Citation:
Ke Bing Wang, Gong Ying Wang. Condensation reaction of formaldehyde and methyl formate catalyzed by a composite catalyst system[J]. Chinese Chemical Letters,
;2007, 18(7): 811-813.
doi:
10.1016/j.cclet.2007.05.004
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The condensation reaction of formaldehyde and methyl formate to form methyl glycolate and methyl methoxy acetate catalyzed by p-toluenesulfonic acid and different Lewis acid compounds has been investigated. The composite catalytic system consisting of p-toluenesulfonic acid and NiX2(X=Cl, Br, I), especially NiI2, exhibited a high catalytic performance for the condensation reaction, the total yield of MG and MMAc was up to 72.37%.
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