Citation: Yu Peng, Jiawei Chen, Yue Yin, Yongjie Cao, Mochou Liao, Congxiao Wang, Xiaoli Dong, Yongyao Xia. Tailored cathode electrolyte interphase via ethylene carbonate-free electrolytes enabling stable and wide-temperature operation of high-voltage LiCoO₂[J]. Acta Physico-Chimica Sinica, ;2025, 41(8): 100087. doi: 10.1016/j.actphy.2025.100087 shu

Tailored cathode electrolyte interphase via ethylene carbonate-free electrolytes enabling stable and wide-temperature operation of high-voltage LiCoO₂

Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Institute of New Energy, iChEM (Collaborative Innovation Center of Chemistry for Energy Materials), Fudan University, Shanghai 200433, China

Corresponding author: Xiaoli Dong, xldong@fudan.edu.cn Yongyao Xia, yyxia@fudan.edu.cn
Received Date: 19 February 2025
Revised Date: 18 March 2025
Accepted Date: 2 April 2025

Fund Project: the National Natural Science Foundation of China 21935003

Raising the charge cut-off voltage of LiCoO₂ (LCO) cathodes provides a straightforward approach to increasing the energy density of lithium-ion batteries (LIBs). However, when the charge cut-off voltage exceeds 4.55 V (vs. Li/Li⁺), the cathode-electrolyte interphase (CEI) becomes unstable, failing to protect the LCO cathode from severe interfacial side reactions and structural instability. These issues accelerate battery degradation and severely hinder the practical application of high-energy-density LIBs. Moreover, ethylene carbonate (EC)-based electrolytes exhibit more pronounced parasitic reactions than EC-free electrolytes under high voltage, further exacerbating performance limitations. Therefore, optimizing the components and structure of the CEI with EC-free electrolytes remains a challenge. In this work, we aim to construct a robust and chemically stable F-/B-containing CEI on the surface of LCO cathodes using an EC-free electrolyte design. By replacing EC with more anti-oxidative propylene carbonate (PC) and fluoroethylene carbonate (FEC) co-solvents, the oxidative stability of the electrolyte is significantly improved. This promotes the formation of LiF within the CEI, thereby enhancing its mechanical strength. Meanwhile, the introduction of the sacrificial film-forming additive lithium bis(oxalato)borate (LiBOB) facilitates the generation of oxalates (Li₂C₂O₄) and B-containing crosslinked polymers (LiB_xO_y) within the CEI. These components exhibit high electrochemical stability and flexibility, compensating for the limitations of the LiF-rich CEI and further enhancing the overall structural stability of the CEI. This combination results in a rigid-flexible coupling architecture composed of inorganic-rich components (LiF and Li₂C₂O₄) embedded in B-containing crosslinked polymers (LiB_xO_y), ensuring both mechanical integrity and chemical stability of the CEI. Consequently, this tailored CEI effectively mitigates interfacial layer cracking and regeneration, reducing irreversible structural degradation and interfacial side reactions in high-voltage LCO cathodes. Based on these improvements, the EC-free PC-based electrolyte enables superior performance of LCO cathodes at 4.6 V, achieving 82% capacity retention at 0.5C over 200 cycles. Furthermore, graphite||LCO full cells demonstrate enhanced cycling stability at 4.5 V and enable operation across a wide temperature range (−40 to 80 ℃), highlighting the effectiveness of the rigid-flexible coupling CEI derived from the tailored electrolyte. By moving away from conventional EC-based electrolyte formulas, this work provides new insights into designing high-performance, wide-temperature, and sustainable PC-based electrolytes.
- High-voltage electrolyte,
- Ethylene carbonate-free electrolyte,
- Additive,
- Lithium cobalt oxide,
- Cathode electrolyte interphase
1. [1]
  M. Li, J. Lu, Z. Chen, K. Amine, Adv. Mater. 30 (2018) 1800561, https://doi.org/10.1002/adma.201800561. doi: 10.1002/adma.201800561
2. [2]
  L. Wang, B. Chen, J. Ma, G. Cui, L. Chen, Chem. Soc. Rev. 47 (2018) 6505, https://doi.org/10.1039/C8CS00322J. doi: 10.1039/C8CS00322J
3. [3]
  Y. Lyu, X. Wu, K. Wang, Z. Feng, T. Cheng, Y. Liu, M. Wang, R. Chen, L. Xu, J. Zhou, Y. Lu, B. Guo, Adv. Energy Mater. 11 (2021) 2000982, https://doi.org/10.1002/aenm.202000982. doi: 10.1002/aenm.202000982
4. [4]
  C. Lin, J. Li, Z.-W. Yin, W. Huang, Q. Zhao, Q. Weng, Q. Liu, J. Sun, G. Chen, F. Pan, Adv. Mater. 36 (2024) 2307404, https://doi.org/10.1002/adma.202307404. doi: 10.1002/adma.202307404
5. [5]
  B. Chu, Y.-J. Guo, J.-L. Shi, Y.-X. Yin, T. Huang, H. Su, A. Yu, Y.-G. Guo, Y.J. Li, Power Sources. 544 (2022) 231873, https://doi.org/10.1016/j.jpowsour.2022.231873. doi: 10.1016/j.jpowsour.2022.231873
6. [6]
  Y. Kim, G.M. Veith, J. Nanda, R.R. Unocic, M. Chi, N.J. Dudney, Electrochim. Acta 56 (2011) 6573, https://doi.org/10.1016/j.electacta.2011.03.070. doi: 10.1016/j.electacta.2011.03.070
7. [7]
  Z. Sun, J. Zhao, M. Zhu, J. Liu, Adv. Energy Mater. 14 (2024) 2303498, https://doi.org/10.1002/aenm.202303498. doi: 10.1002/aenm.202303498
8. [8]
  Q. Wu, B. Zhang, Y. Lu, J. Energy Chem. 74 (2022) 283, https://doi.org/10.1016/j.jechem.2022.07.007. doi: 10.1016/j.jechem.2022.07.007
9. [9]
  N. Qin, Q. Gan, Z. Zhuang, Y. Wang, Y. Li, Z. Li, I. Hussain, C. Zeng, G. Liu, Y. Bai, K. Zhang, Z. Lu, Adv. Energy Mater. 12 (2022) 2201549, https://doi.org/10.1002/aenm.202201549. doi: 10.1002/aenm.202201549
10. [10]
  Z. Zhuang, J. Wang, K. Jia, G. Ji, J. Ma, Z. Han, Z. Piao, R. Gao, H. Ji, X. Zhong, G. Zhou, H.-M. Cheng, Adv. Mater. 35 (2023) 2212059, https://doi.org/10.1002/adma.202212059. doi: 10.1002/adma.202212059
11. [11]
  Z. Liu, M. Han, S. Zhang, H. Li, X. Wu, Z. Fu, H. Zhang, G. Wang, Y. Zhang, Adv. Mater. 36 (2024) 2404188, https://doi.org/10.1002/adma.202404188. doi: 10.1002/adma.202404188
12. [12]
  T. Fan, Y. Wang, V.K. Harika, A. Nimkar, K. Wang, X. Liu, M. Wang, L. Xu, Y. Elias, H. Sclar, M.S. Chae, Y. Min, Y. Lu, N. Shpigel, D. Aurbach, Adv. Sci. 9 (2022) 2202627, https://doi.org/10.1002/advs.202202627. doi: 10.1002/advs.202202627
13. [13]
  T. Cheng, Z. Ma, R. Qian, Y. Wang, Q. Cheng, Y. Lyu, A. Nie, B. Guo, Adv. Funct. Mater. 8 (2021) 2001974, https://doi.org/10.1002/adfm.202001974. doi: 10.1002/adfm.202001974
14. [14]
  X. Yang, C. Wang, P. Yan, T. Jiao, J. Hao, Y. Jiang, F. Ren, W. Zhang, J. Zheng, Y. Cheng, X. Wang, W. Yang, J. Zhu, S. Pan, M. Lin, L. Zeng, Z. Gong, J. Li, Y. Yang, Adv. Energy Mater. 12 (2022) 2200197, https://doi.org/10.1002/aenm.202200197. doi: 10.1002/aenm.202200197
15. [15]
  C. Yang, X. Liao, X. Zhou, C. Sun, R. Qu, J. Han, Y. Zhao, L. Wang, Y. You, J. Lu, Adv. Mater. 35 (2023) 2210966, https://doi.org/10.1002/adma.202210966. doi: 10.1002/adma.202210966
16. [16]
  Y. Li, W. Li, R. Shimizu, D. Cheng, H. Nguyen, J. Paulsen, S. Kumakura, M. Zhang, Y.S. Meng, Adv. Energy Mater. 12 (2022) 2103033, https://doi.org/10.1002/aenm.202103033. doi: 10.1002/aenm.202103033
17. [17]
  M. Mao, X. Ji, Q. Wang, Z. Lin, M. Li, T. Liu, C. Wang, Y.-S. Hu, H. Li, X. Huang, L. Chen, L. Suo, Nat. Commun. 14 (2023) 1082, https://doi.org/10.1038/s41467-023-36853-x. doi: 10.1038/s41467-023-36853-x
18. [18]
  Y. Qin, K. Xu, Q. Wang, M. Ge, T. Cheng, M. Liu, H. Cheng, Y. Hu, C. Shen, D. Wang, Y. Liu, B. Guo, Nano Energy 96 (2022) 107082, https://doi.org/10.1016/j.nanoen.2022.107082. doi: 10.1016/j.nanoen.2022.107082
19. [19]
  Q. Liu, W. Jiang, J. Xu, Y. Xu, Z. Yang, D.-J. Yoo, K.Z. Pupek, C. Wang, C. Liu, K. Xu, Z. Zhang, Nat. Commun. 14 (2023) 3678, https://doi.org/10.1038/s41467-023-38229-7. doi: 10.1038/s41467-023-38229-7
20. [20]
  J. Liu, M. Wu, X. Li, D. Wu, H. Wang, J. Huang, J. Ma, Adv. Energy Mater. 13 (2023) 2300084, https://doi.org/10.1002/aenm.202300084. doi: 10.1002/aenm.202300084
21. [21]
  B. Zhang, L. Wang, X. Wang, S. Zhou, A. Fu, Y. Yan, Q. Wang, Q. Xie, D. Peng, Y. Qiao, S.-G. Sun, Energy Storage Mater. 53 (2022) 492, https://doi.org/10.1016/j.ensm.2022.09.032. doi: 10.1016/j.ensm.2022.09.032
22. [22]
  Z. Wu, G. Zeng, J. Yin, C.-L. Chiang, Q. Zhang, B. Zhang, J. Chen, Y. Yan, Y. Tang, H. Zhang, S. Zhou, Q. Wang, X. Kuai, Y.-G. Lin, L. Gu, Y. Qiao, S.-G. Sun, ACS Energy Lett. 8 (2023) 4806, https://doi.org/10.1021/acsenergylett.3c01954. doi: 10.1021/acsenergylett.3c01954
23. [23]
  S. Kim, J.-A. Lee, D.G. Lee, J. Son, T.H. Bae, T.K. Lee, N.-S. Choi, ACS Energy Lett. 9 (2024) 262, https://doi.org/10.1021/acsenergylett.3c02534. doi: 10.1021/acsenergylett.3c02534
24. [24]
  J. Xu, Nano-Micro Lett. 14 (2022) 166, https://doi.org/10.1007/s40820-022-00917-2. doi: 10.1007/s40820-022-00917-2
25. [25]
  J.C. Hestenes, L.E. Marbella, ACS Energy Lett. 8 (2023) 4572, https://doi.org/10.1021/acsenergylett.3c01529. doi: 10.1021/acsenergylett.3c01529
26. [26]
  Z. Sun, F. Li, J. Ding, Z. Lin, M. Xu, M. Zhu, J. Liu, ACS Energy Lett. 8 (2023) 2478, https://doi.org/10.1021/acsenergylett.3c00324. doi: 10.1021/acsenergylett.3c00324
27. [27]
  Y. Yamada, J. Wang, S. Ko, E. Watanabe, A. Yamada, Nat. Energy 4 (2019) 269, https://doi.org/10.1038/s41560-019-0336-z. doi: 10.1038/s41560-019-0336-z
28. [28]
  W. Li, A. Dolocan, J. Li, Q. Xie, A. Manthiram, Adv. Energy Mater. 9 (2019) 1901152, https://doi.org/10.1002/aenm.201901152. doi: 10.1002/aenm.201901152
29. [29]
  R. Pan, Z. Cui, M. Yi, Q. Xie, A. Manthiram, Adv. Energy Mater. 12 (2022) 2103806, https://doi.org/10.1002/aenm.202103806. doi: 10.1002/aenm.202103806
30. [30]
  M. Qin, M. Liu, Z. Zeng, Q. Wu, Y. Wu, H. Zhang, S. Lei, S. Cheng, J. Xie, Adv. Energy Mater. 12 (2022) 2201801, https://doi.org/10.1002/aenm.202201801. doi: 10.1002/aenm.202201801
31. [31]
  X. Liu, X. Shen, H. Li, P. Li, L. Luo, H. Fan, X. Feng, W. Chen, X. Ai, H. Yang, Y. Cao, Adv. Energy Mater. 11 (2021) 2003905, https://doi.org/10.1002/aenm.202003905. doi: 10.1002/aenm.202003905
32. [32]
  H. Liang, Z. Ma, Y. Wang, F. Zhao, Z. Cao, L. Cavallo, Q. Li, J. Ming, ACS Nano 17 (2023) 18062, https://doi.org/10.1021/acsnano.3c04790. doi: 10.1021/acsnano.3c04790
33. [33]
  X. Fan, C. Wang, Chem. Soc. Rev. 50 (2021) 10486, https://doi.org/10.1039/D1CS00450F. doi: 10.1039/D1CS00450F
34. [34]
  Z. Li, H. Rao, R. Atwi, B.M. Sivakumar, B. Gwalani, S. Gray, K.S. Han, T.A. Everett, T.A. Ajantiwalay, V. Murugesan, N.N. Rajput, V.G. Pol, Nat. Commun. 14 (2023) 868, https://doi.org/10.1038/s41467-023-36647-1. doi: 10.1038/s41467-023-36647-1
35. [35]
  S. Li, W. Zhang, Q. Wu, L. Fan, X. Wang, X. Wang, Z. Shen, Y. He, Y. Lu, Angew. Chem. Int. Ed. 59 (2020) 14935, https://doi.org/10.1002/anie.202004853. doi: 10.1002/anie.202004853
36. [36]
  D. Wu, C. Zhu, H. Wang, J. Huang, G. Jiang, Y. Yang, G. Yang, D. Tang, J. Ma, Angew. Chem. Int. Ed. 63 (2024) 202315608, https://doi.org/10.1002/anie.202315608. doi: 10.1002/anie.202315608
37. [37]
  R. Wang, B. Weng, A. Mahadevegowda, I. Temprano, H. Wang, Z. He, C. Ducati, Y. Xiao, C.P. Grey, M.F.L. De Volder, Adv. Energy Mater. 14 (2024) 2401097, https://doi.org/10.1002/aenm.202401097. doi: 10.1002/aenm.202401097
38. [38]
  W.M. Dose, W. Li, I. Temprano, C.A. O'Keefe, B.L. Mehdi, ACS Energy Lett. 10 (2022) 3524, https://doi.org/10.1021/acsenergylett.2c01722. doi: 10.1021/acsenergylett.2c01722
39. [39]
  D. Wu, J. He, J. Liu, M. Wu, S. Qi, H. Wang, J. Huang, F. Li, D. Tang, J. Ma, Adv. Energy Mater. 12 (2022) 2200337, https://doi.org/10.1002/aenm.202200337. doi: 10.1002/aenm.202200337
40. [40]
  J. Xu, J. Zhang, T.P. Pollard, Q. Li, S. Tan, S. Hou, H. Wan, F. Chen, H. He, E. Hu, K. Xu, X.-Q. Yang, O. Borodin, C. Wang, Nature 614 (2023) 694, https://doi.org/10.1038/s41586-022-05627-8. doi: 10.1038/s41586-022-05627-8
41. [41]
  P. Bai, X. Ji, J. Zhang, W. Zhang, S. Hou, H. Su, M. Li, T. Deng, L. Cao, S. Liu, X. He, Y. Xu, C. Wang, Angew. Chem. Int. Ed. 61 (2022) e202202731, https://doi.org/10.1002/anie.202202731. doi: 10.1002/anie.202202731
42. [42]
  Q. Li, Y. Wang, X. Wang, X. Sun, J.-N. Zhang, X. Yu, H. Li, ACS Appl. Mater. Interfaces 12 (2020) 2319, https://doi.org/10.1021/acsami.9b16727. doi: 10.1021/acsami.9b16727
43. [43]
  Y. Chen, Q. He, Y. Mo, W. Zhou, Y. Zhao, N. Piao, C. Liu, P. Xiao, H. Liu, B. Li, S. Chen, L. Wang, X. He, L. Xing, J. Liu, Adv. Energy Mater. 12 (2022) 2201631, https://doi.org/10.1002/aenm.202201631. doi: 10.1002/aenm.202201631
44. [44]
  J. Lai, Y. Huang, X. Zeng, T. Zhou, Z. Peng, Z. Li, X. Zhang, K. Ding, C. Xu, Y. Ying, Y.-P. Cai, R. Shang, J. Zhao, Q. Zheng, ACS Energy Lett. 8 (2023) 2241, https://doi.org/10.1021/acsenergylett.3c00504. doi: 10.1021/acsenergylett.3c00504
45. [45]
  M. Qin, Z. Zeng, Q. Wu, F. Ma, Q. Liu, S. Cheng, J. Xie, Adv. Funct. Mater. 34 (2024) 2406357, https://doi.org/10.1002/adfm.202406357. doi: 10.1002/adfm.202406357
46. [46]
  Y. Wang, Z. Li, Y. Hou, Z. Hao, Q. Zhang, Y. Ni, Y. Lu, Z. Yan, K. Zhang, Q. Zhao, F. Li, J. Chen, Chem. Soc. Rev. 52 (2023) 2713, https://doi.org/10.1039/D2CS00873D. doi: 10.1039/D2CS00873D
47. [47]
  D.Y. Wang, N.N. Sinha, J.C. Burns, R. Petibon, J.R. Dahn, J. Power Sources 270 (2014) 68, https://doi.org/10.1016/j.jpowsour.2014.07.053. doi: 10.1016/j.jpowsour.2014.07.053
48. [48]
  K. Guo, C. Zhu, H. Wang, S. Qi, J. Huang, D. Wu, J. Ma, Adv. Energy Mater. 13 (2023) 2204272, https://doi.org/10.1002/aenm.202204272. doi: 10.1002/aenm.202204272
49. [49]
  S. Kim, S.O. Park, M.-Y. Lee, J.-A. Lee, I. Kristanto, T.K. Lee, D. Hwang, J. Kim, T.- U. Wi, H.-W. Lee, S.K. Kwak, N.-S. Choi, Energy Storage Mater. 45 (2022) 1, https://doi.org/10.1016/j.ensm.2021.10.031. doi: 10.1016/j.ensm.2021.10.031
50. [50]
  E.W.C. Spotte-Smith, T.B. Petrocelli, H.D. Patel, S.M. Blau, K.A. Persson, ACS Energy Lett. 8 (2023) 347, https://doi.org/10.1021/acsenergylett.2c02351. doi: 10.1021/acsenergylett.2c02351
51. [51]
  Z. Piao, R. Gao, Y. Liu, G. Zhou, H.-M. Cheng, Adv. Mater. 35 (2023) 2206009, https://doi.org/10.1002/adma.202206009. doi: 10.1002/adma.202206009
52. [52]
  S. Li, J. Li, P. Wang, H. Ding, J. Zhou, C. Li, X. Cui, Adv. Funct. Mater. 34 (2024) 2307180, https://doi.org/10.1002/adfm.202307180. doi: 10.1002/adfm.202307180
53. [53]
  Y. Yang, H. Wang, C. Zhu, J. Ma, Angew. Chem. Int. Ed. 62 (2023) e202300057, https://doi.org/10.1002/anie.202300057. doi: 10.1002/anie.202300057
54. [54]
  J. Zhang, P. Wang, P. Bai, H. Wan, S. Liu, S. Hou, X. Pu, J. Xia, W. Zhang, Z. Wang, B. Nan, X. Zhang, J. Xu, C. Wang, Adv. Mater. 34 (2022) 2108353, https://doi.org/10.1002/adma.202108353. doi: 10.1002/adma.202108353
1. [1]
  Hao Chen , Dongyue Yang , Gang Huang , Xinbo Zhang . Progress on Liquid Organic Electrolytes of Li-O₂ Batteries. Acta Physico-Chimica Sinica, 2024, 40(7): 2305059-0. doi: 10.3866/PKU.WHXB202305059
2. [2]
  Jiahe LIU , Gan TANG , Kai CHEN , Mingda ZHANG . Effect of low-temperature electrolyte additives on low-temperature performance of lithium cobaltate batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 719-728. doi: 10.11862/CJIC.20250023
3. [3]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 2408007-0. doi: 10.3866/PKU.WHXB202408007
4. [4]
  Zhuo Han , Danfeng Zhang , Haixian Wang , Guorui Zheng , Ming Liu , Yanbing He . Research Progress and Prospect on Electrolyte Additives for Interface Reconstruction of Long-Life Ni-Rich Lithium Batteries. Acta Physico-Chimica Sinica, 2024, 40(9): 2307034-0. doi: 10.3866/PKU.WHXB202307034
5. [5]
  Jiandong Liu , Xin Li , Daxiong Wu , Huaping Wang , Junda Huang , Jianmin Ma . Anion-Acceptor Electrolyte Additive Strategy for Optimizing Electrolyte Solvation Characteristics and Electrode Electrolyte Interphases for Li||NCM811 Battery. Acta Physico-Chimica Sinica, 2024, 40(6): 2306039-0. doi: 10.3866/PKU.WHXB202306039
6. [6]
  Qianli Ma , Tianbing Song , Tianle He , Xirong Zhang , Huanming Xiong . Sulfur-doped carbon dots: a novel bifunctional electrolyte additive for high-performance aqueous zinc-ion batteries. Acta Physico-Chimica Sinica, 2025, 41(9): 100106-0. doi: 10.1016/j.actphy.2025.100106
7. [7]
  Jiandong Liu , Zhijia Zhang , Kamenskii Mikhail , Volkov Filipp , Eliseeva Svetlana , Jianmin Ma . Research Progress on Cathode Electrolyte Interphase in High-Voltage Lithium Batteries. Acta Physico-Chimica Sinica, 2025, 41(2): 2308048-0. doi: 10.3866/PKU.WHXB202308048
8. [8]
  Zhi Dou , Huiyu Duan , Yixi Lin , Yinghui Xia , Mingbo Zheng , Zhenming Xu . High-Throughput Screening Lithium Alloy Phases and Investigation of Ion Transport for Solid Electrolyte Interphase Layer. Acta Physico-Chimica Sinica, 2024, 40(3): 2305039-0. doi: 10.3866/PKU.WHXB202305039
9. [9]
  Changsheng An , Tao Liu . Decoding SEI chemistry at the lithium-metal potential. Acta Physico-Chimica Sinica, 2025, 41(9): 100101-0. doi: 10.1016/j.actphy.2025.100101
10. [10]
  Da Wang , Xiaobin Yin , Jianfang Wu , Yaqiao Luo , Siqi Shi . All-Solid-State Lithium Cathode/Electrolyte Interfacial Resistance: From Space-Charge Layer Model to Characterization and Simulation. Acta Physico-Chimica Sinica, 2024, 40(7): 2307029-0. doi: 10.3866/PKU.WHXB202307029
11. [11]
  Feiya Cao , Qixin Wang , Pu Li , Zhirong Xing , Ziyu Song , Heng Zhang , Zhibin Zhou , Wenfang Feng . Magnesium-Ion Conducting Electrolyte Based on Grignard Reaction: Synthesis and Properties. University Chemistry, 2024, 39(3): 359-368. doi: 10.3866/PKU.DXHX202308094
12. [12]
  Rui Yang , Hui Li , Qingfei Meng , Wenjie Li , Jiliang Wu , Yongjin Fang , Chi Huang , Yuliang Cao . Influence of PC-based Electrolyte on High-Rate Performance in Li/CrO_x Primary Battery. Acta Physico-Chimica Sinica, 2024, 40(9): 2308053-0. doi: 10.3866/PKU.WHXB202308053
13. [13]
  Xiting Zhou , Zhipeng Han , Xinlei Zhang , Shixuan Zhu , Cheng Che , Liang Xu , Zhenyu Sun , Leiduan Hao , Zhiyu Yang . Dual Modulation via Ag-Doped CuO Catalyst and Iodide-Containing Electrolyte for Enhanced Electrocatalytic CO₂ Reduction to Multi-Carbon Products: A Comprehensive Chemistry Experiment. University Chemistry, 2025, 40(7): 336-344. doi: 10.12461/PKU.DXHX202412070
14. [14]
  Yajie Li , Bin Chen , Yiping Wang , Hui Xing , Wei Zhao , Geng Zhang , Siqi Shi . Inhibiting Dendrite Growth by Customizing Electrolyte or Separator to Achieve Anisotropic Lithium-Ion Transport: A Phase-Field Study. Acta Physico-Chimica Sinica, 2024, 40(3): 2305053-0. doi: 10.3866/PKU.WHXB202305053
15. [15]
  Zhaoxuan ZHU , Lixin WANG , Xiaoning TANG , Long LI , Yan SHI , Jiaojing SHAO . Application of poly(vinyl alcohol) conductive hydrogel electrolytes in zinc ion batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 893-902. doi: 10.11862/CJIC.20240368
16. [16]
  Mingyang Men , Jinghua Wu , Gaozhan Liu , Jing Zhang , Nini Zhang , Xiayin Yao . Sulfide Solid Electrolyte Synthesized by Liquid Phase Approach and Application in All-Solid-State Lithium Batteries. Acta Physico-Chimica Sinica, 2025, 41(1): 100004-0. doi: 10.3866/PKU.WHXB202309019
17. [17]
  Hanmei Lü , Xin Chen , Qifu Sun , Ning Zhao , Xiangxin Guo . Uniform Garnet Nanoparticle Dispersion in Composite Polymer Electrolytes. Acta Physico-Chimica Sinica, 2024, 40(3): 2305016-0. doi: 10.3866/PKU.WHXB202305016
18. [18]
  Xin Feng , Kexin Guo , Chunguang Jia , Bowen Liu , Suqin Ci , Junxiang Chen , Zhenhai Wen . Hydrogen Generation Coupling with High-Selectivity Electrocatalytic Glycerol Valorization into Formate in an Acid-Alkali Dual-Electrolyte Flow Electrolyzer. Acta Physico-Chimica Sinica, 2024, 40(5): 2303050-0. doi: 10.3866/PKU.WHXB202303050
19. [19]
  Xinran Zhang , Siqi Liu , Yichi Chen , Qingli Zou , Qinghong Xu , Yaqin Huang . From Protein to Energy Storage Materials: Edible Gelatin Jelly Electrolyte. University Chemistry, 2025, 40(7): 255-266. doi: 10.12461/PKU.DXHX202408104
20. [20]
  Ke Qiu , Fengmei Wang , Mochou Liao , Kerun Zhu , Jiawei Chen , Wei Zhang , Yongyao Xia , Xiaoli Dong , Fei Wang . A Fumed SiO₂-based Composite Hydrogel Polymer Electrolyte for Near-Neutral Zinc-Air Batteries. Acta Physico-Chimica Sinica, 2024, 40(3): 2304036-0. doi: 10.3866/PKU.WHXB202304036

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(73)
HTML views(12)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Tailored cathode electrolyte interphase via ethylene carbonate-free electrolytes enabling stable and wide-temperature operation of high-voltage LiCoO2

Metrics

通讯作者: 陈斌, bchen63@163.com

Tailored cathode electrolyte interphase via ethylene carbonate-free electrolytes enabling stable and wide-temperature operation of high-voltage LiCoO₂