Citation: Xi Gao Jian, Chun Yan, Hua Min Zhang, Shou Hai Zhang, Cheng Liu, Ping Zhao. Synthesis and characterization of quaternized poly (phthalazinone ether sulfone ketone) for anion-exchange membrane[J]. Chinese Chemical Letters, ;2007, 18(10): 1269-1272. doi: 10.1016/j.cclet.2007.08.022 shu

Synthesis and characterization of quaternized poly (phthalazinone ether sulfone ketone) for anion-exchange membrane

a Department of Polymer Materials, Dalian University of Technology, Dalian 116012, China;
b PEMFC Key Materials & Technology Laboratory, Dalian Institute of Chemical Physics(DICP), Chinese Academy of Sciences, Dalian 116023, China

Fund Project: This work was partly financed by the Major State Basic Research Development Program of China (No.2003 CB615700) and the National Natural Science Foundation of China (No.20604005).

Chloromethylated poly(phthalazinone ether sulfone ketone) (CMPPESK) was prepared from poly(phthalazinone ether sulfone ketone) (PPESK) using chloromethyl octyl ethers (CMOE) with lower toxicity as chloromethylated regent. CMPPESK was soluble in N-methyl-2-pyrrolidone (NMP), N, N-dimethylacetamide (DMAc) and chloroform. Quatemized poly(phthalazinone ether sulfone ketone) (QAPPESK) was prepared from CMPPESK by quaternization. QAPPESK had excellent solvent resistance, which was only partly soluble in sulfuric acid (98%) and swollen in N, N-dimethylformamide (DMF). The vanadium redox flow battery (V-RFB) using QAPPESK anion-exchange membrane had better performance with 88.3% of overall energy efficiency.
- Chloromethylation,
- Quaternization,
- Poly (phthalazinone ether sulfone ketone),
- Anion-exchange membrane,
- Vanadium redox flow battery
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