Citation: Qiang Feng, Chao Zhang, Qiang Tang, Mei Ming Luo. Synthesis of 1,1'-binaphthyl-2,2'-diamine from 2-naphthol under atmospheric pressure[J]. Chinese Chemical Letters, ;2009, 20(10): 1150-1152. doi: 10.1016/j.cclet.2009.05.033 shu

Synthesis of 1,1'-binaphthyl-2,2'-diamine from 2-naphthol under atmospheric pressure

Key Laboratory of Green Chemistry & Technology of Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, China

Received Date: 12 February 2009

Fund Project: We are grateful to National Natural Science Foundation of China (No.20372049) and Application Basic Research Funding of Sichuan.We also thank Analytical & Testing Center of Sichuan University for support in NMR and MS analyses.

A practical protocol to obtain 1,1'-binaphthyl-2,2'-diamine was developed from 2-naphthol and 2-naphthylhydrazine under mild conditions:solvent-free, 125-130℃, atmospheric pressure.The convenient procedure makes the process amenable for large-scale synthesis of the versatile compound.
- 1,1'-Binaphthyl-2,2'-diamine,
- 2-Naphthol,
- 2-Naphthylhydrazine,
- Synthesis
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