Citation: Ying Na Cui, Jing Mei Yin, Da Bin Gao, Ying Ping Jia, Guang Yun Zhou, Shen Min Li. Photopromoted methoxycarbonylation of olefin with methyl formate by Co(OAc)₂[J]. Chinese Chemical Letters, ;2007, 18(1): 17-20. doi: 10.1016/j.cclet.2006.11.021 shu

Photopromoted methoxycarbonylation of olefin with methyl formate by Co(OAc)₂

Liaoning Key Laboratory of Bio-Organic Chemistry, Dalian University, Dalian 116622, China

Received Date: 15 May 2006

Fund Project: The authors are grateful to the National Natural Science Foundations of China (No. 20372012) and the Natural Science Foundations of Liaoning (No. 20032099) for the generous financial support.

The photopromoted methoxycarbonylation of olefin with methyl formate catalyzed by Co(OAc)₂ at ambient conditions has been carried out. The results indicated that the reaction activity increased with the increasing temperature. Methyl formate decomposed into CO and CH₃OH firstly under irradiation, and then the methoxycarbonylation of olefin proceeded under catalysis of Co(OAc)₂.The mechanism of methyl formate participating in the methoxycarbonylation is verified by the IR analysis and the labeling experiments of CD₃OD and CH₃¹⁸OH.
- Methoxycarbonylation,
- Methyl formate,
- Olefin,
- Photopromoted,
- Cobalt acetate
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