电催化氯代芳香烃脱氯催化剂的合成策略、应用与挑战

引用本文: 王琪, 刘宇庆, 王洁菲, 马媛媛, 都京, 韩占刚. 电催化氯代芳香烃脱氯催化剂的合成策略、应用与挑战[J]. 物理化学学报, 2025, 41(10): 100120. doi: 10.1016/j.actphy.2025.100120 shu

Citation: Qi Wang, Yuqing Liu, Jiefei Wang, Yuan-Yuan Ma, Jing Du, Zhan-Gang Han. Catalysts for electrocatalytic dechlorination of chlorinated aromatic hydrocarbons: synthetic strategies, applications, and challenges[J]. Acta Physico-Chimica Sinica, 2025, 41(10): 100120. doi: 10.1016/j.actphy.2025.100120 shu

电催化氯代芳香烃脱氯催化剂的合成策略、应用与挑战

王琪 ^{1, 2,} ,
刘宇庆 ^1, ,
王洁菲 ^1, ,
马媛媛 ^{1,
,} ,
都京 ^{1,
,} ,
韩占刚 ^{1,
,}

1.
河北师范大学化学与材料科学学院, 分析测试中心, 国家级实验化学教育示范中心, 河北薄膜太阳能电池材料与器件工程研究中心, 河北能源转换材料与器件技术创新中心, 河北石家庄 050024
2.
邢台学院化学工程与生物技术学院, 河北邢台 054001

通讯作者: 马媛媛, mayy334@hebtu.edu.cn; 都京, duj622@hebtu.edu.cn; 韩占刚, hanzg116@hebtu.edu.cn

基金项目:
国家自然科学基金 22471056

国家自然科学基金 22301058

国家自然科学基金 22371065

河北省自然科学基金 B2024205033

河北省自然科学基金 B2024205007

河北省自然科学基金 B2022205005

河北省教育厅科学技术研究项目 QN2023049

中国博士后科学基金资助项目 2021TQ0095

河北省科技厅项目 22567622H

河北师范大学科研基金 L2023B51

河北师范大学化学博士后科研流动站

摘要: 电催化脱氯(EHDC)因其高效率、无二次污染及反应条件温和等特点，被认为是极具前景的污染物降解技术。在EHDC过程中，活性氢的生成、C―Cl键的断裂以及氯代芳香烃或反应中间体的吸附/脱附是核心步骤。该技术依赖高活性电催化剂以提升催化效率与成本效益。本文首先系统总结了EHDC中催化剂活性与稳定性的评价方法和指标，分别从贵金属与非贵金属基催化剂体系出发，综述了近年来低成本、高性能电催化剂的前沿进展。重点探讨了催化剂构效关系及提高催化剂活性的关键策略，如构建异质界面和设计合金结构优化活性组分的电子结构特性以及调控催化剂局域微环境改善电荷转移效率等。此外，还探讨了氯代芳香烃的结构对电催化脱氯活性的影响关系。最后分析了当前电催化加氢脱氯技术面临的挑战与未来发展方向，为含氯有机物的高效脱氯转化研究提供理论和技术参考。

关键词:

English

Catalysts for electrocatalytic dechlorination of chlorinated aromatic hydrocarbons: synthetic strategies, applications, and challenges

Qi Wang ^{1, 2,} ,
Yuqing Liu ^1, ,
Jiefei Wang ^1, ,
Yuan-Yuan Ma ^{1,
,} ,
Jing Du ^{1,
,} ,
Zhan-Gang Han ^{1,
,}

1.
Hebei Technology Innovation Center for Energy Conversion Materials and Devices, Hebei Engineering Research Center of Thin Film Solar Cell Materials and Devices, National Demonstration Center for Experimental Chemistry Education, Testing and Analysis Center, College of Chemistry and Materials Science, Hebei Normal University, Shijiazhuang 050024, Hebei Province, China
2.
College of Chemistry and Chemical Engineering, Xingtai University, Xingtai 054001, Hebei Province, China

Corresponding author: Email: mayy334@hebtu.edu.cn (Y. Ma); Email: duj622@hebtu.edu.cn (J. Du); Email: hanzg116@hebtu.edu.cn (Z. Han)

Received Date: 16 April 2025
Accepted Date: 11 June 2025
Revised Date: 25 May 2025
Available Online: 15 October 2025
Fund Project:
the National Natural Science Foundation of China

the National Natural Science Foundation of China

the National Natural Science Foundation of China

the Natural Science Foundation of Hebei Province

the Natural Science Foundation of Hebei Province

the Natural Science Foundation of Hebei Province

the Science and Technology Project of Hebei Education Department

the China Postdoctoral Science Foundation funded project

the Project of Science and Technology Department of Hebei Province

the Science Foundation of Hebei Normal University

the Chemistry Postdoctoral Research Station at Hebei Normal University

Abstract: Electrocatalytic hydrodechlorination (EHDC) is a promising technology for degrading chlorinated aromatic hydrocarbons (CAHs), offering high efficiency, minimal secondary pollution, and mild operating conditions. Its effectiveness relies on three critical steps: atomic hydrogen (H*) generation, C―Cl bond cleavage, and adsorption/desorption of CAHs/products. Developing high-performance electrocatalysts is essential to optimize energy efficiency and cost-effectiveness. It is urgent to summarize research progress on design strategies for catalysts and establish fundamental principles. In this review, we first summarize commonly deployed measurement methods and metrics for assessing catalyst activity and stability in EHDC. Then, a series of strategies for enhancing the production of H*, facilitating the cleavage of C―Cl bonds, and optimizing the adsorption and desorption kinetics of CAHs and their intermediates/products on the catalyst surface are summarized. These strategies include the loading of catalysts on carbon-based/transition-based support to enhance the dispersion of Pd; constructing heterostructures or forming alloys to modulate the electronic structure of active metal nanocatalysts and optimize its binding affinities with reactants and intermediates; and modulating the microenvironment to modify the interface hydrophilicity/hydrophobicity of catalyst to increase reaction rates or improve stability of catalysts. Additionally, the applications of electrocatalysts for EHDC in recent years, such as Pd-based supported electrocatalysts, Pd-based heterostructure electrocatalysts, Pd-based alloy electrocatalysts, and noble-metal-free electrocatalysts are discussed, as well as the influence of catalyst composition on performance. It is noted that the EHDC efficiency of CAHs is influenced not only by the catalyst but also significantly correlated with the structure of CAHs. Thus, the effects of CAHs structures on EHDC performance are also discussed. Studies demonstrate that weak adsorption between the electrode and CAHs is more conducive to EHDC reactions. The number and position of chlorine functional groups, steric hindrance, and the properties of other functional groups in the substrate molecule can also influence EHDC performance. Finally, the challenges and future prospects of EHDC are highlighted, including improving the catalytic performance of non-noble catalysts, employing advanced in situ and operando characterization techniques, and optimizing DFT calculations to more closely align with real catalytic conditions, all aiming to inspire new investigations and advancements in the field of EHDC of CAHs.

Key words:

1. [1]
  M. Chen, S. Shu, J. X. Li, X. S. Lv, F. Dong, G. M. Jiang, J. Hazard. Mater. 389 (2020) 121876, https://doi.org/10.1016/j.jhazmat.2019.121876. doi: 10.1016/j.jhazmat.2019.121876
2. [2]
  M. Y. Mao, J. Wu, Y. Wang, Y. Long, G. Y. Fan, Appl. Surf. Sci. 600 (2022) 153988, https://doi.org/10.1016/j.apsusc.2022.153988. doi: 10.1016/j.apsusc.2022.153988
3. [3]
  T. Wu, Y. Zuo, H. Chen, Z. Xu, S. Zheng, Appl. Catal. A-Gen. 666 (2023) 119407, https://doi.org/10.1016/j.apcata.2023.119407. doi: 10.1016/j.apcata.2023.119407
4. [4]
  G. M. Jiang, K. F. Wang, J. Y. Li, W. Y. Fu, Z. Y. Zhang, G. Johnson, X. S. Lv, Y. Zhang, S. Zhang, F. Dong, Chem. Eng. J. 348 (2018) 26, https://doi.org/10.1016/j.cej.2018.04.173. doi: 10.1016/j.cej.2018.04.173
5. [5]
  B. Yang, G. Yu, D. M. Shuai, Chemosphere 67 (2007) 1361, https://doi.org/10.1016/j.chemosphere.2006.10.046. doi: 10.1016/j.chemosphere.2006.10.046
6. [6]
  Y. Gao, D. He, L. Wu, Z. P. Wang, Y. Yao, Z. -H. Huang, H. Yang, M. -X. Wang, Chem. Eng. J. 420 (2021) 127411, https://doi.org/10.1016/j.cej.2020.127411. doi: 10.1016/j.cej.2020.127411
7. [7]
  Z. T. Liu, Z. Zhou, W. Xiong, Q. Zhang, Langmuir 34 (2018) 10389, https://doi.org/10.1021/acs.langmuir.8b02156. doi: 10.1021/acs.langmuir.8b02156
8. [8]
  Z. W. Cheng, D. Shou, P. Zhao, J. M. Chen, J. K. Zhao, J. M. Yu, S. H. Zhang, Y. H. Guan, Int. Biodeterior. Biodegrad. 180 (2023) 105585, https://doi.org/10.1016/j.ibiod.2023.105585. doi: 10.1016/j.ibiod.2023.105585
9. [9]
  X. Zhou, H. P. Luo, Q. Y. Chen, X. Cao C. S., Shen, J. Zhou, Chem. Eng. J. 402 (2020) 126175, https://doi.org/10.1016/j.cej.2020.126175. doi: 10.1016/j.cej.2020.126175
10. [10]
  Y. Xue, Z. H. Wang, R. Bush, F. Yang, R. X. Yuan, J. S. Liu, N. Smith, M. H. Huang, R. Dharmarajan, P. Annamalai, Chem. Eng. J. 415 (2021) 129041, https://doi.org/10.1016/j.cej.2021.129041. doi: 10.1016/j.cej.2021.129041
11. [11]
  Q. Wang, Q. Liu, Y. -Y. Ma, H. -X. Bi, J. Du, Z. -G. Han, Inorg. Chem. Front. 11 (2024) 1238, https://doi.org/10.1039/D3QI02130K. doi: 10.1039/D3QI02130K
12. [12]
  J. Liu, D. D. Han, P. J. Chen, L. P. Zhai, Y. J. Wang, W. H. Chen, L. W. Mi, L. P. Yang, Chem. Eng. J. 418 (2021) 129492, https://doi.org/10.1016/j.cej.2021.129492. doi: 10.1016/j.cej.2021.129492
13. [13]
  X. Y. Yu, D. Cabooter, R. Dewil, J. Hazard. Mater. 357 (2018) 81, https://doi.org/10.1016/j.jhazmat.2018.05.049. doi: 10.1016/j.jhazmat.2018.05.049
14. [14]
  Z. Zhang, N. Cissoko, J. J. Wo, X. H. Xu, J. Hazard. Mater. 165 (2009) 78, https://doi.org/10.1016/j.jhazmat.2008.09.080. doi: 10.1016/j.jhazmat.2008.09.080
15. [15]
  J. X. Li, Y. Y. Peng, W. D. Zhang, X. L. Shi, M. Chen, P. Wang, X. M. Zhang, H. L. Fu, X. Lv, F. Dong, Appl. Surf. Sci. 509 (2020) 145369, https://doi.org/10.1016/j.apsusc.2020.145369. doi: 10.1016/j.apsusc.2020.145369
16. [16]
  W. Y. Fu, S. Shu, J. X. Li, X. L. X. S. Shi, Y. X. Lv, Huang, F. Dong, G. M. Jiang, Nanoscale 11 (2019) 15892, https://doi.org/10.1039/C9NR04634H. doi: 10.1039/C9NR04634H
17. [17]
  Y. -H. Xu, H. -X. Ma, Q. -Q. Cai, Y. -H. Zhu, C. -A. Ma, Acta Phys. -Chim. Sin. 29 (2013) 973, https://doi.org/10.3866/PKU.WHXB201302283. doi: 10.3866/PKU.WHXB201302283
18. [18]
  H. X. Ma, T. J. Ge, Q. Q. Cai, Y. H. Xu, C. A. Ma, Acta Phys. -Chim. Sin. 32 (2016) 1715, https://doi.org/10.3866/PKU.WHXB20160412. doi: 10.3866/PKU.WHXB20160412
19. [19]
  Z. C. Mao, L. H. Liu, H. B. Yang, Y. L. Zhang, Z. Q. Yao, H. Wu, Y. Q. Huang, Y. H. Xu, B. Liu, Electrochim. Acta 391 (2021) 138886, https://doi.org/10.1016/j.electacta.2021.138886. doi: 10.1016/j.electacta.2021.138886
20. [20]
  H. Wu, H. X. Chen, C. C. Yu, R. F. Qu, M. Q. Shi, Z. M. Lou, J. Q. Zhu, J. M. Yu, Y. H. Xu, Chem. Eng. J. 463 (2023) 142484, https://doi.org/10.1016/j.cej.2023.142484. doi: 10.1016/j.cej.2023.142484
21. [21]
  H. Wu, Z. C. Mao, B. Q. Liu, D. Y. Chen, M. Q. Shi, B. S. Lv, Y. H. Xu, L. B. Wang, Appl. Catal. B-Environ. 337 (2023) 122978, https://doi.org/10.1016/j.apcatb.2023.122978. doi: 10.1016/j.apcatb.2023.122978
22. [22]
  Y. H. Xu, Z. C. Mao, R. F. Qu, J. S. Wang, J. M. Yu, X. Y. Luo, M. Q. Shi, X. B. Mao, J. Ding, B. Liu, Nat. Water 1 (2023) 95, https://doi.org/10.1038/s44221-022-00002-3. doi: 10.1038/s44221-022-00002-3
23. [23]
  H. Wu, L. Q. Chen, C. Tang, X. Y. Fan, Q. Liu, Y. H. Xu, Sep. Purif. Technol. 331 (2024) 125647, https://doi.org/10.1016/j.seppur.2023.125647. doi: 10.1016/j.seppur.2023.125647
24. [24]
  Y. Y. Peng, M. Y. Cui, Z. Y. Zhang, S. Shu, X. L. Shi, J. T. Brosnahan, C. Liu, Y. L. Zhang, P. Godbold, X. M. Zhang, F. Dong, G. M. Jiang, S. Zhang, ACS Catal. 9 (2019) 10803, https://doi.org/10.1021/acscatal.9b02282. doi: 10.1021/acscatal.9b02282
25. [25]
  Z. M. Lou, J. S. Zhou, M. Sun, J. Xu, K. L. Yang, D. Lv, Y. P. Zhao, X. H. Xu, Chem. Eng. J. 352 (2018) 549, https://doi.org/10.1016/j.cej.2018.07.057. doi: 10.1016/j.cej.2018.07.057
26. [26]
  A. Winkel, G. Proske, Ber. Dtsch. Chem. Ges. 69 (1936) 1917, https://doi.org/10.1002/cber.19360690823. doi: 10.1002/cber.19360690823
27. [27]
  M. Stackelberg, W. Z. Stracke, Elektrochem. Angew. Phys. Chem. 53 (2010) 118, https://doi.org/10.1002/bbpc.19490530308. doi: 10.1002/bbpc.19490530308
28. [28]
  G. M. Jiang, M. N. Lan, Z. Y. Zhang, X. S. Lv, Z. M. Lou, X. H. Xu, F. Dong, S. Zhang, Environ. Sci. Technol. 51 (2017) 7599, https://doi.org/10.1021/acs.est.7b01128. doi: 10.1021/acs.est.7b01128
29. [29]
  Z. M. Lou, Z. N. Wang, J. S. Zhou, C. C. Zhou, J. Xu, X. H. Xu, Environ. Sci-Nano. 7 (2020) 1566, https://doi.org/10.1039/D0EN00182A. doi: 10.1039/D0EN00182A
30. [30]
  Q. Wang, L. X. Zhou, Q. Chen, M. Y. Mao, W. D. Jiang, Y. Long, G. Y. Fan, J. Hazard. Mater. 408 (2021) 124456, https://doi.org/10.1016/j.jhazmat.2020.124456. doi: 10.1016/j.jhazmat.2020.124456
31. [31]
  Z. M. Zhang, R. Cheng, J. Nan, X. Q. Chen, C. Huang, D. Cao, C. H. Bai, J. L. Han, B. Liang, Z. L. Li, A. J. Wang, Chin. Chem. Lett. 33 (2022) 3823, https://doi.org/10.1016/j.cclet.2021.11.068. doi: 10.1016/j.cclet.2021.11.068
32. [32]
  K. F. Wang, S. Shu, M. Chen, J. Li, K. Zhou, J. Pan, X. L. Wang, X. J. Li, J. P. Sheng, F. Dong, Chem. Eng. J. 381 (2020) 122673, https://doi.org/10.1016/j.cej.2019.122673. doi: 10.1016/j.cej.2019.122673
33. [33]
  Q. Wang, J. Du, Y. Y. Ma, X. Y. Yin, Z. Y. Tian, Z. G. Han, Chem. Eng. J. 451 (2023) 139107, https://doi.org/10.1016/j.cej.2022.139107. doi: 10.1016/j.cej.2022.139107
34. [34]
  P. Wang, X. L. Shi, C. H. Fu, X. J. Li, J. X. Li, X. S. Lv, Y. H. Chu, F. Dong, G. M. Jiang, Nanoscale 12 (2020) 843, https://doi.org/10.1039/C9NR07528C. doi: 10.1039/C9NR07528C
35. [35]
  A. A. Isse, B. B. Huang, C. Durante, A. Gennaro, Appl. Catal. B-Environ. 126 (2012) 347, https://doi.org/10.1016/j.apcatb.2012.07.004. doi: 10.1016/j.apcatb.2012.07.004
36. [36]
  F. Wang, Z. Q. Fan, X. H. Wu, M. C. Li, C. A. Ma, Int. J. Electrochem. Sci. 10 (2015) 5101, https://doi.org/10.1016/S1452-3981(23)06690-7. doi: 10.1016/S1452-3981(23)06690-7
37. [37]
  J. Halász, B. Imre, I. Hannus, Appl. Catal. A-Gen. 271 (2004) 47, https://doi.org/10.1016/j.apcata.2004.02.045. doi: 10.1016/j.apcata.2004.02.045
38. [38]
  L. V. Romashov, L. L. Khemchyan, E. G. Gordeev, I. O. Koshevoy, S. P. Tunik, V. P. Ananikov, Organometallics 33 (2014) 6003, https://doi.org/10.1021/om500620u. doi: 10.1021/om500620u
39. [39]
  S. X. Wang, M. D. Yang, C. Y. Cui, Q. Z. Zheng, C. Z. Zhou, Y. J. Xin, Electrochim. Acta. 462 (2023) 142707, https://doi.org/10.1016/j.electacta.2023.142707. doi: 10.1016/j.electacta.2023.142707
40. [40]
  H. H. Qian, Y. T. Su, S. Yan, W. J. Fang, K. Yang, X. L. Weng, Appl. Surf. Sci. 665 (2024) 160245, https://doi.org/10.1016/j.apsusc.2024.160245. doi: 10.1016/j.apsusc.2024.160245
41. [41]
  J. M. Wang, X. F. Wei, P. P. Wang, J. Miao, R. C. Zhang, N. Zhang, X. Q. Zhou, H. Xu, J. Zhang, H. S. Li, S. G. Peng, Fuel 341 (2023) 127689, https://doi.org/10.1016/j.fuel.2023.127689. doi: 10.1016/j.fuel.2023.127689
42. [42]
  J. J. Li, S. M. Ma, Z. Y. Qi, J. Ding, M. H. Yin, B. Zhao, Z. R. Zhang, Y. Wang, H. W. Zhang, L. Wang, D. D. Dionysious, Appl. Catal. B-Environ. 322 (2023) 122076, https://doi.org/10.1016/j.apcatb.2022.122076. doi: 10.1016/j.apcatb.2022.122076
43. [43]
  Y. J. Chen, C. Feng, W. H. Wang, Z. Liu, J. X. Li, C. G. Liu, Y. Pan, Y. Q. Liu, Sep. Purif. Technol. 289 (2022) 120731, https://doi.org/10.1016/j.seppur.2022.120731. doi: 10.1016/j.seppur.2022.120731
44. [44]
  Z. Y. Kong, D. H. Li, R. S. Cai, T. Li, L. P. Diao, X. K. Chen, X. X. Wang, H. J. Zheng, Y. Jia, D. J. Yang, J. Hazard. Mater. 463 (2024) 132964, https://doi.org/10.1016/j.jhazmat.2023.132964. doi: 10.1016/j.jhazmat.2023.132964
45. [45]
  Z. F. Zhao, X. Y. Yao, R. P. Yu, X. Y. Luo, M. H. Chen, X. X. Zhang, Y. H. Xu, Y. Q. Chu, X. B. Mao, H. J. Zheng, Chem. Eng. J. 492 (2024) 152340, https://doi.org/10.1016/j.cej.2024.152340. doi: 10.1016/j.cej.2024.152340
46. [46]
  J. W. Lu, S. N. Zhang, H. Z. Zhou, C. J. Huang, L. Xia, X. F. Liu, H. Luo, H. Wang, Acta Phys. -Chim. Sin. 39 (2023) 2302021, https://doi.org/10.3866/PKU.WHXB202302021. doi: 10.3866/PKU.WHXB202302021
47. [47]
  C. M. Li, K. Chen, X. Y. Wang, N. Xue, H. Q. Yang, Acta Phys. -Chim. Sin. 37 (2021) 2009101, https://doi.org/10.3866/PKU.WHXB202009101. doi: 10.3866/PKU.WHXB202009101
48. [48]
  J. X. Li, Y. J. Chen, R. Y. Bai, C. Chen, W. H. Wang, Y. Pan, Y. Q. Liu, Chem. Eng. J. 435 (2022) 134932, https://doi.org/10.1016/j.cej.2022.134932. doi: 10.1016/j.cej.2022.134932
49. [49]
  P. Peng, A. Anastasopoulou, K. Brooks, H. Furukawa, M. E. Bowden, J. R. Long, T. Autrey, H. Breunig, Nat. Energy. 7 (2022) 448, https://doi.org/10.1038/s41560-022-01013-w. doi: 10.1038/s41560-022-01013-w
50. [50]
  X. S. Lv, K. X. Jiang, H. Wu, L. Ao, L. Hu, X. Y. Li, F. Shen, L. Shi, F. Dong, G. M. Jiang, ACS ES & T. Water. 2 (2022) 1451, https://doi.org/10.1021/acsestwater.2c00205. doi: 10.1021/acsestwater.2c00205
51. [51]
  X. Y. Shu, Q. Yang, F. B. Yao, Y. Zhong, W. C. Ren, F. Chen, J. Sun, Y. H. Ma, Z. Y. Fu, D. B. Wang, X. M. Li, Chem. Eng. J. 358 (2019) 903, https://doi.org/10.1016/j.cej.2018.10.095. doi: 10.1016/j.cej.2018.10.095
52. [52]
  L. -Y. Liu, M. -H. Cui, S. -M. Niu, X. -D. Zhang, X. -H. Li, W. -L. Wang, H. Liu, G. -S. Liu, A. -J. Wang, ACS EST. Engg. 4 (2024) 1275, https://doi.org/10.1021/acsestengg.3c00493. doi: 10.1021/acsestengg.3c00493
53. [53]
  J. J. Li, Y. Wang, B. Zhao, J. Ding, J. Zhang, M. H. Yin, Z. H. Zhang, S. M. Ma, Y. Q. Liu, Z. L. Tan, H. W. Zhang, L. Wang, D. D. Dionysiou, Appl. Catal. B-Environ. 332 (2023) 122754, https://doi.org/10.1016/j.apcatb.2023.122754. doi: 10.1016/j.apcatb.2023.122754
54. [54]
  J. T. Tang, K. N. Liu, X. Y. Li, M. Y. Fu, W. T. Yu, L. X. Jiang, J. X. Ye, S. J. Song, Environ. Chem. Eng. 11 (2023) 109843, https://doi.org/10.1016/j.jece.2023.109843. doi: 10.1016/j.jece.2023.109843
55. [55]
  Z. K. Wang, Y. Y. Wang, N. Zhang, L. X. Ma, J. Sun, C. Yu, S. J. Liu, R. B. Jiang, J. Mater. Chem. A 10 (2022) 10342, https://doi.org/10.1039/D2TA01931K. doi: 10.1039/D2TA01931K
56. [56]
  F. F. Qin, X. D. Tian, Z. Y. Guo, W. Z. Shen, ACS Sustainable Chem. Eng. 6 (2018) 15708, https://doi.org/10.1021/acssuschemeng.8b04227. doi: 10.1021/acssuschemeng.8b04227
57. [57]
  C. X. Fan, Y. D. Tian, S. Y. Bai, C. Y. Zhang, X. L. Wu, J. Energy Storage 44 (2021) 103492, https://doi.org/10.1016/j.est.2021.103492. doi: 10.1016/j.est.2021.103492
58. [58]
  Y. Q. Wang, M. C. Zhang, W. Xu, X. Y. Shen, F. Gao, J. L. Zhu, X. Wan, X. J. Lian, J. G. Xu, Y. Tong, Acta Phys. -Chim. Sin. 38 (2022) 1907076, https://doi.org/10.3866/PKU.WHXB202211025. doi: 10.3866/PKU.WHXB202211025
59. [59]
  Y. Liu, L. Liu, J. Shan, J. D. Zhang, J. Hazard. Mater. 290 (2015) 1, https://doi.org/10.1016/j.jhazmat.2015.02.016. doi: 10.1016/j.jhazmat.2015.02.016
60. [60]
  J. J. Li, H. Wang, L. Wang, C. Ma, C. Luan, B. Zhao, Z. R. Zhang, H. W. Zhang, X. W. Cheng, J. L. Liu, Catalysts 8 (2018) 378, https://doi.org/10.3390/catal8090378. doi: 10.3390/catal8090378
61. [61]
  K. Yang, Q. Sun, F. Xue, D. H. Lin, J. Hazard. Mater. 195 (2011) 124, https://doi.org/10.1016/j.jhazmat.2011.08.020. doi: 10.1016/j.jhazmat.2011.08.020
62. [62]
  K. X. Jiang, X. L. Shi, M. Chen, X. S. Lv, H. F. Gong, Y. Shen, P. Wang, F. Dong, M. Liu, X. M. Zhang, G. M. Jiang, J. Hazard. Mater. 411 (2021) 125119, https://doi.org//10.1016/j.jhazmat.2021.125119. doi: 10.1016/j.jhazmat.2021.125119
63. [63]
  G. L. Li, Y. Liu, Y. Shen, Q. L. Fang, F. Liu, Front. Chem. Eng. 3 (2021) 636439, https://doi.org/10.3389/fceng.2021.636439. doi: 10.3389/fceng.2021.636439
64. [64]
  Y. Shen, Y. W. Tong, J. L. Xu, S. B. Wang, J. Wang, T. Zeng, Z. Q. He, W. Q. Yang, S. Song, Appl. Catal. B-Environ. 264 (2020) 118505, https://doi.org/10.1016/j.apcatb.2019.118505. doi: 10.1016/j.apcatb.2019.118505
65. [65]
  C. C. Chen, L. J. Jin, H. L. Dong, J. Jiang, H. Feng, D. Y. Chen, N. J. Li, Q. F. Xu, J. M. Lu, Sep. Purif. Technol. 324 (2023) 124527, https://doi.org/10.1016/j.seppur.2023.124527. doi: 10.1016/j.seppur.2023.124527
66. [66]
  G. P. Lei, D. K. Chen, Q. B. Li, H. T. Liu, Q. Shi, C. Li, Electrochim. Acta 413 (2022) 140143, https://doi.org/10.1016/j.electacta.2022.140143. doi: 10.1016/j.electacta.2022.140143
67. [67]
  K. Y. Li, D. Guo, J. Y. Kang, B. Wei, X. T. Zhang, Y. J. Chen, ACS Sustainable Chem. Eng. 6 (2018) 14641, https://doi.org/10.1021/acssuschemeng.8b03232. doi: 10.1021/acssuschemeng.8b03232
68. [68]
  C. Hu, C. Lv, S. Liu, Y. Shi, J. F. Song, Z. Zhang, J. G. Cai, A. Watanabe, Catalysis 10 (2020) 188, https://doi.org/10.3390/catal10020188. doi: 10.3390/catal10020188
69. [69]
  H. B. Yu, M. Y. Wang, X. H. Wang, Mater. Res. Bull. 172 (2024) 112655, https://doi.org/10.1016/j.materresbull.2023.112655. doi: 10.1016/j.materresbull.2023.112655
70. [70]
  Z. Qiu, Y. Ma, T. Edvinsson, Nano Energy 66 (2019) 104118, https://doi.org/10.1016/j.nanoen.2019.104118. doi: 10.1016/j.nanoen.2019.104118
71. [71]
  Q. X. Liu, Y. T. Shen, S. Song, Z. Q. He, RSC Adv. 66 (2019) 104118, https://doi.org/10.1039/C9RA01843C. doi: 10.1039/C9RA01843C
72. [72]
  J. Zhao, R. Urrego-Ortiz, N. Liao, F. Calle-Vallejo, J. Luo, Nat. Commun. 15 (2024) 6391, https://doi.org/10.1038/s41467-024-50691-5. doi: 10.1038/s41467-024-50691-5
73. [73]
  F. F. Liu, X. Yang, D. Dang, X. L. Tian, ChemElectroChem 6 (2019) 2208, https://doi.org/10.1002/celc.201900252. doi: 10.1002/celc.201900252
74. [74]
  C. X. Guo, Y. Jiao, Y. Zheng, J. Luo, K. Davey, S. -Z. Qiao, Chem 5 (2019) 2429, https://doi.org/10.1016/j.chempr.2019.06.016. doi: 10.1016/j.chempr.2019.06.016
75. [75]
  M. J. Wang, Y. Xu, C. K. Peng, S. Y. Chen, Y. G. Lin, Z. W. Hu, L. Sun, S. Y. Ding, C. W. Pao, Q. Shao, X. Q. Huang, J. Am. Chem. Soc. 143 (2021) 16512, https://doi.org/10.1021/jacs.1c06006. doi: 10.1021/jacs.1c06006
76. [76]
  Z. M. Lou, C. C. Yu, X. F. Wen, Y. H. Xu, J. M. Yu, X. H. Xu, Appl. Catal. B-Environ. 317 (2022) 121730, https://doi.org/10.1016/j.apcatb.2022.121730. doi: 10.1016/j.apcatb.2022.121730
77. [77]
  F. Gao, Y. P. Zhang, P. P. Song, J. Wang, C. Q. Wang, J. Guo, Y. K. Du, J. Power Sources 418 (2019) 186, https://doi.org/10.1016/j.jpowsour.2019.02.031. doi: 10.1016/j.jpowsour.2019.02.031
78. [78]
  Y. P. Zhang, F. Gao, P. P. Song, J. Wang, J. Guo, Y. Shiraishi, Y. K. Du, ACS Sustainable Chem. Eng. 7 (2019) 3176, https://doi.org/10.1021/acssuschemeng.8b05020. doi: 10.1021/acssuschemeng.8b05020
79. [79]
  Z. Y. Xu, X. Tan, C. Chen, X. D. Wang, R. Sui, Z. B. Zhuang, C. Zhang, C. Chen, Natl. Sci. Rev. 11 (2024) nwae315, https://doi.org/10.1093/nsr/nwae315. doi: 10.1093/nsr/nwae315
80. [80]
  G. M. Jiang, X. L. Shi, M. Y. Cui, W. L. Wang, P. Wang, G. Johnson, Y. D. Nie, X. S. Lv, X. M. Zhang, F. Dong, S. Zhang, ACS Appl. Mater. Interfaces 13 (2021) 4072, https://doi.org/10.1021/acsami.0c20994. doi: 10.1021/acsami.0c20994
81. [81]
  Z. M. Fan, H. C. Zhao, K. F. Wang, W. Ran, J. F. Sun, J. F. Liu, R. Liu, Environ. Sci. Technol. 57 (2023) 1499, https://doi.org/10.1021/acs.est.2c07462. doi: 10.1021/acs.est.2c07462
82. [82]
  X. F. Cheng, Q. Cao, Q. Liu, H. Y. Zhang, Q. F. Xu, J. M. Lu, Chin. J. Chem. 42 (2024) 2445, https://doi.org/10.1002/cjoc.202400293. doi: 10.1002/cjoc.202400293
83. [83]
  J. J. Li, K. Z. Kong, Y. T. Chong, J. Ding, L. Wang, Z. C. Ba, J. Zhang, Sep. Purif. Technol. 323 (2023) 124452, https://doi.org/10.1016/j.seppur.2023.124452. doi: 10.1016/j.seppur.2023.124452
84. [84]
  Q. H. Zhao, C. C. Chen, J. H. Fu, Y. P. Zhang, J. Y. Huo, H. B. Zeng, Q. F. Xu, J. M. Lu, Sep. Purif. Technol. 351 (2024) 128040, https://doi.org/10.1016/j.seppur.2024.128040. doi: 10.1016/j.seppur.2024.128040
85. [85]
  W. T. Yu, H. Jiang, J. H. Fang, S. Song, Environ. Sci. Technol. 55 (2021) 10087, https://doi.org/10.1021/acs.est.1c01922. doi: 10.1021/acs.est.1c01922
86. [86]
  T. Li, Z. Y. Kong, M. M. Liu, Y. Y. Sun, L. P. Diao, P. Lu, D. H. Li, D. J. Yang, Appl. Catal. B-Environ. 351 (2024) 123968, https://doi.org/10.1016/j.apcatb.2024.123968. doi: 10.1016/j.apcatb.2024.123968
87. [87]
  Z. M. Lou, Y. Z. Li, J. S. Zhou, K. L. Yang, Y. L. Liu, S. A. Baig, X. H. Xu, J. Hazard. Mater. 362 (2019) 148, https://doi.org/10.1016/j.jhazmat.2018.08.066. doi: 10.1016/j.jhazmat.2018.08.066
88. [88]
  S. Shu, X. Y. Tang, C. C. Huang, Y. N. Liu, J. J. Li, Ind. Eng. Chem. Res. 63 (2024), 7114, https://doi.org/10.1021/acs.iecr.3c04493. doi: 10.1021/acs.iecr.3c04493
89. [89]
  J. Li, C. Feng, C. Chen, Y. Pan, Y. J. Liu, Environ. Sci. 149 (2025) 288, https://doi.org/10.1016/j.jes.2024.01.053. doi: 10.1016/j.jes.2024.01.053
90. [90]
  Y. F. Wu, L. Gan, S. P. Zhang, H. O. Song, C. Lu, W. T. Li, Z. Wang, B. C. Jiang, A. J. Li, J. Hazard. Mater. 356 (2018) 17, https://doi.org/10.1016/j.jhazmat.2018.05.034. doi: 10.1016/j.jhazmat.2018.05.034
91. [91]
  Y. L. Chen, L. Xiong, X. N. Song, W. K. Wang, Y. X. Huang, H. Q. Yu, Chemosphere 125 (2015) 57, https://doi.org/10.1016/j.chemosphere.2015.01.052. doi: 10.1016/j.chemosphere.2015.01.052
92. [92]
  L. Y. Liu, M. H. Cui, J. J. Ambuchi, S. M. Niu, X. H. Li, W. L. Wang, H. Liu, G. S. Liu, A. J. Wang, Environ. Res. 252 (2024) 118859, https://doi.org/10.1016/j.envres.2024.118859. doi: 10.1016/j.envres.2024.118859
93. [93]
  X. Z. Song, Q. Shi, H. Wang, S. L. Liu, C. Tai, Z. Y. Bian, Appl. Catal. B-Environ. 20 (2017) 442, https://doi.org/10.1016/j.apcatb.2016.10.036. doi: 10.1016/j.apcatb.2016.10.036
94. [94]
  N. Li, X. Song, L. Wang, X. Geng, H. Wang, H. Tang, Z. Y. Bian, ACS Appl. Mater. Interfaces 12 (2020) 24019, https://doi.org/10.1021/acsami.0c05159. doi: 10.1021/acsami.0c05159
95. [95]
  J. L. Xie, Y. X. Li, X. Yan, Z. H. Yu, H. Chen, F. Jiang, Appl. Mater. Interfaces 16 (2024) 44817, https://doi.org/10.1021/acsami.4c08043. doi: 10.1021/acsami.4c08043
96. [96]
  P. Rugira, S. Pan, Z. M. Liang, R. Boutaleb, W. Q. Huang, N. B. Ullah, X. Zhao, C. Wang, Sep. Purif. Technol. 361 (2025) 131573, https://doi.org/10.1016/j.seppur.2025.131573. doi: 10.1016/j.seppur.2025.131573
97. [97]
  Y. Pan, C. Zhang, Y. Lin, Z. Liu, M. M. Wang, C. Chen, Sci. China Mater. 63 (2020) 921, https://doi.org/10.1007/s40843-019-1242-1. doi: 10.1007/s40843-019-1242-1
98. [98]
  X. Zhao, D. Luo, Y. Wang, Z. -H. Liu, Nano Res. 12 (2019) 2872, https://doi.org/10.1007/s12274-019-2529-y. doi: 10.1007/s12274-019-2529-y
99. [99]
  J. J. Li, K. Z. Kong, S. M. Ma, J. Ding, L. Wang, J. Crittenden, Appl. Catal. B-Environ. 356 (2024) 124245, https://doi.org/10.1016/j.apcatb.2024.124245. doi: 10.1016/j.apcatb.2024.124245
100. [100]
  J. J. Li, H. Yu, Y. J. Ding, L. J. Wang, Environ. Chem. Eng. 13 (2025) 115548, https://doi.org/10.1016/j.jece.2025.115548. doi: 10.1016/j.jece.2025.115548
101. [101]
  J. Wang, C. Y. Cui, Y. J. Xin, Q. Z. Zheng, X. Zhang, Electrochim. Acta 296 (2019) 874, https://doi.org/10.1016/j.electacta.2018.11.115. doi: 10.1016/j.electacta.2018.11.115
102. [102]
  S. L. Xu, W. Wang, H. T. Li, Y. X. Gao, Y. Min, P. Liu, X. Zheng, D. -F. Liu, J. J. Chen, H. Q. Yu, X. Zhou, Y. Wu, Adv. Mater. 37 (2025) 2500371, https://doi.org/10.1002/adma.202500371. doi: 10.1002/adma.202500371
103. [103]
  B. Yang, G. Yu, J. Huang, Environ. Sci. Technol. 41 (2007) 7503, https://doi.org/10.1021/es071168o. doi: 10.1021/es071168o
104. [104]
  J. Han, R. L. Deming, F. -M. Tao, J. Phys. Chem. A 108 (2004) 7736, https://doi.org/10.1021/jp047923r. doi: 10.1021/jp047923r
105. [105]
  W. Y. He, S. Y. Yang, K. J. Ye, S. Y. Bai, S. Xu, A. Amrane, M. Zhang, H. Wang, H. Q. Wang, Q. Yuan, X. L. Shi, Chem. Eng. J. 487 (2024) 150460, https://doi.org/10.1016/j.cej.2024.150460. doi: 10.1016/j.cej.2024.150460
106. [106]
  Z. J. Liu, E. A. Betterton, R. G. Arnold, Environ. Sci. Technol. 34 (2000) 804, https://doi.org/10.1021/es991049b. doi: 10.1021/es991049b
107. [107]
  C. Durante, V. Perazzolo, A. A. Isse, M. Favaro, G. Granozzi, A. Gennaro, ChemElectroChem 1 (2014) 1370, https://doi.org/10.1002/celc.201402032. doi: 10.1002/celc.201402032
108. [108]
  X. F. Wei, J. M. Wang, J. Miao, R. C. Zhang, W. W. Lu, N. Zhang, X. Q. Zhou, H. Xu, J. Zhang, S. G. Peng, Colloids Surf. A Physicochem. Eng. Asp. 648 (2022) 129320, https://doi.org/10.1016/j.colsurfa.2022.129320. doi: 10.1016/j.colsurfa.2022.129320
109. [109]
  Z. R. Sun, X. F. Wei, Y. B. Han, S. Tong, X. Hu, J. Hazard. Mater. 244-245 (2013) 287, https://doi.org/10.1016/j.jhazmat.2012.11.017. doi: 10.1016/j.jhazmat.2012.11.017
110. [110]
  S. Shu, W. Y. Fu, P. Wang, W. L. Cen, Y. H. Chu, F. S. Wei, X. M. Zhang, F. Dong, G. M. Jiang, Appl. Catal. A Gen. 583 (2019) 117146, https://doi.org/10.1016/j.apcata.2019.117146. doi: 10.1016/j.apcata.2019.117146
111. [111]
  A. L. Tang, L. M. Wang, R. H. Zhou, Comput. Theor. Chem. 960 (2010) 31, https://doi.org/10.1016/j.theochem.2010.08.021. doi: 10.1016/j.theochem.2010.08.021

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沈阳化工大学材料科学与工程学院沈阳 110142

电催化氯代芳香烃脱氯催化剂的合成策略、应用与挑战

通讯作者: 马媛媛, mayy334@hebtu.edu.cn; 都京, duj622@hebtu.edu.cn; 韩占刚, hanzg116@hebtu.edu.cn

English

Catalysts for electrocatalytic dechlorination of chlorinated aromatic hydrocarbons: synthetic strategies, applications, and challenges

Corresponding author: Email: mayy334@hebtu.edu.cn (Y. Ma); Email: duj622@hebtu.edu.cn (J. Du); Email: hanzg116@hebtu.edu.cn (Z. Han)

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

电催化氯代芳香烃脱氯催化剂的合成策略、应用与挑战

通讯作者: 马媛媛, mayy334@hebtu.edu.cn; 都京, duj622@hebtu.edu.cn; 韩占刚, hanzg116@hebtu.edu.cn

English

Catalysts for electrocatalytic dechlorination of chlorinated aromatic hydrocarbons: synthetic strategies, applications, and challenges

Corresponding author: Email: mayy334@hebtu.edu.cn (Y. Ma); Email: duj622@hebtu.edu.cn (J. Du); Email: hanzg116@hebtu.edu.cn (Z. Han)

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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