软模板法诱导Cu/Al2O3深孔道结构促进等离子催化CO2加氢制二甲醚

引用本文: 陈柳云, 王文举, 陆泰榕, 罗轩, 谢新玲, 黄科林, 覃善丽, 苏通明, 秦祖赠, 纪红兵. 软模板法诱导Cu/Al₂O₃深孔道结构促进等离子催化CO₂加氢制二甲醚[J]. 物理化学学报, 2025, 41(6): 100054. doi: 10.1016/j.actphy.2025.100054 shu

Citation: Liuyun Chen, Wenju Wang, Tairong Lu, Xuan Luo, Xinling Xie, Kelin Huang, Shanli Qin, Tongming Su, Zuzeng Qin, Hongbing Ji. Soft template-induced deep pore structure of Cu/Al₂O₃ for promoting plasma-catalyzed CO₂ hydrogenation to DME[J]. Acta Physico-Chimica Sinica, 2025, 41(6): 100054. doi: 10.1016/j.actphy.2025.100054 shu

软模板法诱导Cu/Al₂O₃深孔道结构促进等离子催化CO₂加氢制二甲醚

陈柳云 ^1, ,
王文举 ^1, ,
陆泰榕 ^3, ,
罗轩 ^1, ,
谢新玲 ^1, ,
黄科林 ^3, ,
覃善丽 ^3, ,
苏通明 ^1, ,
秦祖赠 ^1, ,
纪红兵 ^1,2,

1.
广西大学化学化工学院, 南宁 530004;
2.
浙江工业大学浙江绿色石化与轻烃转化研究院, 杭州 310014;
3.
广西产研院新型功能材料研究所, 南宁 530201
基金项目:
国家自然科学基金(22078074,22208065)和广西科技重大专项(Guike AA24263003)资助项目

摘要: 等离子体活化非均相催化反应是在温和条件下实现CO₂加氢反应的前沿策略。在本研究中，采用软模板法在Al₂O₃-x上构建了深孔通道结构。以Al₂O₃-x作为载体，通过浸渍法制备了Cu/Al₂O₃-x催化剂，并将其应用于等离子体催化CO₂加氢制二甲醚(DME)反应。在等离子体催化CO₂加氢反应中，Cu/Al₂O₃-0.75/HZSM-5展现出高性能和高放电效率。其等离子体催化CO₂加氢的CO₂转化率和DME产率分别达21.98%和9.83%，其中CO、CH₃OH和DME的选择性分别为25.39%、29.89%和44.72%。Al₂O₃-x上的深孔道结构能够作为Cu的负载位点，同时介孔结构的限域效应增强了金属-载体之间的相互作用及Cu的金属分散度。更丰富且更强的Brønsted碱性和Lewis酸性位点促进了CO₂的吸附、活化及加氢。值得注意地，锚定在深孔道结构中的Cu位点能够形成电场，从而引导等离子体活化CO₂中间体进入难以接近的孔隙中进行加氢反应。深孔通道中等离子体活化CO₂中间体的加氢对于提升等离子体催化CO₂加氢制DME反应效率具有重要意义。

关键词:

English

Soft template-induced deep pore structure of Cu/Al₂O₃ for promoting plasma-catalyzed CO₂ hydrogenation to DME

1.
School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, China;
2.
Zhejiang Green Petrochemical and Light Hydrocarbon Transformation Research Institute, Zhejiang University of Technology, Hangzhou 310014, China;
3.
Institute of New Functional Materials of Guangxi Institute of Industrial Technology, Nanning 530201, China
Received Date: 22 December 2024
Accepted Date: 21 January 2025
Revised Date: 21 January 2025
Fund Project:
The project was supported by the National Natural Science Foundation of China (22078074, 22208065) and the Key Projects of Guangxi Science and Technology (Guike AA24263003).

Abstract: Plasma-activated heterogeneous catalysis is a promising strategy for catalytic CO₂ hydrogenation under mild conditions. In this study, pore structures with deep pore channels were constructed on Al₂O₃-x via a soft template method, and Cu/Al₂O₃-x was prepared by an impregnation method, with Al₂O₃-x serving as the support for plasma-catalyzed CO₂ hydrogenation to dimethyl ether (DME). Cu/Al₂O₃-0.75/HZSM-5 demonstrated a high performance and discharge efficiency for plasma-catalyzed CO₂ hydrogenation. The CO₂ conversion and DME yield for plasma-catalyzed CO₂ hydrogenation on Cu/Al₂O₃-0.75/HZSM-5 reached 21.98% and 9.83%, respectively, with selectivities for CO, CH₃OH, and DME on Cu/Al₂O₃-0.75/HZSM-5 of 25.39%, 29.89%, and 44.72%, respectively. The deep pore structures on Al₂O₃-x serve as Cu loading sites, and the confinement effect of the pores enhances the metal-support interaction and Cu metal dispersion. More abundant and stronger Brønsted basic and Lewis acidic sites facilitate the activation and hydrogenation of CO₂. Notably, the electric field formed by Cu sites anchored in the deep pore channel structures is conducive to guiding the activated plasma CO₂ intermediates into the difficult-to-access pores for hydrogenation. Hydrogenation of the plasma-activated CO₂ intermediates in the deep pore channels is crucial for improving plasma-catalyzed CO₂ hydrogenation to DME.

Key words:

1. [1]
  Zhang, L.; Zhao, Z.-J.; Wang, T.; Gong, J. Chem. Soc. Rev. 2018, 47, 5423. doi: 10.1039/C8CS00016FZhang, L.; Zhao, Z.-J.; Wang, T.; Gong, J. Chem. Soc. Rev. 2018, 47, 5423. doi: 10.1039/C8CS00016F
2. [2]
  Gómez-Bravo, E.; González-Marcos, J. A.; González-Velasco, J. R.; Pereda-Ayo, B. Chem. Eng. Sci. 2024, 297, 120312. doi: 10.1016/j.ces.2024.120312Gómez-Bravo, E.; González-Marcos, J. A.; González-Velasco, J. R.; Pereda-Ayo, B. Chem. Eng. Sci. 2024, 297, 120312. doi: 10.1016/j.ces.2024.120312
3. [3]
  Lv, J.; Xie, J.; Mohamed, A. G. A.; Zhang, X.; Feng, Y.; Jiao, L.; Zhou, E.; Yuan, D.; Wang, Y. Nat. Rev. Chem. 2023, 7, 91. doi: 10.1038/s41570-022-00448-9Lv, J.; Xie, J.; Mohamed, A. G. A.; Zhang, X.; Feng, Y.; Jiao, L.; Zhou, E.; Yuan, D.; Wang, Y. Nat. Rev. Chem. 2023, 7, 91. doi: 10.1038/s41570-022-00448-9
4. [4]
  Deng, X.; Zhang, J.; Qi, K.; Liang, G.; Xu, F.; Yu, J. Nat. Commun. 2024, 15, 4807. doi: 10.1038/s41467-024-49004-7Deng, X.; Zhang, J.; Qi, K.; Liang, G.; Xu, F.; Yu, J. Nat. Commun. 2024, 15, 4807. doi: 10.1038/s41467-024-49004-7
5. [5]
  Guo, W.; Li, G.; bai, C.; Liu, Q.; Chen, F.; Chen, R. Nat. Commun. 2024, 15, 1573. doi: 10.1038/s41467-024-46072-7Guo, W.; Li, G.; bai, C.; Liu, Q.; Chen, F.; Chen, R. Nat. Commun. 2024, 15, 1573. doi: 10.1038/s41467-024-46072-7
6. [6]
  She, X.; Zhai, L.; Wang, Y.; Xiong, P.; Li, M. M.-J.; Wu, T.-S.; Wong, M. C.; Guo, X.; Xu, Z.; Li, H.; et al. Nat. Energy 2024, 9, 81. doi: 10.1038/s41560-023-01415-4She, X.; Zhai, L.; Wang, Y.; Xiong, P.; Li, M. M.-J.; Wu, T.-S.; Wong, M. C.; Guo, X.; Xu, Z.; Li, H.; et al. Nat. Energy 2024, 9, 81. doi: 10.1038/s41560-023-01415-4
7. [7]
  Chen, C.; Zhang, Z.; Li, G.; Li, L.; Lin, Z. Energy Fuels 2021, 35, 7485. doi: 10.1021/acs.energyfuels.1c00448Chen, C.; Zhang, Z.; Li, G.; Li, L.; Lin, Z. Energy Fuels 2021, 35, 7485. doi: 10.1021/acs.energyfuels.1c00448
8. [8]
  Hasan, M. M. F.; Rossi, L. M.; Debecker, D. P.; Leonard, K. C.; Li, Z.; Makhubela, B. C. E.; Zhao, C.; Kleij, A. ACS Sustainable Chem. Eng. 2021, 9, 12427. doi: 10.1021/acssuschemeng.1c06008Hasan, M. M. F.; Rossi, L. M.; Debecker, D. P.; Leonard, K. C.; Li, Z.; Makhubela, B. C. E.; Zhao, C.; Kleij, A. ACS Sustainable Chem. Eng. 2021, 9, 12427. doi: 10.1021/acssuschemeng.1c06008
9. [9]
  Chen, X.; Su, T.; Luo, X.; Xie, X.; Qin, Z.; Ji, H. Surf. Interfaces 2024, 48, 104346. doi: 10.1016/j.surfin.2024.104346Chen, X.; Su, T.; Luo, X.; Xie, X.; Qin, Z.; Ji, H. Surf. Interfaces 2024, 48, 104346. doi: 10.1016/j.surfin.2024.104346
10. [10]
  Kubas, D.; Gierse, M.; Salem, O.; Krossing, I. ACS Catal. 2023, 13, 3960. doi: 10.1021/acscatal.2c06207Kubas, D.; Gierse, M.; Salem, O.; Krossing, I. ACS Catal. 2023, 13, 3960. doi: 10.1021/acscatal.2c06207
11. [11]
  Le, N.; Fong, Y. J. Ind. Eng. Chem. 2024, 140, 88. doi: 10.1016/j.jiec.2024.05.058Le, N.; Fong, Y. J. Ind. Eng. Chem. 2024, 140, 88. doi: 10.1016/j.jiec.2024.05.058
12. [12]
  Chen, H.; Goodarzi, F.; Mu, Y.; Chansai, S.; Mielby, J. J.; Mao, B.; Sooknoi, T.; Hardacre, C.; Kegnæs, S.; Fan, X. Appl. Catal.b:Environ. 2020, 272, 119013. doi: 10.1016/j.apcatb.2020.119013Chen, H.; Goodarzi, F.; Mu, Y.; Chansai, S.; Mielby, J. J.; Mao, B.; Sooknoi, T.; Hardacre, C.; Kegnæs, S.; Fan, X. Appl. Catal.b:Environ. 2020, 272, 119013. doi: 10.1016/j.apcatb.2020.119013
13. [13]
  Neyts, E. C.; Ostrikov, K.; Sunkara, M. K.; Bogaerts, A. Chem. Rev. 2015, 115, 13408. doi: 10.1021/acs.chemrev.5b00362Neyts, E. C.; Ostrikov, K.; Sunkara, M. K.; Bogaerts, A. Chem. Rev. 2015, 115, 13408. doi: 10.1021/acs.chemrev.5b00362
14. [14]
  Ciocarlan, R. G.; Blommaerts, N.; Lenaerts, S.;COol, P.; Verbruggen, S. W. ChemSusChem 2023, 16, 25. doi: 10.1002/cssc.202201647Ciocarlan, R. G.; Blommaerts, N.; Lenaerts, S.;COol, P.; Verbruggen, S. W. ChemSusChem 2023, 16, 25. doi: 10.1002/cssc.202201647
15. [15]
  Joshi, N.; Loganathan, S. Plasma Process. Polym. 2021, 18, 11. doi: 10.1002/ppap.202000104Joshi, N.; Loganathan, S. Plasma Process. Polym. 2021, 18, 11. doi: 10.1002/ppap.202000104
16. [16]
  Su, T.; Zhou, X.; Qin, Z.; Ji, H. ChemPhysChem 2017, 18, 299. doi: 10.1002/cphc.201601283Su, T.; Zhou, X.; Qin, Z.; Ji, H. ChemPhysChem 2017, 18, 299. doi: 10.1002/cphc.201601283
17. [17]
  Whitehead, J. C. Front. Chem. Sci. Eng. 2019, 13, 264. doi: 10.1007/s11705-019-1794-3Whitehead, J. C. Front. Chem. Sci. Eng. 2019, 13, 264. doi: 10.1007/s11705-019-1794-3
18. [18]
  Wang, J.; Zhang, K.; Bogaerts, A.; Meynen, V. Chem. Eng. J. 2023, 464, 142574. doi: 10.1016/j.cej.2023.142574Wang, J.; Zhang, K.; Bogaerts, A.; Meynen, V. Chem. Eng. J. 2023, 464, 142574. doi: 10.1016/j.cej.2023.142574
19. [19]
  Tedeeva, M. A.; Kustov, A. L.; Pribytkov, P. V.; Kapustin, G. I.; Leonov, A. V.; Tkachenko, O. P.; Tursunov, O. B.; Evdokimenko, N. D.; Kustov, L. M. Fuel 2022, 313, 122698. doi: 10.1016/j.fuel.2021.122698Tedeeva, M. A.; Kustov, A. L.; Pribytkov, P. V.; Kapustin, G. I.; Leonov, A. V.; Tkachenko, O. P.; Tursunov, O. B.; Evdokimenko, N. D.; Kustov, L. M. Fuel 2022, 313, 122698. doi: 10.1016/j.fuel.2021.122698
20. [20]
  Kuwahara, Y.; Fujie, Y.; Mihogi, T.; Yamashita, H. ACS Catal. 2020, 10, 6356. doi: 10.1021/acscatal.0c01505Kuwahara, Y.; Fujie, Y.; Mihogi, T.; Yamashita, H. ACS Catal. 2020, 10, 6356. doi: 10.1021/acscatal.0c01505
21. [21]
  Xu, L.; Song, H.; Chou, L. Int. J. Hydrog. Energy 2013, 38, 7307. doi: 10.1016/j.ijhydene.2013.04.034Xu, L.; Song, H.; Chou, L. Int. J. Hydrog. Energy 2013, 38, 7307. doi: 10.1016/j.ijhydene.2013.04.034
22. [22]
  Guo, X.; Liu, F.; Hua, Y.; Xue, H.; Yu, J.; Mao, D.; Rempel, G. L.; Ng, F. T. T. Catal. Today 2023, 407, 125. doi: 10.1016/j.cattod.2022.02.004Guo, X.; Liu, F.; Hua, Y.; Xue, H.; Yu, J.; Mao, D.; Rempel, G. L.; Ng, F. T. T. Catal. Today 2023, 407, 125. doi: 10.1016/j.cattod.2022.02.004
23. [23]
  Ai, X.; Xie, H.; Chen, S.; Zhang, G.; Xu, B.; Zhou, G. Int. J. Hydrog. Energy 2022, 47, 14884. doi: 10.1016/j.ijhydene.2022.03.002Ai, X.; Xie, H.; Chen, S.; Zhang, G.; Xu, B.; Zhou, G. Int. J. Hydrog. Energy 2022, 47, 14884. doi: 10.1016/j.ijhydene.2022.03.002
24. [24]
  Zafar, F.; Zhao, R.; Ali, M.; Min Park, Y.; Roh, H.-S.; Gao, X.; Tian, J.; Wookbae, J. Chem. Eng. J. 2022, 439, 135649. doi: 10.1016/j.cej.2022.135649Zafar, F.; Zhao, R.; Ali, M.; Min Park, Y.; Roh, H.-S.; Gao, X.; Tian, J.; Wookbae, J. Chem. Eng. J. 2022, 439, 135649. doi: 10.1016/j.cej.2022.135649
25. [25]
  Guo, Y.; Feng, L.; Liu, Y.; Zhao, Z. Chin. Chem. Lett. 2022, 33, 2906. doi: 10.1016/j.cclet.2021.10.031Guo, Y.; Feng, L.; Liu, Y.; Zhao, Z. Chin. Chem. Lett. 2022, 33, 2906. doi: 10.1016/j.cclet.2021.10.031
26. [26]
  Qin, Z.-Z.; Su, T.-M.; Ji, H.-B.; Jiang, Y.-X.; Liu, R.-W.; Chen, J.-H. AIChE J. 2015, 61, 1613. doi: 10.1002/aic.14743Qin, Z.-Z.; Su, T.-M.; Ji, H.-B.; Jiang, Y.-X.; Liu, R.-W.; Chen, J.-H. AIChE J. 2015, 61, 1613. doi: 10.1002/aic.14743
27. [27]
  Yang, Y.; Su, T.; Xie, X.; Luo, X.; Ji, H.; Sin, J.-C.; Lam, S.-M.; Qin, Z. Catal. Lett. 2024, 154, 6454. doi: 10.1007/s10562-024-04828-2Yang, Y.; Su, T.; Xie, X.; Luo, X.; Ji, H.; Sin, J.-C.; Lam, S.-M.; Qin, Z. Catal. Lett. 2024, 154, 6454. doi: 10.1007/s10562-024-04828-2
28. [28]
  Zhou, X.; Su, T.; Jiang, Y.; Qin, Z.; Ji, H.; Guo, Z. Chem. Eng. Sci. 2016, 153, 10. doi: 10.1016/j.ces.2016.07.007Zhou, X.; Su, T.; Jiang, Y.; Qin, Z.; Ji, H.; Guo, Z. Chem. Eng. Sci. 2016, 153, 10. doi: 10.1016/j.ces.2016.07.007
29. [29]
  Su, T.; Zhou, X.; Qin, Z.; Ji, H. ChemPhysChem 2017, 18, 299. doi: 10.1002/cphc.201601283Su, T.; Zhou, X.; Qin, Z.; Ji, H. ChemPhysChem 2017, 18, 299. doi: 10.1002/cphc.201601283
30. [30]
  Chen, T.; Chen, J.; Wu, J.; Song, W.; Hu, S.; Feng, X.; Chen, Z.; Yuan, E.; Ji, W.; Au, C.-T. ACS Catal. 2023, 13, 887. doi: 10.1021/acscatal.2c04784Chen, T.; Chen, J.; Wu, J.; Song, W.; Hu, S.; Feng, X.; Chen, Z.; Yuan, E.; Ji, W.; Au, C.-T. ACS Catal. 2023, 13, 887. doi: 10.1021/acscatal.2c04784
31. [31]
  Li, B.-H.; Zhang, K.-H.; Wang, X.-J.; Li, Y.-P.; Liu, X.; Han, B.-H.; Li, F.-T. J. Coll. Interf. Sci. 2024, 660, 961. doi: 10.1016/j.jcis.2024.01.159Li, B.-H.; Zhang, K.-H.; Wang, X.-J.; Li, Y.-P.; Liu, X.; Han, B.-H.; Li, F.-T. J. Coll. Interf. Sci. 2024, 660, 961. doi: 10.1016/j.jcis.2024.01.159
32. [32]
  Zhang, P.; Shi, Y.; Zhang, Y.; Feng, S.; Shi, L.; Pan, J.; Cao, J.; Li, C. Chem. Eng. J. 2024, 487, 150727. doi: 10.1016/j.cej.2024.150727Zhang, P.; Shi, Y.; Zhang, Y.; Feng, S.; Shi, L.; Pan, J.; Cao, J.; Li, C. Chem. Eng. J. 2024, 487, 150727. doi: 10.1016/j.cej.2024.150727
33. [33]
  Fang, M.-J.; Lin, Y.-C.; Jan, J.-Y.; Lai, T.-H.; Hsieh, P.-Y.; Kuo, M.-Y.; Chiu, Y.-H.; Tsao, C.-W.; Chen, Y.-A.; Wang, Y.-T.; et al. Appl. Catal. B:Environ. 2023, 324, 122198. doi: 10.1016/j.apcatb.2022.122198Fang, M.-J.; Lin, Y.-C.; Jan, J.-Y.; Lai, T.-H.; Hsieh, P.-Y.; Kuo, M.-Y.; Chiu, Y.-H.; Tsao, C.-W.; Chen, Y.-A.; Wang, Y.-T.; et al. Appl. Catal. B:Environ. 2023, 324, 122198. doi: 10.1016/j.apcatb.2022.122198
34. [34]
  Deng, K.; Chen, X.; Moncada, J.; Salvatore, K. L.; Rui, N.; Xu, W.; Xiang, S.; Marinkovic, N.; Frenkel, A. I.; Zhou, G.; et al. ACS Catal. 2024, 14, 11832. doi: 10.1021/acscatal.4c02694Deng, K.; Chen, X.; Moncada, J.; Salvatore, K. L.; Rui, N.; Xu, W.; Xiang, S.; Marinkovic, N.; Frenkel, A. I.; Zhou, G.; et al. ACS Catal. 2024, 14, 11832. doi: 10.1021/acscatal.4c02694
35. [35]
  Sing, K. S. W. Pure Appl. Chem. 1985, 57, 603. doi: 10.1351/pac198557040603Sing, K. S. W. Pure Appl. Chem. 1985, 57, 603. doi: 10.1351/pac198557040603
36. [36]
  Chen, L.; Sun, M.; Meng, J.; Chu,b.; Xie, X.; Luo, X.; Ji, H.; Su, T.; Qin, Z. Appl. Surf. Sci. 2023, 637, 157948. doi: 10.1016/j.apsusc.2023.157948Chen, L.; Sun, M.; Meng, J.; Chu,b.; Xie, X.; Luo, X.; Ji, H.; Su, T.; Qin, Z. Appl. Surf. Sci. 2023, 637, 157948. doi: 10.1016/j.apsusc.2023.157948
37. [37]
  Peng, C.; Wei, P.; Li, X.; Liu, Y.; Cao, Y.; Wang, H.; Yu, H.; Peng, F.; Zhang, L.; Zhang, B.; et al. Nano Energy 2018, 53, 97. doi: 10.1016/j.nanoen.2018.08.040Peng, C.; Wei, P.; Li, X.; Liu, Y.; Cao, Y.; Wang, H.; Yu, H.; Peng, F.; Zhang, L.; Zhang, B.; et al. Nano Energy 2018, 53, 97. doi: 10.1016/j.nanoen.2018.08.040
38. [38]
  Dai, J.; Zhang, H. Small 2021, 17, 2005334. doi: 10.1002/smll.202005334Dai, J.; Zhang, H. Small 2021, 17, 2005334. doi: 10.1002/smll.202005334
39. [39]
  Luo, Y.; Su, T.; Song, P.; Chen, L.; Xie, X.; Luo, X.; Ji, H.; Qin, Z. Mol. Catal. 2024, 562, 114226. doi: 10.1016/j.mcat.2024.114226Luo, Y.; Su, T.; Song, P.; Chen, L.; Xie, X.; Luo, X.; Ji, H.; Qin, Z. Mol. Catal. 2024, 562, 114226. doi: 10.1016/j.mcat.2024.114226
40. [40]
  Khalakhan, I.; Vorokhta, M.; Xie, X.; Piliai, L.; Matolínová, I. J. Electron Spectrosc. 2021, 246, 147027. doi: 10.1016/j.elspec.2020.147027Khalakhan, I.; Vorokhta, M.; Xie, X.; Piliai, L.; Matolínová, I. J. Electron Spectrosc. 2021, 246, 147027. doi: 10.1016/j.elspec.2020.147027
41. [41]
  Tanos, F.; Makhoul, E.; Nada, A. A.; Bekheet, M. F.; Riedel, W.; Kawrani, S.; Belaid, H.; Petit, E.; Viter, R.; Fedorenko, V.; et al. Appl. Surf. Sci. 2024, 656, 159698. doi: 10.1016/j.apsusc.2024.159698Tanos, F.; Makhoul, E.; Nada, A. A.; Bekheet, M. F.; Riedel, W.; Kawrani, S.; Belaid, H.; Petit, E.; Viter, R.; Fedorenko, V.; et al. Appl. Surf. Sci. 2024, 656, 159698. doi: 10.1016/j.apsusc.2024.159698
42. [42]
  Oh, Y.; Theerthagiri, J.; ArunaKumari, M. L.; Min, A.; Moon, C. J.; Choi, M. Y. J. Energy Chem. 2024, 91, 145. doi: 10.1016/j.jechem.2023.12.023Oh, Y.; Theerthagiri, J.; ArunaKumari, M. L.; Min, A.; Moon, C. J.; Choi, M. Y. J. Energy Chem. 2024, 91, 145. doi: 10.1016/j.jechem.2023.12.023
43. [43]
  Zhang, K.; Lu, J.; Li, J.; Zhang, D.; Gao, L.; Zhou, H. Corros. Sci. 2020, 164, 108352. doi: 10.1016/j.corsci.2019.108352Zhang, K.; Lu, J.; Li, J.; Zhang, D.; Gao, L.; Zhou, H. Corros. Sci. 2020, 164, 108352. doi: 10.1016/j.corsci.2019.108352
44. [44]
  Li, M.; Ma, Y.; Chen, J.; Lawrence, R.; Luo, W.; Sacchi, M.; Jiang, W.; Yang, J. Angew. Chem. Int. Ed. 2021, 60, 11487. doi: 10.1002/anie.202102606Li, M.; Ma, Y.; Chen, J.; Lawrence, R.; Luo, W.; Sacchi, M.; Jiang, W.; Yang, J. Angew. Chem. Int. Ed. 2021, 60, 11487. doi: 10.1002/anie.202102606
45. [45]
  Wang, C.; Su, T.; Qin, Z.; Ji, H. Catal. Sci. Technol. 2022, 12, 4826. doi: 10.1039/D2CY00582DWang, C.; Su, T.; Qin, Z.; Ji, H. Catal. Sci. Technol. 2022, 12, 4826. doi: 10.1039/D2CY00582D
46. [46]
  Lo, A.-Y.; Chung, Y.-C.; Xie, P.-J.; Delbari, H.; Yang, Z.-H.; Taghipour, F. Appl. Mater. Today 2023, 32, 101811. doi: 10.1016/j.apmt.2023.101811Lo, A.-Y.; Chung, Y.-C.; Xie, P.-J.; Delbari, H.; Yang, Z.-H.; Taghipour, F. Appl. Mater. Today 2023, 32, 101811. doi: 10.1016/j.apmt.2023.101811
47. [47]
  Li, H.; Zhao, S.; Zhang, W.; Du, H.; Yang, X.; Peng, Y.; Han, D.; Wang, B.; Li, Z. Fuel 2023, 342, 127786. doi: 10.1016/j.fuel.2023.127786Li, H.; Zhao, S.; Zhang, W.; Du, H.; Yang, X.; Peng, Y.; Han, D.; Wang, B.; Li, Z. Fuel 2023, 342, 127786. doi: 10.1016/j.fuel.2023.127786
48. [48]
  Chong, R.; Su, C.; Du, Y.; Fan, Y.; Ling, Z.; Chang, Z.; Li, D. J. Catal. 2018, 363, 92. doi: 10.1016/j.jcat.2018.04.020Chong, R.; Su, C.; Du, Y.; Fan, Y.; Ling, Z.; Chang, Z.; Li, D. J. Catal. 2018, 363, 92. doi: 10.1016/j.jcat.2018.04.020
49. [49]
  Li, D.; Sun, Y.; Yang, Y.-L.; Shi, X.-L.; Xie, D.-A.; Nie, L.; Chen, J.-G.; Luo, Z.; Chen, H.-J.; Yang, C.-A.; et al. Sustain. Materi. Techno. 2024, 39, e00834. doi: 10.1016/j.susmat.2024.e00834Li, D.; Sun, Y.; Yang, Y.-L.; Shi, X.-L.; Xie, D.-A.; Nie, L.; Chen, J.-G.; Luo, Z.; Chen, H.-J.; Yang, C.-A.; et al. Sustain. Materi. Techno. 2024, 39, e00834. doi: 10.1016/j.susmat.2024.e00834
50. [50]
  Kostyniuk, A.; Key, D.; Mdleleni, M. J. Saudi Chem. Soc. 2019, 23, 612. doi: 10.1016/j.jscs.2018.11.001Kostyniuk, A.; Key, D.; Mdleleni, M. J. Saudi Chem. Soc. 2019, 23, 612. doi: 10.1016/j.jscs.2018.11.001

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沈阳化工大学材料科学与工程学院沈阳 110142

软模板法诱导Cu/Al₂O₃深孔道结构促进等离子催化CO₂加氢制二甲醚

English

Soft template-induced deep pore structure of Cu/Al₂O₃ for promoting plasma-catalyzed CO₂ hydrogenation to DME

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