Citation: Yi LU, Ruo-wen LIANG, Gui-yang YAN, Zhi-yu LIANG, Wei-neng HU, Yu-zhou XIA, Ren-kun HUANG. Solvothermal synthesis of TiO₂@MIL-101(Cr) for efficient photocatalytic fuel denitrification[J]. Journal of Fuel Chemistry and Technology, ;2022, 50(4): 456-463. doi: 10.1016/S1872-5813(21)60170-6 shu

Solvothermal synthesis of TiO₂@MIL-101(Cr) for efficient photocatalytic fuel denitrification

Yi LU ^{1, 2,} ,
Ruo-wen LIANG ^{1, 2, 3} ,
Gui-yang YAN ¹ ,
Zhi-yu LIANG ^{1, 3} ,
Wei-neng HU ² ,
Yu-zhou XIA ¹ ,
Ren-kun HUANG ^{1, 2, 3,,}

1.
Province University Key Laboratory of Green Energy and Environment Catalysis, Ningde Normal University, Ningde 352100, China
2.
State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou 350002, China
3.
Fujian Provincial Key Laboratory of Featured Materials in Biochemical Industry, Ningde Normal University, Ningde 352100, China

Author Bio: 957832459@qq.com
Corresponding author: Ren-kun HUANG, t1432@ndnu.edu.cn
Received Date: 4 August 2021
Revised Date: 23 September 2021

Figures(12)

Solvothermal synthesis technique is an effective method to create composite materials. In this paper, a series of TiO₂@MIL-101(Cr) were prepared by the solvothermal method for photocatalytic denitrification of pyridine in fuel under visible light irradiation. The products were characterized by XRD, FT-IR, SEM, TEM, BET, DRS and ESR. The result shows that 20%TiO₂@MIL-101(Cr) has high catalytic activity, the pyridine removal efficiency reaches values as high as 70% after irradiation for 240 min. Finally, we obtained the possible mechanism of photocatalytic denitrification according to the HPLC-MS spectrometry results analysis.
- photocatalytic,
- fuel,
- denitrification,
- MIL-101(Cr),
- TiO₂
1. [1]
  YIN C. International law regulation of offshore oil and gas exploitation[J]. Environ Impact Assess Rev,2021,88:106551.
2. [2]
  PRADO G H C, RAO Y, KLERK A. Nitrogen removal from oil: A review[J]. Energy Fuels,2016,31(1):14−36.
3. [3]
  BHADRA B N, BAEK Y S, CHOI C H, JHUNG S H. How neutral nitrogen-containing compounds are oxidized in oxidative-denitrogenation of liquid fuel with TiO₂@carbon[J]. Phys Chem Chem Phys,2021,23(14):8368−8374. doi: 10.1039/D1CP00633A
4. [4]
  DEESE R D, MORRIS R E, METZ A E, MYERS K M, JOHNSON K, LOEGEL T N. Characterization of organic nitrogen compounds and their impact on the stability of marginally stable diesel fuels[J]. Energy Fuels,2019,33(7):6659−6669. doi: 10.1021/acs.energyfuels.9b00932
5. [5]
  PAUCAR N E, KIGGINS P, BLAD B, DE JESUS K, AFRIN F, PASHIKANTI S, SHARMA K. Ionic liquids for the removal of sulfur and nitrogen compounds in fuels: A review[J]. Environ Chem Lett,2021,19(2):1205−1228. doi: 10.1007/s10311-020-01135-1
6. [6]
  JURY M R. Meteorology of air pollution in Los Angeles[J]. Atmospheric Pollut Res,2020,11(7):1226−1237. doi: 10.1016/j.apr.2020.04.016
7. [7]
  LIANG R, HUANG R, WANG X, YING S, YAN G, WU L. Functionalized MIL-68(In) for the photocatalytic treatment of Cr(VI)-containing simulation wastewater: Electronic effects of ligand substitution[J]. Appl Surf Sci,2019,464:396−403. doi: 10.1016/j.apsusc.2018.09.100
8. [8]
  ALVARO M, CARBONELL E, FERRER B, LLABRES I XAMENA F X, GARCIA H. Semiconductor behavior of a metal-organic framework (MOF)[J]. Chem Eur J,2007,13(18):5106−51112. doi: 10.1002/chem.200601003
9. [9]
  DHAKSHINAMOORTHY A, LI Z, GARCIA H. Catalysis and photocatalysis by metal organic frameworks[J]. Chem Soc Rev,2018,47(22):8134−8172. doi: 10.1039/C8CS00256H
10. [10]
  GAO P, LIU R, HUANG H, JIA X, PAN H. MOF-templated controllable synthesis of α-Fe₂O₃ porous nanorods and their gas sensing properties[J]. RSC Adv,2016,6(97):94699−94705. doi: 10.1039/C6RA21567J
11. [11]
  LI Q, WU J, HUANG L, GAO J, ZHOU H, SHI Y, PAN Q, ZHANG G, DU Y, LIANG W. Sulfur dioxide gas-sensitive materials based on zeolitic imidazolate framework-derived carbon nanotubes[J]. J Mater Chem A,2018,6(25):12115−12124. doi: 10.1039/C8TA02036A
12. [12]
  CUI Y F, JIANG W, LIANG S, ZHU L F, YAO Y W. MOF-derived synthesis of mesoporous In/Ga oxides and their ultra-sensitive ethanol-sensing properties[J]. J Mater Chem A,2018,6(30):14930−14938. doi: 10.1039/C8TA00269J
13. [13]
  FANG Y, MA Y, ZHENG M, YANG P, ASIRI A M, WANG X. Metal-organic frameworks for solar energy conversion by photoredox catalysis[J]. Coord Chem Rev,2018,373:83−115. doi: 10.1016/j.ccr.2017.09.013
14. [14]
  YUAN S, FENG L, WANG K, PANG J, BOSCH M, LOLLAR C, SUN Y, QIN J, YANG X, ZHANG P, WANG Q, ZOU L, ZHANG Y, ZHANG L, FANG Y, LI J, ZHOU H C. Stable metal-organic frameworks: Design, synthesis, and applications[J]. Adv Mater,2018,30(37):e1704303. doi: 10.1002/adma.201704303
15. [15]
  XUE D-X, WANG Q, BAI J. Amide-functionalized metal-organic frameworks: Syntheses, structures and improved gas storage and separation properties[J]. Coord Chem Rev,2019,378:2−16. doi: 10.1016/j.ccr.2017.10.026
16. [16]
  YING M, TANG R, YANG W, LIANG W, YANG G, PAN H, LIAO X, HUANG J. Tailoring electronegativity of bimetallic Ni/Fe metal-organic framework nanosheets for electrocatalytic water oxidation[J]. ACS Appl Nano Mater,2021,4(2):1967−1975. doi: 10.1021/acsanm.0c03310
17. [17]
  LIANG R, HUANG R, YING S, WANG X, YAN G, WU L. Facile in situ growth of highly dispersed palladium on phosphotungstic-acid-encapsulated MIL-100(Fe) for the degradation of pharmaceuticals and personal care products under visible light[J]. J Nano Res,2017,11(2):1109−1123.
18. [18]
  WANG C-C, DU X-D, LI J, GUO X-X, WANG P, ZHANG J. Photocatalytic Cr(VI) reduction in metal-organic frameworks: A mini-review[J]. App Catal B: Environ,2016,193:198−216. doi: 10.1016/j.apcatb.2016.04.030
19. [19]
  KHAN N A, JHUNG S H. Phytic acid-encapsulated MIL-101(Cr): Remarkable adsorbent for the removal of both neutral indole and basic quinoline from model liquid fuel[J]. Chem Eng J,2019,375.
20. [20]
  GUO Q, ZHOU C, MA Z, YANG X. Fundamentals of TiO₂ photocatalysis: Concepts, mechanisms, and challenges[J]. Adv Mater,2019,31(50):1901997. doi: 10.1002/adma.201901997
21. [21]
  FUJIMOTO T M, PONCZEK M, ROCHETTO U L, LANDERS R, TOMAZ E. Photocatalytic oxidation of selected gas-phase VOCs using UV light, TiO₂, and TiO₂/Pd[J]. Environ Sci Pollut Res Int,2017,24(7):6390−6396. doi: 10.1007/s11356-016-6494-7
22. [22]
  LIN J Y, LEE J, WEN D O, KWON E, LIN K. Hierarchical zif-decorated nanoflower-covered 3-dimensional foam for enhanced catalytic reduction of nitrogen-containing contaminants[J]. J Colloid Interface Sci 2021, 602: 95-104.
23. [23]
  HU W, YAN G, LIANG R, JIANG M, HUANG R, XIA Y, CHEN L, LU Y. Construction of a novel step-scheme CdS/Pt/Bi₂MoO₆ photocatalyst for efficient photocatalytic fuel denitrification[J]. RSC Adv,2021,11(38):23288−23300. doi: 10.1039/D1RA04417F
24. [24]
  LIANG R, LIANG I, CHEN F, XIE P, WV Y, WANG X, YAN G, WV L. Sodium dodecyl sulfate-decorated MOF-derived porous Fe₂O₃ nanoparticles: High performance, recyclable photocatalysts for fuel denitrification[J]. Chin J Catal,2020,41(1):188−199.
25. [25]
  HUANG R, LIANG R, FAN H, YING S, WU L, WANG X, YAN G. Enhanced Photocatalytic fuel denitrification over TiO₂/alpha-Fe₂O₃ nanocomposites under visible light irradiation[J]. Sci Rep,2017,7(1):7858. doi: 10.1038/s41598-017-08439-3
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Solvothermal synthesis of TiO2@MIL-101(Cr) for efficient photocatalytic fuel denitrification

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通讯作者: 陈斌, bchen63@163.com

Solvothermal synthesis of TiO₂@MIL-101(Cr) for efficient photocatalytic fuel denitrification