Citation: Deyun Ma, Fenglan Liang, Qingquan Xue, Yanping Liu, Chunqiang Zhuang, Shijie Li. Interfacial engineering of Cd_0.5Zn_0.5S/BiOBr S-scheme heterojunction with oxygen vacancies for effective photocatalytic antibiotic removal[J]. Acta Physico-Chimica Sinica, ;2025, 41(12): 100190. doi: 10.1016/j.actphy.2025.100190 shu

Interfacial engineering of Cd_0.5Zn_0.5S/BiOBr S-scheme heterojunction with oxygen vacancies for effective photocatalytic antibiotic removal

Deyun Ma ^{1, †} ,
Fenglan Liang ^{1, †} ,
Qingquan Xue ^2,, ,
Yanping Liu ³ ,
Chunqiang Zhuang ^4,, ,
Shijie Li ^{3, 5,,}

1.
School of Food and Pharmaceutical Engineering, School of Life Sciences, Zhaoqing University, Zhaoqing 526061, Guangdong Province, China
2.
Key Laboratory of Pollution Exposure and Health Intervention of Zhejiang Province, Interdisciplinary Research Academy (IRA), Zhejiang Shuren University, Hangzhou 310015, Zhejiang Provincne, China
3.
Zhejiang Key Laboratory of Pollution Control for Port-Petrochemical Industry, National Engineering Research Center for Marine Aquaculture, Zhejiang Ocean University, Zhoushan 316022, Zhejiang Province, China
4.
Institute of Microstructure and Property of Advanced Materials, Beijing University of Technology, Beijing 100124, China
5.
Henan Engineering Research Center of Resource & Energy Recovery from Waste, School of Energy Science and Technology, Henan University, Zhengzhou 450046, Henan Province, China

Corresponding author: Qingquan Xue, qingquanxue@zjsru.edu.cn Chunqiang Zhuang, chunqiang.zhuang@bjut.edu.cn Shijie Li, lishijie@zjou.edu.cn
Received Date: 10 August 2025
Revised Date: 19 September 2025
Accepted Date: 19 September 2025

Fund Project: the Natural Science Foundation of Zhejiang Province LY20E080014the National Natural Science Foundation of China 51708504the Open Cooperation Foundation of the Department of Chemical Science of Henan University DCSHENU2413

The construction of S-scheme heterojunction photocatalysts has emerged as a promising strategy to address the urgent need for efficient antibiotic wastewater remediation. However, persistent challenges in achieving interfacial intimacy and precise charge transfer regulation between semiconductors have hindered their practical implementation. In this work, we engineered a hierarchical Cd_0.5Zn_0.5S/BiOBr S-scheme heterojunction via a controlled solvothermal synthesis, where BiOBr microspheres serve as the core, and Cd_0.5Zn_0.5S nanoparticles form a conformal shell. This architecture ensures maximal interfacial contact and directional charge dynamics, critical for optimizing photocatalytic efficiency. The optimized heterojunction exhibits superior catalytic performance, achieving tetracycline (TC) degradation rate constants 3.3- and 1.6-fold greater than pristine BiOBr and Cd_0.5Zn_0.5S, respectively. This enhancement stems from the synergistic interplay of efficient charge separation and preserved redox capacities inherent to the S-scheme mechanism. Furthermore, the TC degradation process and mechanism were elucidated. This study provides a new perspective on developing defective S-scheme heterojunctions for antibiotic wastewater purification with high performance.
- Internal electric field,
- Cd_0.5Zn_0.5S/BiOBr,
- S-scheme heterojunction,
- Oxygen vacancies,
- Antibiotic degradation,
- Photocatalysis,
- Toxicity analysis
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Interfacial engineering of Cd0.5Zn0.5S/BiOBr S-scheme heterojunction with oxygen vacancies for effective photocatalytic antibiotic removal

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通讯作者: 陈斌, bchen63@163.com

Interfacial engineering of Cd_0.5Zn_0.5S/BiOBr S-scheme heterojunction with oxygen vacancies for effective photocatalytic antibiotic removal