Citation: Shi Qiang Yan, Xue Min Wu, Xiao Mei Liang, Jian Jun Zhang, Dao Quan Wang. Synthesis of di-and tetrasaccharide containing 6-deoxytalose from the O-antigenic polysaccharide of B. pseudomallei strain 304b[J]. Chinese Chemical Letters, ;2009, 20(5): 582-585. doi: 10.1016/j.cclet.2009.01.007 shu

Synthesis of di-and tetrasaccharide containing 6-deoxytalose from the O-antigenic polysaccharide of B. pseudomallei strain 304b

Key Lab of Pesticide Chemistry and Application Technology, Department of Applied Chemistry, China Agricultural University, Beijing 100193, China

Received Date: 10 September 2008

Fund Project: This work was supported by the Doctoral Program Foundation of Institutions of Higher Education of China (No.20070019072).

Synthesis of the disaccharide β-D-Glup-(1→3)-6-deoxy-α-L-Talp II, and its dimer III from the O-antigenic polysaccharide of Burkholderia pseudomallei strain 304b, were achieved through assembly of suitably synthesized building blocks, 4-methoxylphenyl 6-deoxy-2,4-di-O-benzoyl-α-L-talopyranoside (7), 3-O-allyl-2,4,6-tri-O-benzoyl-α,β-D-glucopyranosyl trichloroacetimidate (8) and 2,3,4,6-tetra-O-benzoyl-α,β-D-glucopyranosyl trichloroacetimidate (11). The total yield of III from 4-methoxylphenyl 2,3-O-isopropylidene-α-L-rhamnopyranoside (1) was 18%.
- Oligosaccharide,
- Glucose,
- Rhamnose,
- 6-Deoxytalose
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