Citation: Xiao Tong Li, Sheng Hua Li, Si Ping Pang, Yong Zhong Yu, Yun Jun Luo. A new efficient route for the synthesis of 4,4',6,6'-tetra (azido) azo-1,3,5-triazine[J]. Chinese Chemical Letters, ;2007, 18(9): 1037-1039. doi: 10.1016/j.cclet.2007.06.028 shu

A new efficient route for the synthesis of 4,4',6,6'-tetra (azido) azo-1,3,5-triazine

a School of Materials Science & Engineering, Beijing Institute of Technology, Beijing 100081, China;
b School of Life Science & Technology, Beijing Institute of Technology, Beijing 100081, China

Received Date: 16 April 2007

Fund Project: We gratefully acknowledge the support of this work by Joint Foundation of National Natural Science Foundation of China and China Academy of Engineering Physics (NSAF)(No.10576002).

A new method for the synthesis of 4, 4', 6, 6'-tetra (azido) azo-1, 3, 5-triazine (TAAT) is described. The key intermediate 4, 4', 6, 6'-tetra (azido) hydrazo-1, 3, 5-triazine (THAT) was synthesized by nucleophilic substitution in the case of sodium azide as nucleophile. N-Bromosuccinide (NBS) was used as oxidant to oxidize THAT by a tractable operation under mild reaction condition. The target compound TAAT was obtained with a facile process and high overall yield of 81%. The structures of TAAT and its intermediates were identified by spectroscopic methods.
- High-nitrogen compounds,
- Azide,
- Triazine,
- Synthesis
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