Citation: Chengxin Chen, Hongfei Shi, Xiaoyan Cai, Liang Mao, Zhe Chen. Enhanced bifunctional photocatalytic performances for H₂ evolution and HCHO elimination with an S-scheme CoWO₄/CdIn₂S₄ heterojunction[J]. Acta Physico-Chimica Sinica, ;2025, 41(12): 100155. doi: 10.1016/j.actphy.2025.100155 shu

Enhanced bifunctional photocatalytic performances for H₂ evolution and HCHO elimination with an S-scheme CoWO₄/CdIn₂S₄ heterojunction

Chengxin Chen ¹ ,
Hongfei Shi ^1,, ,
Xiaoyan Cai ² ,
Liang Mao ^{2, 3,,} ,
Zhe Chen ^1,,

1.
Institute of Petrochemical Technology, Jilin University of Chemical Technology, Jilin, 132022, Jilin Province, China
2.
School of Materials Science and Physics, China University of Mining and Technology, Xuzhou, 221116, Jiangsu Province, China
3.
Caparol Hangzhou Ltd., Hangzhou, 311200, Zhejiang Province, China

Corresponding author: Hongfei Shi, shihf813@nenu.edu.cn Liang Mao, maoliang@cumt.edu.cn Zhe Chen, chenz@jlict.edu.cn
Received Date: 11 July 2025
Revised Date: 6 August 2025
Accepted Date: 9 August 2025

Fund Project: the National Natural Science Foundation of China 22309061the National Natural Science Foundation of China 22209203the National Natural Science Foundation of China 22309204the National Natural Science Foundation of China 22278172the Education Department project of Jilin Province JJKH20240305KJthe Science and Technology Department project of Jilin Province YDZJ202401372ZYTS

Designing and establishing dual-functional S-scheme heterojunction photocatalysts with efficient separation of photoproduced carriers and intense oxidation/reduction capabilities holds immense practical value for their photocatalytic application in energy conversion and environmental purification. Herein, a novel series of x% CoWO₄/CdIn₂S₄ (x% reflects the weight ratio of CWO to CIS; x = 10, 20, 30, 40 and 50) composites have been systematically designed and synthesized via electrospinning technique and hydrothermal methods. Their photocatalytic properties were assessed through HCHO removal and H₂ generation under visible light. As anticipated, the optimized 30% CWO/CIS heterojunction presented an outstanding H₂ generation performance of 865.14 μmol g⁻¹ h⁻¹ with AQE = 3.6% at λ = 420 nm, and achieved a 69% removal percentage for HCHO within 1 h. Meanwhile, the pathway of HCHO degradation was presented based on in situ diffuse reflectance infrared Fourier transform spectroscopy (in situ DRIFTS) technique. The great catalytic performance was primarily ascribed to the enhancement in the visible-light absorption, number of active sites, and the construction of S-scheme heterojunction. Furthermore, the S-scheme charge transfer mechanism for the CWO/CIS catalyst system has been confirmed by in situ X-ray photoelectron spectroscopy (in situ XPS), electron spin resonance data, radical capturing experiments, and density functional theory (DFT) calculations. This research contributes valuable understanding for the systematic design and development of bifunctional S-scheme heterojunctions for gaseous pollutants removal and H₂ production.
- CoWO₄,
- CdIn₂S₄,
- H₂ production,
- HCHO degradation,
- DFT calculations
1. [1]
  Z. Wu, X. Meng, Z. Zhao, Nano Energy 132 (2024) 110364, https://doi.org/10.1016/j.nanoen.2024.110364. doi: 10.1016/j.nanoen.2024.110364
2. [2]
  Y. Li, Y. Ma, Y. Jiang, M. Sun, S. Zhou, W. Jiang, B. Liu, C. Liu, G. Che, Sep. Purif. Technol. 354 (2025) 128993, https://doi.org/10.1016/j.seppur.2024.128993. doi: 10.1016/j.seppur.2024.128993
3. [3]
  J. Cai, C. Cheng, B. Liu, J. Zhang, C. Jiang, B. Cheng, Acta Phys. Chim. Sin. 41 (2025) 100084, https://doi.org/10.1016/j.actphy.2025.100084. doi: 10.1016/j.actphy.2025.100084
4. [4]
  S. Li, R. Yan, M. Cai, W. Jiang, M. Zhang, X. Li, J. Mater. Sci. Technol. 164 (2023) 59, https://doi.org/10.1016/j.jmst.2023.05.009. doi: 10.1016/j.jmst.2023.05.009
5. [5]
  K. Meng, J. Zhang, B. Zhu, C. Jiang, H. García, J. Yu, Adv. Mater. 37 (2025) 2505088, https://doi.org/10.1002/adma.202505088. doi: 10.1002/adma.202505088
6. [6]
  L. Zhang, J. Zhang, J. Yu, H. García, Nat. Rev. Chem. 9 (2025) 328, https://doi.org/10.1038/s41570-025-00698-3 doi: 10.1038/s41570-025-00698-3
7. [7]
  B. Liu, K. Meng, B. Cheng, L. Wang, G. Liang, C. Bie, J. Mater. Sci. Technol. 231 (2025) 286, https://doi.org/10.1016/j.jmst.2025.02.013. doi: 10.1016/j.jmst.2025.02.013
8. [8]
  H. Ding, R. Shen, K. Huang, C. Liang, P. Zhang, Adv. Funct. Mater. 34 (2024) 2400065, https://doi.org/10.1002/adfm.202400065. doi: 10.1002/adfm.202400065
9. [9]
  A. Rong, Q. Zhao, H. Shi, X. Cai, H. Zhu, C. Chen, X. Zhou, G. Yan, L. Mao, Sep. Purif. Technol. 356 (2025) 130010, https://doi.org/10.1016/j.seppur.2024.130010. doi: 10.1016/j.seppur.2024.130010
10. [10]
  X. Zhou, H. Shi, A. Rong, M. Wei, C. Chen, Z. Chen, Appl. Surf. Sci. 694 (2025) 162844, https://doi.org/10.1016/j.apsusc.2025.162844. doi: 10.1016/j.apsusc.2025.162844
11. [11]
  S. Cao, B. Zhong, C. Bie, B. Cheng, F. Xu, Acta Phys. Chim. Sin. 40 (2024) 2307016, https://doi.org/10.3866/PKU.WHXB202307016. doi: 10.3866/PKU.WHXB202307016
12. [12]
  K. Huang, G. Liang, S. Sun, H. Hu, X. Peng, R. Shen, X. Li, J. Mater. Sci. Technol. 193 (2024) 98, https://doi.org/10.1016/j.jmst.2024.01.034. doi: 10.1016/j.jmst.2024.01.034
13. [13]
  M. Sayed, K. Qi, X. Wu, L. Zhang, H. García, J. Yu, Chem. Soc. Rev. 54 (2025) 4874, https://doi.org/10.1039/d4cs01091d. doi: 10.1039/d4cs01091d
14. [14]
  H. Shi, E. Zhang, H. Zhu, H. Wang, A. Rong, L. Mao, Int. J. Hydrogen Energy. 51 (2024) 1287, https://doi.org/10.1016/j.ijhydene.2023.09.183. doi: 10.1016/j.ijhydene.2023.09.183
15. [15]
  A. Bhirud, N. Chaudhari, L. Nikam, R. Sonawane, K. Patil, B. Kale, Int. J. Hydrogen Energy. 36 (2011) 11628, https://doi.org/10.1016/j.ijhydene.2011.06.061. doi: 10.1016/j.ijhydene.2011.06.061
16. [16]
  Q. Wang, L. Wang, Y. Jiang, Y. Liu, W. Zhang, J. Zhang, A. L. O. Macauley, Environ. Res. 209 (2022) 112800, https://doi.org/10.1016/j.envres.2022.112800. doi: 10.1016/j.envres.2022.112800
17. [17]
  X. Ma, S. Hou, D. Li, Y. Wu, S. Li, Sep. Purif. Technol. 354 (2025) 129057, https://doi.org/10.1016/j.seppur.2024.129057. doi: 10.1016/j.seppur.2024.129057
18. [18]
  C. Bie, C. Jiang, J. Yang, X. Sun, X. Zeng, J. Zhang, B. Zhu, J. Mater. Sci. Technol. 229 (2025) 48, https://doi.org/10.1016/j.jmst.2024.12.047. doi: 10.1016/j.jmst.2024.12.047
19. [19]
  Y. Liu, Y. Liu, Z. Yao, Z. Yu, H. Zhu, C. Xing, Y. Wang, X. Tan, Y. Huang, Y. Hou, S. Wang, Appl. Catal. B Environ. 371 (2025) 125275, https://doi.org/10.1016/j.apcatb.2025.125275. doi: 10.1016/j.apcatb.2025.125275
20. [20]
  L. Li, K. Kuang, X. Zheng, J. Wang, W. Ren, J. Ge, S. Zhang, S. Chen, J. Colloid Interface Sci. 663 (2024) 981, https://doi.org/10.1016/j.jcis.2024.02.218. doi: 10.1016/j.jcis.2024.02.218
21. [21]
  F. Liu, B. Sun, Z. Liu, Y. Wei, T. Gao, G. Zhou, Chin. J. Catal. 64 (2024) 152, https://doi.org/10.1016/s1872-2067(24)60099-9. doi: 10.1016/s1872-2067(24)60099-9
22. [22]
  M. Gu, J. Zhang, I. V. Kurganskii, A. S. Poryvaev, M. V. Fedin, B. Cheng, J. Yu, L. Zhang, Adv. Mater. 37 (2025) 2414803, https://doi.org/10.1002/adma.202414803. doi: 10.1002/adma.202414803
23. [23]
  X. Zhou, S. Zhang, W. Liu, T. Liu, Adv. Compos. Hybrid Mater. 8 (2025) 102, https://doi.org/10.1007/s42114-024-01134-8. doi: 10.1007/s42114-024-01134-8
24. [24]
  D. Peng, Z. Zhao, A. Rong, J. Sun, X. Li, H. Shi, Z. Su, ACS Appl. Nano Mater. 8 (2025) 7419, https://doi.org/10.1021/acsanm.5c01092. doi: 10.1021/acsanm.5c01092
25. [25]
  C. Chen, H. Shi, A. Rong, M. Wei, X. Zhou, B. Feng, W. Wang, Int. J. Hydrogen. Energy. 130 (2025) 249, https://doi.org/10.1016/j.ijhydene.2025.04.330. doi: 10.1016/j.ijhydene.2025.04.330
26. [26]
  F. Rong, Y. Xue, W. Tang, Q. Lu, M. Wei, E. Guo, Y. Pang, J. Taiwan Inst. Chem. E. 133 (2022) 104267, https://doi.org/10.1016/j.jtice.2022.104267. doi: 10.1016/j.jtice.2022.104267
27. [27]
  G. Yang, H. Zhang, M. Dou, H. Yang, X. Yin, D. Li, H. Zhao, J. Dou, J. Colloid Interface Sci. 610 (2022) 1057, https://doi.org/10.1016/j.jcis.2021.11.159. doi: 10.1016/j.jcis.2021.11.159
28. [28]
  Z. Zeng, L. Mao, R. Zhang, Y. Liu, Y. Ling, X. Cai, J. Zhang, Chem. Eng. J. 496 (2024) 153769, https://doi.org/10.1016/j.cej.2024.153769. doi: 10.1016/j.cej.2024.153769
29. [29]
  W. Chen, T. Huang, Y. Hua, T. Liu, X. Liu, S. Chen, J. Hazard. Mater. 320 (2016) 529, https://doi.org/10.1016/j.jhazmat.2016.08.025. doi: 10.1016/j.jhazmat.2016.08.025
30. [30]
  P. Bagwade, V. Magdum, D. Malavekar, Y. Chitare, J. Gunjakar, J. Mater. Sci-Mater. El. 33 (2022) 24646, https://doi.org/10.1007/s10854-022-09174-w. doi: 10.1007/s10854-022-09174-w
31. [31]
  H. Zhu, H. Shi, J. Li, X. Qu, S. Zhao, H. Wang, A. Rong, Z. Chen, J. Alloys Compd. 976 (2024) 173072, https://doi.org/10.1016/j.jallcom.2023.173072. doi: 10.1016/j.jallcom.2023.173072
32. [32]
  J. Yan, L. Wei, Acta Phys. Chim. Sin. 40 (2024) 2312024, https://doi.org/10.3866/PKU.WHXB202312024. doi: 10.3866/PKU.WHXB202312024
33. [33]
  J. Wang, J. Li, Z. Li, J. Wu, H. Si, Y. Wu, Z. Guo, X. Wang, F. Liao, H. Huang, M. Shao, Y. Liu, Z. Kang, Nano Res. 17 (2024) 5956, https://doi.org/10.1007/s12274-024-6623-4. doi: 10.1007/s12274-024-6623-4
34. [34]
  M. Cai, Y. Liu, K. Dong, X. Chen, S. Li, Chin. J. Catal. 52 (2023) 239, https://doi.org/10.1016/s1872-2067(23)64496-1. doi: 10.1016/s1872-2067(23)64496-1
35. [35]
  Y. Zhang, S. Wang, Chin. J. Catal. 71 (2025) 1, https://doi.org/10.1016/S1872-2067(24)60253-6. doi: 10.1016/S1872-2067(24)60253-6
36. [36]
  G. Sun, Z. Tai, J. Zhang, B. Cheng, H. Yu, J. Yu, Appl. Catal. B. 358 (2024) 124459, https://doi.org/10.1016/j.apcatb.2024.124459. doi: 10.1016/j.apcatb.2024.124459
37. [37]
  S. Li, C. You, F. Yang, G. Liang, C. Zhuang, X. Li, Chin. J. Catal. 68 (2025) 259–271, https://doi.org/10.1016/s1872-2067(24)60181-6. doi: 10.1016/s1872-2067(24)60181-6
38. [38]
  Y. Deng, S. Wang, T. Zhou, B. Liu, L. Wang, C. Liu, W. Jiang, G. Che, Chem. Eng. J. 497 (2024) 154580, https://doi.org/10.1016/j.cej.2024.154580. doi: 10.1016/j.cej.2024.154580
39. [39]
  B. Zhu, C. Jiang, J. Xu, Z. Zhang, J. Fu, J. Yu, Mater. Today 82 (2025) 251, https://doi.org/10.1016/j.mattod.2024.11.012. doi: 10.1016/j.mattod.2024.11.012
40. [40]
  Z. Yan, X. Zhang, B. Yu, J. Yu, D. Han, Y. Jin, C. Wu, G. Dai, X. Xiong, Ceram. Int. 50 (2024) 3052, https://doi.org/10.1016/j.ceramint.2023.11.053. doi: 10.1016/j.ceramint.2023.11.053
41. [41]
  A. Rong, H. Shi, Q. Zhao, H. Zhu, H. Wang, G. Yan, Sep. Purif. Technol. 348 (2024) 127782, https://doi.org/10.1016/j.seppur.2024.127782. doi: 10.1016/j.seppur.2024.127782
42. [42]
  P. Li, Y. Cui, Z. Wang, G. Dawson, C. Shao, K. Dai, Acta Phys. Chim. Sin. 41 (2025) 100065, https://doi.org/10.1016/j.actphy.2025.100065. doi: 10.1016/j.actphy.2025.100065
43. [43]
  U. Sahoo, S. Pattnayak, S. Choudhury, P. Aparajita, DK. Pradhan, G. Hota, Appl. Catal. B–Environ. 343 (2024) 123524, https://doi.org/10.1016/j.apcatb.2023.123524. doi: 10.1016/j.apcatb.2023.123524
44. [44]
  H. Long, X. Zhang, Z. Zhang, J. Zhang, J. Yu, H. Yu, Nat. Commun. 16 (2025) 946, https://doi.org/10.1038/s41467-025-56306-x. doi: 10.1038/s41467-025-56306-x
45. [45]
  J. Wang, X. Xu, Y. Shen, J. Environ. Chem. Eng. 10 (2022) 107436, https://doi.org/10.1016/j.jece.2022.107436. doi: 10.1016/j.jece.2022.107436
46. [46]
  Y. Yang, T. Ji, Y. Lin, W. Su, J. Clean. Prod. 295 (2021) 126458, https://doi.org/10.1016/j.jclepro.2021.126458. doi: 10.1016/j.jclepro.2021.126458
47. [47]
  S. Xin, G. Liu, X. Ma, J. Gong, B. Ma, Q. Yan, Q. Chen, D. Ma, G. Zhang, M. Gao, Y. Xin, Appl. Catal. B–Environ. 280 (2021) 119386, https://doi.org/10.1016/j.apcatb.2020.119386. doi: 10.1016/j.apcatb.2020.119386
48. [48]
  Y. Li, W. Li, F. Liu, M. Li, X. Qi, M. Xue, Y. Wang, F. Han, J. Nanopart. Res. 22 (2020) 122, https://doi.org/10.1007/s11051-020-04860-4. doi: 10.1007/s11051-020-04860-4
49. [49]
  W. Yu, Z. Shu, M. Zhao, W. Ma, Sep. Purif. Technol. 327 (2023) 124966, https://doi.org/10.1016/j.seppur.2023.124966. doi: 10.1016/j.seppur.2023.124966
50. [50]
  J. Ye, M. Wu, B. Zhu, B. Cheng, J. Yu, J. Hazard. Mater. 474 (2024) 134672, https://doi.org/10.1016/j.jhazmat.2024.134672. doi: 10.1016/j.jhazmat.2024.134672
51. [51]
  Z. Ai, K. Deng, Q. Wan, L. Zhang, S. Lee, J. Phys. Chem. C. 114 (2010) 6237, https://doi.org/10.1021/jp910514f. doi: 10.1021/jp910514f
52. [52]
  J. Guo, C. Lin, C. Jiang, P. Zhang, Appl. Surf. Sci. 475 (2019) 237, https://doi.org/10.1016/j.apsusc.2018.12.238. doi: 10.1016/j.apsusc.2018.12.238
53. [53]
  X. Li, Y. Huang, W. Ho, S. Han, P. Wang, S. Lee, Z. Zhang, Appl. Catal. B-Environ. 338 (2023) 123048, https://doi.org/10.1016/j.apcatb.2023.123048. doi: 10.1016/j.apcatb.2023.123048
54. [54]
  S. Mao, R. He, S. Song, Chin. J. Catal. 64 (2024) 1, https://doi.org/10.1016/S1872-2067(24)60102-6. doi: 10.1016/S1872-2067(24)60102-6
55. [55]
  Y. Li, D. Han, Z. Wang, F. Gou, ACS Appl. Mater. Interfaces. 16 (2024) 7080, https://doi.org/10.1021/acsami.3c15898. doi: 10.1021/acsami.3c15898
56. [56]
  D. Peng, L. Mao, J. Sun, X. Li, H. Shi, Z. Su, Int. J. Hydrogen Energy. 114 (2025) 60–70, https://doi.org/10.1016/j.ijhydene.2025.03.029. doi: 10.1016/j.ijhydene.2025.03.029
57. [57]
  D. Xu, R. He, Z. Jiang, J. Mater. Sci. Technol. 236 (2025) 280, https://doi.org/10.1016/j.jmst.2025.02.040. doi: 10.1016/j.jmst.2025.02.040
58. [58]
  H. Moon, S. Kim, S. Joo, M. Kim, N. Park, Nano Today. 49 (2023) 101785, https://doi.org/10.1016/j.nantod.2023.101785. doi: 10.1016/j.nantod.2023.101785
59. [59]
  X. Wang, K. Sun, S. Gu, Y. Zhang, D. Wu, X. Zhou, K. Gao, Y. Ding, Appl. Surf. Sci. 549 (2021) 149341, https://doi.org/10.1016/j.apsusc.2021.149341. doi: 10.1016/j.apsusc.2021.149341
60. [60]
  D. Peng, Y. Wang, H. Shi, W. Jiang, T. Jin, Z. Jin, Z. Chen, J. Colloid Interface Sci. 613 (2022) 194, https://doi.org/10.1016/j.jcis.2021.10.179. doi: 10.1016/j.jcis.2021.10.179
61. [61]
  C. Shen, X. Li, B. Xue, D. Feng, Y. Liu, F. Yang, M. Zhang, S. Li, Appl. Surf. Sci. 679 (2025) 161303, https://doi.org/10.1016/j.apsusc.2024.161303. doi: 10.1016/j.apsusc.2024.161303
62. [62]
  H. Shi, T. Zhao, J. Wang, Y. Wang, Z. Chen, B. Liu, H. Ji, W. Wang, G. Zhang, Y. Li, J. Alloys Compd. 860 (2021) 157924, https://doi.org/10.1016/j.jallcom.2020.157924. doi: 10.1016/j.jallcom.2020.157924
63. [63]
  S. Wan, W. Wang, B. Cheng, G. Luo, Q. Shen, J. Yu, J. Zhang, S. Cao, Nat. Commun. 15 (2024) 9612, https://doi.org/10.1038/s41467-024-53951. doi: 10.1038/s41467-024-53951
64. [64]
  J. Sun, Y. Zhang, S. Fan, X. Li, Q. Zhao, Appl. Catal. B-Environ. 356 (2024) 124248, https://doi.org/10.1016/j.apcatb.2024.124248. doi: 10.1016/j.apcatb.2024.124248
65. [65]
  Z. Meng, J. Zhang, H. Long, H. García, L. Zhang, B. Zhu, J. Yu, Angew. Chem. Int. Ed. 64 (2025) e202425456, https://doi.org/10.1002/anie.202505456. doi: 10.1002/anie.202505456
66. [66]
  Z. Wu, L. Hou, W. Li, Q. Chen, C. Jin, Y. Chen, Q. Wei, H. Yang, Y. Jiang, D. Tang, J. Colloid Interface Sci. 610 (2022) 136, https://doi.org/10.1016/j.jcis.2021.12.036. doi: 10.1016/j.jcis.2021.12.036
67. [67]
  Z. Chen, Y. Gao, F. Chen, H. Shi, Chem. Eng. J. 413 (2021) 127474, https://doi.org/10.1016/j.cej.2020.127474. doi: 10.1016/j.cej.2020.127474
68. [68]
  T. Zhao, D. Peng, W. Hu, H. Shi, A. Rong, X. Li, G. Yan, Z. Su, J. Mol. Struct. 1335 (2025) 141934, https://doi.org/10.1016/j.molstruc.2025.141934. doi: 10.1016/j.molstruc.2025.141934
69. [69]
  M. Wei, X. Zhou, C. Cheng, J. Zhang, C. Jiang, B. Cheng, J. Mater. Sci. Technol. 232 (2025) 302, https://doi.org/10.1016/j.jmst.2025.01.036. doi: 10.1016/j.jmst.2025.01.036
70. [70]
  R. Li, H. Li, X. Zhang, B. Liu, B. Wu, B. Zhu, J. Yu, G. Liu, L. Zheng, Q. Zeng, Adv. Funct. Mater. 34 (2024) 2402797, https://doi.org/10.1002/adfm.202402797. doi: 10.1002/adfm.202402797
71. [71]
  H. Hu, X. Zhang, K. Zhang, Y. Ma, H. Wang, H. Li, H. Huang, X. Sun, T. Ma, Adv. Energy Mater. 14 (2024) 2303638, https://doi.org/10.1002/aenm.202303638. doi: 10.1002/aenm.202303638
72. [72]
  J. Zhu, S. Zhang, R. He, Chin. J. Catal. 59 (2024) 4, https://doi.org/10.1016/S1872-2067(24)60011-2. doi: 10.1016/S1872-2067(24)60011-2
73. [73]
  X. Jiang, Z. Chen, Y. Shu, A. Idris, S. Li, B. Peng, J. Wang, Z. Li, Appl. Catal. B-Environ. 348 (2024) 123840, https://doi.org/10.1016/j.apcatb.2024.123840. doi: 10.1016/j.apcatb.2024.123840
1. [1]
  Yanyan Zhao , Zhen Wu , Yong Zhang , Bicheng Zhu , Jianjun Zhang . Enhancing photocatalytic H₂O₂ production via dual optimization of charge separation and O₂ adsorption in Au-decorated S-vacancy-rich CdIn₂S₄. Acta Physico-Chimica Sinica, 2025, 41(11): 100142-0. doi: 10.1016/j.actphy.2025.100142
2. [2]
  Haitao Wang , Lianglang Yu , Jizhou Jiang , Arramel , Jing Zou . S-Doping of the N-Sites of g-C₃N₄ to Enhance Photocatalytic H₂ Evolution Activity. Acta Physico-Chimica Sinica, 2024, 40(5): 2305047-0. doi: 10.3866/PKU.WHXB202305047
3. [3]
  Jingzhao Cheng , Shiyu Gao , Bei Cheng , Kai Yang , Wang Wang , Shaowen Cao . Construction of 4-Amino-1H-imidazole-5-carbonitrile Modified Carbon Nitride-Based Donor-Acceptor Photocatalyst for Efficient Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(11): 2406026-0. doi: 10.3866/PKU.WHXB202406026
4. [4]
  Chenye An , Sikandaier Abiduweili , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . Hierarchical S-scheme Heterojunction of Red Phosphorus Nanoparticles Embedded Flower-like CeO₂ Triggering Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-0. doi: 10.3866/PKU.WHXB202405019
5. [5]
  Shuang Cao , Bo Zhong , Chuanbiao Bie , Bei Cheng , Feiyan Xu . Insights into Photocatalytic Mechanism of H₂ Production Integrated with Organic Transformation over WO₃/Zn_0.5Cd_0.5S S-Scheme Heterojunction. Acta Physico-Chimica Sinica, 2024, 40(5): 2307016-0. doi: 10.3866/PKU.WHXB202307016
6. [6]
  Jiawei Hu , Kai Xia , Ao Yang , Zhihao Zhang , Wen Xiao , Chao Liu , Qinfang Zhang . Interfacial Engineering of Ultrathin 2D/2D NiPS₃/C₃N₅ Heterojunctions for Boosting Photocatalytic H₂ Evolution. Acta Physico-Chimica Sinica, 2024, 40(5): 2305043-0. doi: 10.3866/PKU.WHXB202305043
7. [7]
  Fanpeng Meng , Fei Zhao , Jingkai Lin , Jinsheng Zhao , Huayang Zhang , Shaobin Wang . Optimizing interfacial electric fields in carbon nitride nanosheet/spherical conjugated polymer S-scheme heterojunction for hydrogen evolution. Acta Physico-Chimica Sinica, 2025, 41(8): 100095-0. doi: 10.1016/j.actphy.2025.100095
8. [8]
  Jiajie Cai , Chang Cheng , Bowen Liu , Jianjun Zhang , Chuanjia Jiang , Bei Cheng . CdS/DBTSO-BDTO S-scheme photocatalyst for H₂ production and its charge transfer dynamics. Acta Physico-Chimica Sinica, 2025, 41(8): 100084-0. doi: 10.1016/j.actphy.2025.100084
9. [9]
  Xiaorui Chen , Xuan Luo , Tongming Su , Xinling Xie , Liuyun Chen , Yuejing Bin , Zuzeng Qin , Hongbing Ji . Ga-doped Cu/γ-Al₂O₃ bifunctional interface sites promote the direct hydrogenation of CO₂ to DME. Acta Physico-Chimica Sinica, 2025, 41(10): 100126-0. doi: 10.1016/j.actphy.2025.100126
10. [10]
  Peipei Sun , Jinyuan Zhang , Yanhua Song , Zhao Mo , Zhigang Chen , Hui Xu . Built-in Electric Fields Enhancing Photocarrier Separation and H₂ Evolution. Acta Physico-Chimica Sinica, 2024, 40(11): 2311001-0. doi: 10.3866/PKU.WHXB202311001
11. [11]
  Jiabo Huang , Quanxin Li , Zhongyan Cao , Li Dang , Shaofei Ni . Elucidating the Mechanism of Beckmann Rearrangement Reaction Using Quantum Chemical Calculations. University Chemistry, 2025, 40(3): 153-159. doi: 10.12461/PKU.DXHX202405172
12. [12]
  Jiali Lei , Juan Wang , Wenhui Zhang , Guohong Wang , Zihui Liang , Jinmao Li . TiO₂/CdIn₂S₄ S-scheme heterojunction photocatalyst promotes photocatalytic hydrogen evolution coupled vanillyl alcohol oxidation. Acta Physico-Chimica Sinica, 2025, 41(12): 100174-0. doi: 10.1016/j.actphy.2025.100174
13. [13]
  Sumiya Akter Dristy , Md Ahasan Habib , Shusen Lin , Mehedi Hasan Joni , Rutuja Mandavkar , Young-Uk Chung , Md Najibullah , Jihoon Lee . Exploring Zn doped NiBP microspheres as efficient and stable electrocatalyst for industrial-scale water splitting. Acta Physico-Chimica Sinica, 2025, 41(7): 100079-0. doi: 10.1016/j.actphy.2025.100079
14. [14]
  Jianyin He , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Construction of ZnCoP/CdLa₂S₄ Schottky Heterojunctions for Enhancing Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(11): 2404030-0. doi: 10.3866/PKU.WHXB202404030
15. [15]
  Yi Yang , Xin Zhou , Miaoli Gu , Bei Cheng , Zhen Wu , Jianjun Zhang . Femtosecond transient absorption spectroscopy investigation on ultrafast electron transfer in S-scheme ZnO/CdIn₂S₄ photocatalyst for H₂O₂ production and benzylamine oxidation. Acta Physico-Chimica Sinica, 2025, 41(6): 100064-0. doi: 10.1016/j.actphy.2025.100064
16. [16]
  Jingzhuo Tian , Chaohong Guan , Haobin Hu , Enzhou Liu , Dongyuan Yang . Waste plastics promoted photocatalytic H₂ evolution over S-scheme NiCr₂O₄/twinned-Cd_0.5Zn_0.5S homo-heterojunction. Acta Physico-Chimica Sinica, 2025, 41(6): 100068-0. doi: 10.1016/j.actphy.2025.100068
17. [17]
  Ruiyun Liu , Ping Wang , Xuefei Wang , Feng Chen , Huogen Yu . Work-function-engineered Mo 4d electronic structure modulation in Mo₂C MXene cocatalyst for efficient photocatalytic H₂ evolution. Acta Physico-Chimica Sinica, 2025, 41(11): 100137-0. doi: 10.1016/j.actphy.2025.100137
18. [18]
  Menglan Wei , Xiaoxia Ou , Yimeng Wang , Mengyuan Zhang , Fei Teng , Kaixuan Wang . S-scheme heterojunction g-C₃N₄/Bi₂WO₆ highly efficient degradation of levofloxacin: performance, mechanism and degradation pathway. Acta Physico-Chimica Sinica, 2025, 41(9): 100105-0. doi: 10.1016/j.actphy.2025.100105
19. [19]
  Linfeng Xiao , Wanlu Ren , Shishi Shen , Mengshan Chen , Runhua Liao , Yingtang Zhou , Xibao Li . Enhancing Photocatalytic Hydrogen Evolution through Electronic Structure and Wettability Adjustment of ZnIn₂S₄/Bi₂O₃ S-Scheme Heterojunction. Acta Physico-Chimica Sinica, 2024, 40(8): 2308036-0. doi: 10.3866/PKU.WHXB202308036
20. [20]
  Mian Wei , Chang Cheng , Bowen He , Bei Cheng , Kezhen Qi , Chuanbiao Bie . Inorganic-organic CdS/YBTPy S-scheme photocatalyst for efficient hydrogen production and its mechanism. Acta Physico-Chimica Sinica, 2025, 41(12): 100158-0. doi: 10.1016/j.actphy.2025.100158

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(80)
HTML views(10)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Enhanced bifunctional photocatalytic performances for H2 evolution and HCHO elimination with an S-scheme CoWO4/CdIn2S4 heterojunction

Metrics

通讯作者: 陈斌, bchen63@163.com

Enhanced bifunctional photocatalytic performances for H₂ evolution and HCHO elimination with an S-scheme CoWO₄/CdIn₂S₄ heterojunction