-dicarboxylate (DHP) and a catalytic amount of potassium iodide,several α-halo ketones were easily reduced to the corresponding ketones in acetone media.The procedure presented here showed several merits such as short reaction time,practical experimental and isolated procedure,and excellent yields of products.
- Dehalogenation,
- α-Halo ketones,
- Hantzsch ester,
- 1,4-Dihydro-2,6-dimethylpyridine-3,5-dicarboxylate,
- Potassium iodide
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