Citation: Jun Jie Gao, Hui Quan Li, Yi Zhang. Synthesis of methyl N-phenyl carbamate from dimethyl carbonate and 1,3-diphenyl urea under mild conditions[J]. Chinese Chemical Letters, ;2007, 18(2): 149-151. doi: 10.1016/j.cclet.2006.12.014 shu

Synthesis of methyl N-phenyl carbamate from dimethyl carbonate and 1,3-diphenyl urea under mild conditions

Jun Jie Gao ^a,b, ,
Hui Quan Li ^a ,
Yi Zhang ^a

a Institute of Process Engineering, Chinese Academy of Sciences, P.O. Box 353, Beijing 100080, China;
b Graduate University of Chinese Academy of Sciences, Beijing 100049, China

Received Date: 14 September 2006

Fund Project: This work was supported by the National Natural Science Foundation of China (no. 20436050).

Synthesis of methyl N-phenyl carbamate from dimethyl carbonate and 1,3-diphenyl urea was investigated under atmospheric pressure. The results showed that homogenous catalyst sodium methoxide had the excellent activity to efficiently catalyze the synthesis of methyl N-phenyl carbamate under atmospheric pressure.
- Methyl N-phenyl carbamate,
- Dimethyl carbonate,
- 1,3-diphenyl urea,
- Atmospheric pressure
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