电容去离子提锂技术中电极材料的研究进展

引用本文: 陈泽秋, 蔡黎淼, 关杰, 李瞻洋, 王昊, 郭耀广, 徐兴涛, 潘丽坤. 电容去离子提锂技术中电极材料的研究进展[J]. 物理化学学报, 2025, 41(8): 100089. doi: 10.1016/j.actphy.2025.100089 shu

Citation: Zeqiu Chen, Limiao Cai, Jie Guan, Zhanyang Li, Hao Wang, Yaoguang Guo, Xingtao Xu, Likun Pan. Advanced electrode materials in capacitive deionization for efficient lithium extraction[J]. Acta Physico-Chimica Sinica, 2025, 41(8): 100089. doi: 10.1016/j.actphy.2025.100089 shu

电容去离子提锂技术中电极材料的研究进展

陈泽秋 ^{1, †,} ,
蔡黎淼 ^{1, †,} ,
关杰 ^1, ,
李瞻洋 ^1, ,
王昊 ^2, ,
郭耀广 ^{1,
,} ,
徐兴涛 ^{3,
,} ,
潘丽坤 ^{2, 4,
,}

1.
上海第二工业大学资源与环境工程学院, 上海电子废弃物回收协同创新中心, 上海 201209
2.
华东师范大学物理与电子科学学院, 上海磁共振重点实验室, 上海 200241
3.
浙江海洋大学海洋科技学院, 浙江舟山 316022
4.
华东师范大学医学磁共振与分子影像技术研究院, 上海 200241

通讯作者: 郭耀广, ygguo@sspu.edu.cn; 徐兴涛, xingtao.xu@zjou.edu.cn; 潘丽坤, lkpan@phy.ecnu.edu.cn

基金项目:
国家自然科学基金 52400174

国家自然科学基金 52270129

国家自然科学基金 52370142

上海扬帆计划 24YF2714000

东方英才青年计划及上海曙光计划 23SG52

摘要: 随着新能源领域对锂资源需求的持续增长，开发高效的锂提取技术变得及其重要。然而，由于其高能耗和可能引发的二次污染问题，传统的锂提取和回收技术具有实际应用和发展的局限性。电容去离子(CDI)技术作为一种新兴的锂提取技术，在效率、成本效益和能源消耗方面展现出巨大的潜力。本综述从文献计量入手，剖析了CDI提锂的关键研究主题，进而全面总结了在CDI提锂技术中电极材料的最新进展，并探讨了使用这些材料构建的各种CDI系统类型。本研究详细阐明了CDI系统中用于锂资源回收的主要电极材料——水系锂离子电极材料(包括LiFePO₄、LiMn₂O₄、LiNi_1/3Co_1/3Mn_1/3O₂等)及其修饰材料(包括碳纳米管、石墨烯、MOF等)。此外，本文讨论了通过不同的电容去离子(CDI)系统提高锂提取效率，并评估了各种先进电极材料在这些系统中的性能。文末强调了机器学习在CDI提锂领域的应用潜力，并期望本研究将为未来开发基于CDI的高效锂提取系统提供坚实的理论基础和实践指导。

关键词:

English

Advanced electrode materials in capacitive deionization for efficient lithium extraction

Zeqiu Chen ^{1, †,} ,
Limiao Cai ^{1, †,} ,
Jie Guan ^1, ,
Zhanyang Li ^1, ,
Hao Wang ^2, ,
Yaoguang Guo ^{1,
,} ,
Xingtao Xu ^{3,
,} ,
Likun Pan ^{2, 4,
,}

1.
Shanghai Collaborative Innovation Centre for WEEE Recycling, School of Resources and Environmental Engineering, Shanghai Polytechnic University, Shanghai 201209, China
2.
Shanghai Key Laboratory of Magnetic Resonance, School of Physics and Electronic Science, East China Normal University, Shanghai 200241, China
3.
Marine Science and Technology College, Zhejiang Ocean University, Zhoushan 316022, Zhejiang Province, China
4.
Institute of Magnetic Resonance and Molecular Imaging in Medicine, East China Normal University, Shanghai 200241, China

Corresponding author: Email: ygguo@sspu.edu.cn (Y.G. Guo); Email: xingtao.xu@zjou.edu.cn (X.T. Xu); Email: lkpan@phy.ecnu.edu.cn (L.K. Pan)

Received Date: 17 January 2025
Accepted Date: 07 April 2025
Revised Date: 03 April 2025
Available Online: 15 August 2025
Fund Project:
the National Natural Science Foundation of China

the National Natural Science Foundation of China

the National Natural Science Foundation of China

Shanghai Sailing Program

Oriental Talent Youth Program, and Shanghai Shuguang Program
^†These authors contributed equally to this work.

Abstract: Efficient technologies for lithium extraction are progressively pivotal in response to the growing requirement for lithium in new energy applications. However, due to its high energy consumption and possible secondary pollution problems, traditional lithium absorption and recovery technologies, are limited in practical application and development. Capacitive deionization (CDI) demonstrates significant potential for lithium extraction with regard to efficiency, cost-effectiveness, and energy consumption. This review commences with bibliometric analysis to dissect the key research topics of lithium extraction via CDI, and presents a complete synopsis of recent advances in electrode materials for lithium extraction using CDI technology, along with various types of CDI systems that utilize these materials. This study elucidates in detail the main electrode materials used in CDI systems for lithium resource recovery——aqueous lithium ion electrode materials (including LiFePO₄, LiMn₂O₄, LiNi_1/3Co_1/3Mn_1/3O₂) and their modification materials (including carbon nanotubes, graphene, MOFs). In addition, this paper discusses the improvement of lithium extraction efficiency through different CDI systems and evaluates the capability of various advanced electrode materials in these systems. The end of the paper emphasizes the application potential of machine learning in the domain of lithium extraction via CDI. The study is anticipated to deliver a strong theoretical basis and practical recommendations for advancing efficient lithium extraction systems that utilize CDI.

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沈阳化工大学材料科学与工程学院沈阳 110142

电容去离子提锂技术中电极材料的研究进展

通讯作者: 郭耀广, ygguo@sspu.edu.cn; 徐兴涛, xingtao.xu@zjou.edu.cn; 潘丽坤, lkpan@phy.ecnu.edu.cn

English

Advanced electrode materials in capacitive deionization for efficient lithium extraction

Corresponding author: Email: ygguo@sspu.edu.cn (Y.G. Guo); Email: xingtao.xu@zjou.edu.cn (X.T. Xu); Email: lkpan@phy.ecnu.edu.cn (L.K. Pan)

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

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中国化学会秘书处

电容去离子提锂技术中电极材料的研究进展

通讯作者: 郭耀广, ygguo@sspu.edu.cn; 徐兴涛, xingtao.xu@zjou.edu.cn; 潘丽坤, lkpan@phy.ecnu.edu.cn

English

Advanced electrode materials in capacitive deionization for efficient lithium extraction

Corresponding author: Email: ygguo@sspu.edu.cn (Y.G. Guo); Email: xingtao.xu@zjou.edu.cn (X.T. Xu); Email: lkpan@phy.ecnu.edu.cn (L.K. Pan)

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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