Citation: Jiajie Cai, Chang Cheng, Bowen Liu, Jianjun Zhang, Chuanjia Jiang, Bei Cheng. CdS/DBTSO-BDTO S-scheme photocatalyst for H₂ production and its charge transfer dynamics[J]. Acta Physico-Chimica Sinica, ;2025, 41(8): 100084. doi: 10.1016/j.actphy.2025.100084 shu

CdS/DBTSO-BDTO S-scheme photocatalyst for H₂ production and its charge transfer dynamics

Jiajie Cai ¹ ,
Chang Cheng ² ,
Bowen Liu ¹ ,
Jianjun Zhang ^2,, ,
Chuanjia Jiang ^3,, ,
Bei Cheng ^1,,

1.
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, Hubei Province, China
2.
Laboratory of Solar Fuel, Faculty of Materials Science and Chemistry, China University of Geosciences, Wuhan 430078, Hubei Province, China
3.
College of Environmental Science and Engineering, Nankai University, Tianjin 300350, China

Corresponding author: Jianjun Zhang, zhangjianjun@cug.edu.cn Chuanjia Jiang, jiangcj@nankai.edu.cn Bei Cheng, chengbei2013@whut.edu.cn
Received Date: 20 February 2025
Revised Date: 10 March 2025
Accepted Date: 24 March 2025

Fund Project: the National Key Research and Development Program of China 2022YFB3803600the National Natural Science Foundation of China 22238009the National Natural Science Foundation of China 22361142704the National Natural Science Foundation of China 22261142666the National Natural Science Foundation of China 22278324the National Natural Science Foundation of China 52073223the Natural Science Foundation of Hubei Province of China 2022CFA001the Fundamental Research Funds for the Central Universities 63241632

Photocatalytic hydrogen (H₂) production is a clean energy technology, with great potential for addressing the global energy crisis and related environmental problems. However, single-component photocatalysts often suffer from low efficiency primarily due to fast charge carrier recombination and the tradeoff between light-absorbing capacity and redox capabilities. Constructing heterojunctions provides a promising strategy to overcome these drawbacks, and S-scheme heterojunctions have recently stood out, demonstrating the capability to efficiently facilitate electron/hole separation, while maximizing the redox capability. Among them, polymer-based S-scheme photocatalysts are emerging, though the charge carrier dynamics in inorganic-organic S-scheme heterojunctions remain to be elucidated. Herein, we fabricated an S-scheme heterojunction comprised of the conjugated polymer dibenzothiophene-S, S-dioxide-alt-benzodithiophene (DBTSO-BDTO) and cadmium sulfide (CdS) for photocatalytic H₂ production. The S-scheme mechanism was verified using in situ irradiated X-ray photoelectron spectroscopy, and the charge carrier transfer dynamics were analyzed in depth using femtosecond transient absorption spectroscopy, which revealed that a considerable fraction of electrons undergo interfacial charge transfer in the CdS/DBTSO-BDTO composite. Owing to the improved charge separation efficiency and redox capability, the performance of the composite surpassed that of DBTSO-BDTO and CdS, and the H₂ evolution rate of the optimized CdS/DBTSO-BDTO material reached 3313 μmol·h⁻¹·g⁻¹, three times that of pure CdS. The findings provide new insights into the electron transfer mechanisms of S-scheme heterojunctions, and can guide the design of polymer-based photocatalysts for solar fuel production.
- Photocatalysis,
- Cadmium sulfide,
- S-scheme heterojunction,
- H₂ production,
- Femtosecond transient absorption spectroscopy
1. [1]
  Z.Y. Yu, Y. Duan, X.Y. Feng, X.X. Yu, M.R. Gao, S.H. Yu, Adv. Mater. 33 (2021) 2007100, https://doi.org/10.1002/adma.202007100. doi: 10.1002/adma.202007100
2. [2]
  Y.X. Wu, M.R. Qu, S.J. Jiang, J.J. Zhang, S.Q. Song, Sci. China Mater. 67 (2024) 524, https://doi.org/10.1007/s40843-023-2760-1. doi: 10.1007/s40843-023-2760-1
3. [3]
  B.B. Zhao, W. Zhong, F. Chen, P. Wang, C.B. Bie, H.G. Yu, Chin. J. Catal. 52 (2023) 127, https://doi.org/10.1016/s1872-2067(23)64491-2. doi: 10.1016/s1872-2067(23)64491-2
4. [4]
  H. Nishiyama, T. Yamada, M. Nakabayashi, Y. Maehara, M. Yamaguchi, Y.Kuromiya, Y. Nagatsuma, H. Tokudome, S. Akiyama, T. Watanabe, R. Narushima, S. Okunaka, N. Shibata, T. Takata, T. Hisatomi, K. Domen, Nature 598 (2021) 304, https://doi.org/10.1038/s41586-021-03907-3. doi: 10.1038/s41586-021-03907-3
5. [5]
  P. Zhou, I.A. Navid, Y.J. Ma, Y.X. Xiao, P. Wang, Z.W. Ye, B.W. Zhou, K. Sun, Z.T. Mi, Nature 613 (2023) 66, https://doi.org/10.1038/s41586-022-05399-1. doi: 10.1038/s41586-022-05399-1
6. [6]
  G.T. Sun, Z.G. Tai, J.J. Zhang, B. Cheng, H.G. Yu, J.G. Yu, Appl. Catal. B Environ. 358 (2024) 124459, https://doi.org/10.1016/j.apcatb.2024.124459. doi: 10.1016/j.apcatb.2024.124459
7. [7]
  Z.H. Yu, C. Guan, X.Y. Yue, Q.J. Xiang, Chin. J. Catal. 50 (2023) 361, https://doi.org/10.1016/s1872-2067(23)64448-1. doi: 10.1016/s1872-2067(23)64448-1
8. [8]
  Y.W. Zhu, L.L. Wang, Y.T. Liu, L.H. Shao, X.N. Xia, Appl. Catal. B Environ. 241 (2019) 483, https://doi.org/10.1016/j.apcatb.2018.09.062. doi: 10.1016/j.apcatb.2018.09.062
9. [9]
  S. Cao, B. Zhong, C.B. Bie, B. Cheng, F.Y. Xu, Acta Phys. Chim. Sin. 40 (2024) 2307016, https://doi.org/10.3866/PKU.WHXB202307016. doi: 10.3866/PKU.WHXB202307016
10. [10]
  H.F. Liu, X. Huang, J.Z. Chen, Chin. J. Catal. 51 (2023) 49, https://doi.org/10.1016/s1872-2067(23)64483-3. doi: 10.1016/s1872-2067(23)64483-3
11. [11]
  Q. Li, B.D. Guo, J.G. Yu, J.R. Ran, B.H. Zhang, H.J. Yan, J.R. Gong, J. Am. Chem. Soc. 133 (2011) 10878, https://doi.org/10.1021/ja2025454. doi: 10.1021/ja2025454
12. [12]
  N.Z. Bao, L.M. Shen, T. Takata, K. Domen, Chem. Mater. 20 (2008) 110, https://doi.org/10.1021/cm7029344. doi: 10.1021/cm7029344
13. [13]
  X. Zong, H.J. Yan, G.P. Wu, G.J. Ma, F.Y. Wen, W. Lu, L. Can, J. Am. Chem. Soc. 130 (2008) 7176, doi: 10.1021/ja8007825. doi: 10.1021/ja8007825
14. [14]
  Y.J. Ren, Y.F. Li, G.X. Pan, N. Wang, Y. Xing, Z.Y. Zhang, J. Mater. Sci. Technol. 171 (2024) 162, https://doi.org/10.1016/j.jmst.2023.06.052. doi: 10.1016/j.jmst.2023.06.052
15. [15]
  R.C. Shen, D.D. Ren, Y.N. Ding, Y.T. Guan, Y.H. Ng, P. Zhang, X. Li, Sci. China Mater. 63 (2020) 2153, https://doi.org/10.1007/s40843-020-1456-x. doi: 10.1007/s40843-020-1456-x
16. [16]
  K. Sharma, V. Hasija, M. Malhotra, P.K. Verma, A.A. Parwaz Khan, S. Thakur, Q. Van Le, H.H. Phan Quang, V.-H. Nguyen, P. Singh, P. Raizada, Int. J. Hydrogen Energy 52 (2024) 804, https://doi.org/10.1016/j.ijhydene.2023.09.033. doi: 10.1016/j.ijhydene.2023.09.033
17. [17]
  M.Y. Qi, Q. Lin, Z.R. Tang, Y.J. Xu, Appl. Catal. B Environ. 307 (2022) 121158, https://doi.org/10.1016/j.apcatb.2022.121158. doi: 10.1016/j.apcatb.2022.121158
18. [18]
  Q. Liang, G.Y. Jiang, Z. Zhao, Z.Y. Li, M. MacLachlan, J. Catal. Sci. Technol. 5 (2015) 3368, https://doi.org/10.1039/c5cy00470e. doi: 10.1039/c5cy00470e
19. [19]
  G.T. Sun, J.J. Zhang, B. Cheng, H.G. Yu, J.G. Yu, J.S. Xu, Chem. Eng. J. 476 (2023) 146818, https://doi.org/10.1016/j.cej.2023.146818. doi: 10.1016/j.cej.2023.146818
20. [20]
  L.J. Sun, X.H. Yu, L.Y. Tang, W.K. Wang, Q.Q. Liu, Chin. J. Catal. 52 (2023) 164, https://doi.org/10.1016/s1872-2067(23)64507-3. doi: 10.1016/s1872-2067(23)64507-3
21. [21]
  X.L. Xiang, L.X. Wang, J.J. Zhang, B. Cheng, J.G. Yu, W. Macyk, Adv. Photonics Res. 3 (2022) 2200065, https://doi.org/10.1002/adpr.202200065. doi: 10.1002/adpr.202200065
22. [22]
  X.L. Xiang, L.Y. Zhang, C. Luo, J.J. Zhang, B. Cheng, G.J. Liang, Z.Y. Zhang, J.G. Yu, Appl. Catal. B Environ. 340 (2024) 123196, https://doi.org/10.1016/j.apcatb.2023.123196. doi: 10.1016/j.apcatb.2023.123196
23. [23]
  C. Cheng, B.W. He, J.J. Fan, B. Cheng, S.W. Cao, J.G. Yu, Adv. Mater. 33 (2021) 2100317, https://doi.org/10.1002/adma.202100317. doi: 10.1002/adma.202100317
24. [24]
  X.Y. Deng, J.J. Zhang, K.Z. Qi, G.J. Liang, F.Y. Xu, J.G. Yu, Nat. Commun. 15 (2024) 4807, https://doi.org/10.1038/s41467-024-49004-7. doi: 10.1038/s41467-024-49004-7
25. [25]
  K. Meng, J.J. Zhang, B. Cheng, X.G. Ren, Z.S. Xia, F.Y. Xu, L.Y. Zhang, J.G. Yu, Adv. Mater. 36 (2024) e2406460, https://doi.org/10.1002/adma.202406460. doi: 10.1002/adma.202406460
26. [26]
  M.L. Gu, Y. Yang, B. Cheng, L.Y. Zhang, P. Xiao, T. Chen, Chin. J. Catal. 59 (2024) 185, https://doi.org/10.1016/s1872-2067(23)64610-8. doi: 10.1016/s1872-2067(23)64610-8
27. [27]
  J.W. Fu, Q.L. Xu, J.X. Low, C.J. Jiang, J.G. Yu, Appl. Catal. B Environ. 243 (2019) 556, https://doi.org/10.1016/j.apcatb.2018.11.011. doi: 10.1016/j.apcatb.2018.11.011
28. [28]
  Z. Wang, X. Yue, Q. Xiang, Coord. Chem. Rev. 504 (2024), 125674, doi: 10.1016/j.ccr.2024.215674. doi: 10.1016/j.ccr.2024.215674
29. [29]
  Z. Yu, F. Li, Q. Xiang, J. Mater. Sci. Technol. 175 (2024) 244, https://doi.org/10.1016/j.jmst.2023.08.023. doi: 10.1016/j.jmst.2023.08.023
30. [30]
  S. Wageh, A.A. Al-Ghamdi, O.A. Al-Hartomy, M.F. Alotaibi, L.X. Wang, Chin. J. Catal. 43 (2022) 586, https://doi.org/10.1016/s1872-2067(21)63925-6. doi: 10.1016/s1872-2067(21)63925-6
31. [31]
  X.H. Wu, G.Q. Chen, J. Wang, J.M. Li, G.H. Wang, Acta Phys. Chim. Sin. 39 (2023) 2212016, https://doi.org/10.3866/PKU.WHXB202212016. doi: 10.3866/PKU.WHXB202212016
32. [32]
  Q.L. Xu, R.G. He, Y.J. Li, Acta Phys. Chim. Sin. 39 (2023) 2211009, https://doi.org/10.3866/PKU.WHXB202211009. doi: 10.3866/PKU.WHXB202211009
33. [33]
  C. Cheng, J.J. Zhang, B.C. Zhu, G.J. Liang, L.Y. Zhang, J.G. Yu, Angew. Chem. Int. Ed. 62 (2023) e202218688, https://doi.org/10.1002/anie.202218688. doi: 10.1002/anie.202218688
34. [34]
  J.T. Yan, J.J. Zhang, J. Mater. Sci. Technol. 193 (2024) 18, https://doi.org/10.1016/j.jmst.2023.12.054. doi: 10.1016/j.jmst.2023.12.054
35. [35]
  Y. Wu, C. Cheng, K.Z. Qi, B. Cheng, J.J. Zhang, J.G. Yu, L.Y. Zhang, Acta Phys. Chim. Sin. 40 (2024) 2406027, doi: 10.3866/PKU.WHXB202406027. doi: 10.3866/PKU.WHXB202406027
36. [36]
  C. Cheng, X.C. Wang, F. Wang, Appl. Surf. Sci. 495 (2019) 143537, https://doi.org/10.1016/j.apsusc.2019.143537. doi: 10.1016/j.apsusc.2019.143537
37. [37]
  X.Y. Xiong, Y.R. Jin, H.W. Wang, P. He, X. Xiang, P.C. Hu, K.F. Liu, Q.Q. Wei, B.Z. Wang, Mater. Chem. Phys. 281 (2022) 125824, https://doi.org/10.1016/j.matchemphys.2022.125824. doi: 10.1016/j.matchemphys.2022.125824
38. [38]
  Q. Li, J. Li, W.R. Wang, L.N. Liu, Z.W. Xu, G.H. Xie, J.J. Li, J.H. Yao, W.S. Li, Chin. J. Chem. 40 (2022) 2457, https://doi.org/10.1002/cjoc.202200355. doi: 10.1002/cjoc.202200355
39. [39]
  T. Senasu, K. Hemavibool, S. Nanan, RSC Adv. 8 (2018) 22592, https://doi.org/10.1039/c8ra02061b. doi: 10.1039/c8ra02061b
40. [40]
  Y. Yang, J.S. Wu, B. Cheng, L.Y. Zhang, A.A. Al-Ghamdi, S. Wageh, Y.J. Li, Chin. J. Struct. Chem. 41 (2022) 2206006, https://doi.org/10.14102/j.cnki.0254-5861.2022-0124. doi: 10.14102/j.cnki.0254-5861.2022-0124
41. [41]
  B.W. Liu, J.J. Cai, J.J. Zhang, H.Y. Tan, B. Cheng, J.S. Xu, Chin. J. Catal. 51 (2023) 204, https://doi.org/10.1016/s1872-2067(23)64466-3. doi: 10.1016/s1872-2067(23)64466-3
42. [42]
  M. Thommes, K. Kaneko, A.V. Neimark, J.P. Olivier, F. Rodriguez-Reinoso, J.Rouquerol, K.S.W. Sing, Pure Appl. Chem. 87 (2015) 1051, https://doi.org/10.1515/pac-2014-1117. doi: 10.1515/pac-2014-1117
43. [43]
  L.W. Wang, R.R. Zheng, Q.F. Niu, H.L. Yuan, M. Meng, Mater. Lett. 362 (2024) 136179, https://doi.org/10.1016/j.matlet.2024.136179. doi: 10.1016/j.matlet.2024.136179
44. [44]
  L. Wang, H.H. Zhou, H.Z. Zhang, Y.L. Song, H. Zhang, L.K. Luo, Y.F. Yang, S.Q. Bai, Y. Wang, S.X. Liu, Nanoscale 12 (2020) 13791, https://doi.org/10.1039/d0nr03196h. doi: 10.1039/d0nr03196h
45. [45]
  B.C. Zhu, J. Sun, Y.Y. Zhao, L.Y. Zhang, J.G. Yu, Adv. Mater. 36 (2024) 2310600, https://doi.org/10.1002/adma.202310600. doi: 10.1002/adma.202310600
46. [46]
  G.T. Sun, Z.G. Tai, F. Li, Q. Ye, T. Wang, Z.Y. Fang, L.C. Jia, W. Liu, H.Q. Wang, Small 19 (2023) e2207758, https://doi.org/10.1002/smll.202207758. doi: 10.1002/smll.202207758
47. [47]
  B.W. He, P. Xiao, S.J. Wan, J.J. Zhang, T. Chen, L.Y. Zhang, J.G. Yu, Angew. Chem. Int. Ed. 62 (2023) e202313172, https://doi.org/10.1002/anie.202313172. doi: 10.1002/anie.202313172
48. [48]
  W.L. Yu, C.B. Bie, Acta Phys. Chim. Sin. 40 (2024) 2307022, https://doi.org/10.3866/PKU.WHXB202307022. doi: 10.3866/PKU.WHXB202307022
49. [49]
  B.C. Zhu, J.J. Liu, J. Sun, F. Xie, H.Y. Tan, B. Cheng, J.J. Zhang, J. Mater. Sci. Technol. 162 (2023) 90, https://doi.org/10.1016/j.jmst.2023.03.054. doi: 10.1016/j.jmst.2023.03.054
50. [50]
  Z. Meng, J.J. Zhang, C.C. Jiang, C. Trapalis, L.Y. Zhang, J.G. Yu, Small (2023) e2308952, https://doi.org/10.1002/smll.202308952. doi: 10.1002/smll.202308952
51. [51]
  W.C. Wang, Y. Tao, J.C. Fan, Z.P. Yan, H. Shang, D.L. Phillips, M. Chen, G.S. Li, Adv. Funct. Mater. 32 (2022) 2201357, https://doi.org/10.1002/adfm.202201357. doi: 10.1002/adfm.202201357
52. [52]
  C.B. Bie, B.C. Zhu, L.X. Wang, H.G. Yu, C.H. Jiang, T. Chen, J.G. Yu, Angew. Chem. Int. Ed. 61 (2022) e202212045, https://doi.org/10.1002/anie.202212045. doi: 10.1002/anie.202212045
53. [53]
  L. Zhu, Z.F. Liang, H. Li, Q.N. Xu, D.C. Jiang, H.W. Du, C.H. Zhu, H.Q. Li, Z. Lu, Y.P. Yuan, Small 19 (2023) 2301017, https://doi.org/10.1002/smll.202301017. doi: 10.1002/smll.202301017
54. [54]
  J.J. Cai, B.W. Liu, S.M. Zhang, L.X. Wang, Z. Wu, J.J. Zhang, B. Cheng, J. Mater. Sci. Technol. 197 (2024) 183, https://doi.org/10.1016/j.jmst.2024.02.012. doi: 10.1016/j.jmst.2024.02.012
55. [55]
  K.F. Wu, H.M. Zhu, Z. Liu, W. Rodríguez, T.Q. Lian, J. Am. Chem. Soc. 134 (2012) 10337, https://doi.org/10.1021/ja303306u. doi: 10.1021/ja303306u
56. [56]
  B.C. Qiu, L. Cai, N. Zhang, X.M. Tao, Y. Chai, Adv. Sci. 7 (2020) 1903568, https://doi.org/10.1002/advs.201903568. doi: 10.1002/advs.201903568
57. [57]
  J.J. Zhang, J.J. Liu, Z. Meng, S. Jana, L.X. Wang, B.C. Zhu, J. Mater. Sci. Technol. 159 (2023) 1, https://doi.org/10.1016/j.jmst.2023.02.044. doi: 10.1016/j.jmst.2023.02.044
58. [58]
  J.J. Zhang, G.Y. Yang, B.W. He, B. Cheng, Y.J. Li, G.J. Liang, L.X. Wang, Chin. J. Catal. 43 (2022) 2530, https://doi.org/10.1016/s1872-2067(22)64108-1. doi: 10.1016/s1872-2067(22)64108-1
59. [59]
  C. Cheng, B.C. Zhu, B. Cheng, W. Macyk, L.X. Wang, J.G. Yu, ACS Catal. 13 (2022) 459, https://doi.org/10.1021/acscatal.2c05001. doi: 10.1021/acscatal.2c05001
60. [60]
  J.Y. Qiu, K. Meng, Y. Zhang, B. Cheng, J.J. Zhang, L.X. Wang, J.G. Yu, Adv. Mater. 36 (2024) 2400288, https://doi.org/10.1002/adma.202400288. doi: 10.1002/adma.202400288
61. [61]
  M.M. Luo, G.J. Jiang, M. Yu, Y.P. Yan, Z.J. Qin, Y. Li, Q. Zhang, J. Mater. Sci. Technol. 161 (2023) 220, https://doi.org/10.1016/j.jmst.2023.03.038. doi: 10.1016/j.jmst.2023.03.038
62. [62]
  J.H. Hua, Z.L. Wang, J.F. Zhang, K. Dai, C.F. Shao, K. Fan, J. Mater. Sci. Technol. 156 (2023) 64, https://doi.org/10.1016/j.jmst.2023.03.003. doi: 10.1016/j.jmst.2023.03.003
63. [63]
  T. Sun, C.X. Li, Y.P. Bao, J. Fan, E.Z. Liu, Acta Phys. Chim. Sin. 39 (2023) 2212009, https://doi.org/10.3866/PKU.WHXB202212009. doi: 10.3866/PKU.WHXB202212009
1. [1]
  Chenye An , Sikandaier Abiduweili , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . Hierarchical S-scheme Heterojunction of Red Phosphorus Nanoparticles Embedded Flower-like CeO₂ Triggering Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-0. doi: 10.3866/PKU.WHXB202405019
2. [2]
  Shuang Cao , Bo Zhong , Chuanbiao Bie , Bei Cheng , Feiyan Xu . Insights into Photocatalytic Mechanism of H₂ Production Integrated with Organic Transformation over WO₃/Zn_0.5Cd_0.5S S-Scheme Heterojunction. Acta Physico-Chimica Sinica, 2024, 40(5): 2307016-0. doi: 10.3866/PKU.WHXB202307016
3. [3]
  Jiawei Hu , Kai Xia , Ao Yang , Zhihao Zhang , Wen Xiao , Chao Liu , Qinfang Zhang . Interfacial Engineering of Ultrathin 2D/2D NiPS₃/C₃N₅ Heterojunctions for Boosting Photocatalytic H₂ Evolution. Acta Physico-Chimica Sinica, 2024, 40(5): 2305043-0. doi: 10.3866/PKU.WHXB202305043
4. [4]
  Haitao Wang , Lianglang Yu , Jizhou Jiang , Arramel , Jing Zou . S-Doping of the N-Sites of g-C₃N₄ to Enhance Photocatalytic H₂ Evolution Activity. Acta Physico-Chimica Sinica, 2024, 40(5): 2305047-0. doi: 10.3866/PKU.WHXB202305047
5. [5]
  Fanpeng Meng , Fei Zhao , Jingkai Lin , Jinsheng Zhao , Huayang Zhang , Shaobin Wang . Optimizing interfacial electric fields in carbon nitride nanosheet/spherical conjugated polymer S-scheme heterojunction for hydrogen evolution. Acta Physico-Chimica Sinica, 2025, 41(8): 100095-0. doi: 10.1016/j.actphy.2025.100095
6. [6]
  Xinyu Miao , Hao Yang , Jie He , Jing Wang , Zhiliang Jin . Adjusting the electronic structure of Keggin-type polyoxometalates to construct S-scheme heterojunction for photocatalytic hydrogen evolution. Acta Physico-Chimica Sinica, 2025, 41(6): 100051-0. doi: 10.1016/j.actphy.2025.100051
7. [7]
  Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta₃N₅ S-scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-0. doi: 10.3866/PKU.WHXB202403005
8. [8]
  Kaihui Huang , Dejun Chen , Xin Zhang , Rongchen Shen , Peng Zhang , Difa Xu , Xin Li . Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu₂O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(12): 2407020-0. doi: 10.3866/PKU.WHXB202407020
9. [9]
  Yi Yang , Xin Zhou , Miaoli Gu , Bei Cheng , Zhen Wu , Jianjun Zhang . Femtosecond transient absorption spectroscopy investigation on ultrafast electron transfer in S-scheme ZnO/CdIn₂S₄ photocatalyst for H₂O₂ production and benzylamine oxidation. Acta Physico-Chimica Sinica, 2025, 41(6): 100064-0. doi: 10.1016/j.actphy.2025.100064
10. [10]
  You Wu , Chang Cheng , Kezhen Qi , Bei Cheng , Jianjun Zhang , Jiaguo Yu , Liuyang Zhang . Efficient Photocatalytic Production of H₂O₂ over ZnO/D-A Conjugated Polymer S-scheme Heterojunction and Charge Transfer Dynamics Investigation. Acta Physico-Chimica Sinica, 2024, 40(11): 2406027-0. doi: 10.3866/PKU.WHXB202406027
11. [11]
  Changjun You , Chunchun Wang , Mingjie Cai , Yanping Liu , Baikang Zhu , Shijie Li . Improved Photo-Carrier Transfer by an Internal Electric Field in BiOBr/N-rich C₃N₅ 3D/2D S-Scheme Heterojunction for Efficiently Photocatalytic Micropollutant Removal. Acta Physico-Chimica Sinica, 2024, 40(11): 2407014-0. doi: 10.3866/PKU.WHXB202407014
12. [12]
  Yang Xia , Kangyan Zhang , Heng Yang , Lijuan Shi , Qun Yi . Improving Photocatalytic H₂O₂ Production over iCOF/Bi₂O₃ S-Scheme Heterojunction in Pure Water via Dual Channel Pathways. Acta Physico-Chimica Sinica, 2024, 40(11): 2407012-0. doi: 10.3866/PKU.WHXB202407012
13. [13]
  Menglan Wei , Xiaoxia Ou , Yimeng Wang , Mengyuan Zhang , Fei Teng , Kaixuan Wang . S-scheme heterojunction g-C₃N₄/Bi₂WO₆ highly efficient degradation of levofloxacin: performance, mechanism and degradation pathway. Acta Physico-Chimica Sinica, 2025, 41(9): 100105-0. doi: 10.1016/j.actphy.2025.100105
14. [14]
  Jianyin He , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Construction of ZnCoP/CdLa₂S₄ Schottky Heterojunctions for Enhancing Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(11): 2404030-0. doi: 10.3866/PKU.WHXB202404030
15. [15]
  Jizhou Liu , Chenbin Ai , Chenrui Hu , Bei Cheng , Jianjun Zhang . Accelerated Interfacial Electron Transfer in Perovskite Solar Cell by Ammonium Hexachlorostannate Modification and fs-TAS Investigation. Acta Physico-Chimica Sinica, 2024, 40(11): 2402006-0. doi: 10.3866/PKU.WHXB202402006
16. [16]
  Jingzhuo Tian , Chaohong Guan , Haobin Hu , Enzhou Liu , Dongyuan Yang . Waste plastics promoted photocatalytic H₂ evolution over S-scheme NiCr₂O₄/twinned-Cd_0.5Zn_0.5S homo-heterojunction. Acta Physico-Chimica Sinica, 2025, 41(6): 100068-0. doi: 10.1016/j.actphy.2025.100068
17. [17]
  Jingzhao Cheng , Shiyu Gao , Bei Cheng , Kai Yang , Wang Wang , Shaowen Cao . Construction of 4-Amino-1H-imidazole-5-carbonitrile Modified Carbon Nitride-Based Donor-Acceptor Photocatalyst for Efficient Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(11): 2406026-0. doi: 10.3866/PKU.WHXB202406026
18. [18]
  Yifan ZHAO , Qiyun MAO , Meijing GUO , Guoying ZHANG , Tongliang HU . Z-scheme bismuth-based multi-site heterojunction: Synthesis and hydrogen production from photocatalytic hydrogen production. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1318-1330. doi: 10.11862/CJIC.20250001
19. [19]
  Linfeng Xiao , Wanlu Ren , Shishi Shen , Mengshan Chen , Runhua Liao , Yingtang Zhou , Xibao Li . Enhancing Photocatalytic Hydrogen Evolution through Electronic Structure and Wettability Adjustment of ZnIn₂S₄/Bi₂O₃ S-Scheme Heterojunction. Acta Physico-Chimica Sinica, 2024, 40(8): 2308036-0. doi: 10.3866/PKU.WHXB202308036
20. [20]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . Architecting Inorganic/Organic S-Scheme Heterojunction of Bi₄Ti₃O₁₂ Coupling with g-C₃N₄ for Photocatalytic H₂O₂ Production from Pure Water. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-0. doi: 10.3866/PKU.WHXB202403009

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(69)
HTML views(10)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

CdS/DBTSO-BDTO S-scheme photocatalyst for H2 production and its charge transfer dynamics

Metrics

通讯作者: 陈斌, bchen63@163.com

CdS/DBTSO-BDTO S-scheme photocatalyst for H₂ production and its charge transfer dynamics