Citation: Cong Wen Ding, Ming Jie Zhang Ning Ma. Clean synthesis of calix[4]crown-5-sulfonyl cyclothiourea derivatives at room temperature in aqueous solution[J]. Chinese Chemical Letters, ;2009, 20(10): 1166-1168. doi: 10.1016/j.cclet.2009.04.031 shu

Clean synthesis of calix[4]crown-5-sulfonyl cyclothiourea derivatives at room temperature in aqueous solution

Chemistry Department of Science School, Tianjin University, Tianjin 300072, China

Received Date: 23 February 2009

Fund Project: Financial support from the National Natural Science Foundation of China (No.20802049) and Program for New Century Excellent Talents in University of Tianjin City were greatly acknowledged.

Calix[4]-crown-5-sulfonyl cyclothiourea derivatives 6 and 7 were synthesized from calix[4]-crown-5-monosulfonylethylenediamine derivatives 4 and 5 and carbon disulfide through nucleophilic addition and subsequent cyclization of intramolecule at room temperature in aqueous solution.The advantages of the novel protocol are the mild reaction condition, free organic solvent, simple final treatment, easy isolation of products and excellent yields.
- Room temperature,
- Aqueous solution,
- Calix[4]-crown-5-sulfonyl cyclothiourea,
- Clean synthesis
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