Citation: Lin Bo Gong, Shu Ling Gong, Qin Zheng, Xiong Li, Yuan Yin Chen. High extraction ability of 1,3-dialkynyl calixarene towards mercury(Ⅱ) ion[J]. Chinese Chemical Letters, ;2007, 18(4): 435-436. doi: 10.1016/j.cclet.2007.01.015 shu

High extraction ability of 1,3-dialkynyl calixarene towards mercury(Ⅱ) ion

College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China

Received Date: 31 October 2006

The reaction of 1,3-dipropyn-2-yloxycalix[4]arene with mercury(Ⅱ) acetate could give mercury-containing alkynyl calixarene polymer. The extraction behavior of 1,3-dipropyn-2-yl-oxycalix[4]arene towards mercury(Ⅱ) ion was examined. When the mole ratio of Hg²⁺/calixarene was 1:1, the extractive percent can reach to 99.1%, and the extraction capacity was up to 431 mg/g. It could also decrease the Hg²⁺ concentration from 5 to 0.85 mg/L, which was only 17% of the national standard of effluent and satisfied the national standard of drinking water. The extraction process included chemical reaction.
- Calixarene,
- Extraction,
- Mercury(Ⅱ) ion,
- Alkynyl calixarene
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