Citation: Shi Xu Yi, Jian Men, Xiao Yan Ma, Yan Jiang, Guo Wei Gao. A novel efficient synthetic method for 2,2',3,3'-biphenyltetracarboxylic dianhydride[J]. Chinese Chemical Letters, ;2009, 20(3): 306-309. doi: 10.1016/j.cclet.2008.11.008 shu

A novel efficient synthetic method for 2,2',3,3'-biphenyltetracarboxylic dianhydride

Shi Xu Yi ^a, ,
Jian Men ^a ,
Xiao Yan Ma ^b ,
Yan Jiang ^a ,
Guo Wei Gao ^a

a College of Chemistry, Sichuan University, Chengdu 610064, China;
b College of Material and Chemical Engineering, Chengdu University of Technology, Chengdu 610059, China

Received Date: 8 September 2008

Fund Project: The authors are grateful to the National Undergraduates'Innovative Experiment Project of China and the Undergraduates'Innovative Experiment Project of Sichuan University for financial support.

A novel approach to the synthesis of 2,2',3,3'-biphenyltetracarboxylic dianhydride is described. The target compound was prepared by a nickel-catalyzed coupling reaction of dimethy 3-chlorophthalate (3-DMCP) for 4 h at 70-80℃, followed by subsequent hydrolysis of tetra-ester in acid solution and dehydration of tetra-acid, with overall yield of 68%. The structures of the products were characterized by IR, ¹H NMR and ¹³C NMR respectively.
- 2,2',3,3'-Biphenyltetracarboxylic dianhydride,
- Nickel-catalyzed,
- Coupling reaction
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