Citation: Ke Zeng, Ke Zhou, Wen Rui Tang, Yan Tang, Hong Fei Zhou, Tao Liu, Yi Peng Wang, Hai Bing Zhou, Gang Yang. Synthesis and curing of a novel amino-containing phthalonitrile derivative[J]. Chinese Chemical Letters, ;2007, 18(5): 523-526. doi: 10.1016/j.cclet.2007.03.035 shu

Synthesis and curing of a novel amino-containing phthalonitrile derivative

State Key Laboratory of Polymer Materials Engineering, College of Polymer Science and Engineering, Sichuan University, Chengdu 610065, China

Received Date: 14 December 2006

A novel phthalonitrile derivative containing an amino group, 3, 5-bis (3, 4-dicyanophenoxy) aniline (CPA), was synthesized via a nucleophilic displacement of 4-nitrophthalonitrile and 5-aminoresorcinol hydrochloride. The structure of CPA was confirmed by Fourier transform infrared spectra (FT-IR) and nuclear magnetic resonance (¹H NMR). Thermal analysis performed on CPA revealed that the novel phthalonitrile derivative showed a self-promotion curing behavior and the resulting polymer exhibited outstanding heat-resistance.
- Phthalonitrile derivative,
- Amino group,
- Self-promotion curing behavior
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