Citation: Qiu Hua Xu, Ping Ping Wang, Ming Zhong Cai. A facile approach to asymmetrical biaryls via coupling reaction of aryl halides with sodium tetraphenylborate catalyzed by MCM-41-supported sulfur palladium(0) complex[J]. Chinese Chemical Letters, ;2007, 18(4): 387-389. doi: 10.1016/j.cclet.2007.01.046 shu

A facile approach to asymmetrical biaryls via coupling reaction of aryl halides with sodium tetraphenylborate catalyzed by MCM-41-supported sulfur palladium(0) complex

a Department of Chemistry, Jiangxi Normal University, 330027 Nanchang, China;
b Department of Chemistry, Jiujiang University, 332000 Jiujiang, China

Received Date: 25 October 2006

Fund Project: We thank the National Natural Science Foundation of China (Project 20462002) and Natural Science Foundation of Jiangxi Province (Project 0420015) for financial support.

Various functionalized asymmetrical biaryls can be synthesized in high to excellent yields via coupling reaction of aryl iodides or bromides with NaBPh₄ catalyzed by MCM-41-supported sulfur palladium(O) complex. This palladium complex can be easily recovered and reused many times without loss of activity.
- Asymmetrical biaryl,
- NaBPh₄,
- Aryl halide,
- Palladium,
- Coupling reaction
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14. [14]
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