Citation: Li-ye ZHAO, Ru-shun AN, Xin SHI, Guo-bo CHEN, Liang WANG, Chun-hu LI. The effect of Bi content on the photocatalytic performance of bismuth oxybromides[J]. Journal of Fuel Chemistry and Technology, ;2022, 50(2): 250-256. doi: 10.1016/S1872-5813(21)60144-5 shu

The effect of Bi content on the photocatalytic performance of bismuth oxybromides

Li-ye ZHAO ^{1, #,} ,
Ru-shun AN ^{1, #} ,
Xin SHI ² ,
Guo-bo CHEN ^1,, ,
Liang WANG ^1,, ,
Chun-hu LI ¹

1.
College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100, China
2.
Sinopec Northwest Oilfield Branch, Xinjiang 830011, China

Corresponding author: Guo-bo CHEN, chenguobo@ouc.edu.cn Liang WANG, wangliang_good@163. com
Received Date: 14 May 2021
Revised Date: 21 June 2021

Figures(11)

BiOBr, Bi₃O₄Br and Bi₄O₅Br₂ were prepared by hydrothermal and solvothermal methods. Their structural composition, surface morphology, chemical states and optical properties were characterized by XRD, SEM, XPS and UV-vis. The band structure and density of states of the photocatalysts were calculated by density functional theory (DFT). The photocatalytic activity was evaluated by degradation of RhB. The results show that band gap and the position of conduction band is affected by Bi content. The Bi₄O₅Br₂ photocatalyst can completely degrade RhB in 50 min. Radical-trapping experiments proves that ·\begin{document}$ {\rm{O}}_2^- $\end{document} is the main active species in photocatalytic degradation of RhB.
- BiOBr,
- Bi content,
- DFT,
- photocatalytic performance
1. [1]
  VAYA D, SUROLIA P K. Semiconductor based photocatalytic degradation of pesticides: An overview[J]. Environ Technol Innovation,2020,20:101128. doi: 10.1016/j.eti.2020.101128
2. [2]
  IKREEDEEGH RR, TAHIR M. A critical review in recent developments of metal-organic-frameworks (MOFs) with band engineering alteration for photocatalytic CO₂ reduction to solar fuels[J]. J CO₂ Util,2021,43:101381. doi: 10.1016/j.jcou.2020.101381
3. [3]
  HU Qing-song. Construction of bismuth oxyhalide composite catalysts with enhanced photocatalytic activity for the removal of contaminants[D]. Shanghai: East China Normal University, 2020.
4. [4]
  SUN J J, LI X Y, ZHAO Q D, LIU B J. Ultrathin nanoflake-assembled hierarchical BiOBr microflower with highly exposed {001} facets for efficient photocatalytic degradation of gaseous ortho-dichlorobenzene[J]. App Catal B: Environ,2021,281:119478. doi: 10.1016/j.apcatb.2020.119478
5. [5]
  MAO D J, DING S S, MENG L J, DAI Y X, SUN C, YANG S G, HE H. One-pot microemulsion-mediated synthesis of Bi-rich Bi₄O₅Br₂ with controllable morphologies and excellent visible-light photocatalytic removal of pollutants[J]. App Catal B: Environ,2017,207:153−165. doi: 10.1016/j.apcatb.2017.02.010
6. [6]
  TIAN H D, CHENG R R, LIN M H, LI P, LV Y H, RAN S L. Oxygen-vacancy-rich ultrathin BiOBr nonosheets for high-performance supercapacitor electrodes[J]. Inorg Chem Commun,2020,118:108018. doi: 10.1016/j.inoche.2020.108018
7. [7]
  BAI Y, YANG P, WANG L, YANG B, XIE H Q, ZHOU Y, YE L Q. Ultrathin Bi₄O₅Br₂ nanosheets for selective photocatalytic CO₂ conversion into CO[J]. Chem Eng J,2019,360:473−482. doi: 10.1016/j.cej.2018.12.008
8. [8]
  Mao D J, Yuan J L, Qu X L, SUN C, YANG S G, HE H. Size tunable Bi₃O₄Br hierarchical hollow spheres assembled with {0 0 1}-facets exposed nanosheets for robust photocatalysis against phenolic pollutants[J]. J Catal,2019,369:209−221. doi: 10.1016/j.jcat.2018.11.016
9. [9]
  ZHANG H G, WANG W T, FENG LJ, LI C H WANG L. Effect of hydrothermal pH value on composition and morphology of bismuth oxybromide and their photocatalytic performance[J]. J Fuel Chem Technol,2019,47(5):582−589. doi: 10.1016/S1872-5813(19)30026-X
10. [10]
  ZHANG W B, XIAO X, WU Q F, FAN Q, ZAHNG F C. Facile synthesis of novel Mn-doped Bi₄O₅Br₂ for enhanced photocatalytic NO removal activity[J]. J Alloys Compd,2020,826:154204. doi: 10.1016/j.jallcom.2020.154204
11. [11]
  ZHANG Y, YANG W. Comment on ''generalized gradient approximation made simple''[J]. Phys Rev Lett,1998,80(4):891−891. doi: 10.1103/PhysRevLett.80.891
12. [12]
  MONKHORST H J, PACK J D. Special points for brillonin-zone integrations[J]. Phys Rev B,1976,13(12):5188−5192. doi: 10.1103/PhysRevB.13.5188
13. [13]
  LI K L, LEE WW, LU CS, DAI Y M, CHOU S Y, CHEN S L, LIN H P, CHEN C C. Synthesis of BiOBr, Bi₃O₄Br, and Bi₁₂O₁₇Br₂ by controlled hydrothermal method and their photocatalytic properties[J]. J Taiwan Inst Chem Eng,2014,45(5):2688−2697. doi: 10.1016/j.jtice.2014.04.001
14. [14]
  JIN X L, LV C, ZHOU X, XIE H Q, SUN S F, LIU Y, MENG Q Q, CHEN G. A bismuth rich hollow Bi₄O₅Br₂ photocatalyst enables dramatic CO₂ reduction activity[J]. Nano Energy,2019,64:103955. doi: 10.1016/j.nanoen.2019.103955
15. [15]
  WANG X K, LIU Y X, WANG J N, ZHANG J M, HUANG Y H, WEI X M. Theoretical investigation of the photocatalytic mechanism of single Au adsorption on the Bi₄O₅Br₂ (101) surface[J]. Chem Phys Lett,2020,757(6):137851.
16. [16]
  GUO N N, CAO Y L, RONG Y L, JIA D Z. Green synthesis of BiOBr modified Bi₂O₂CO₃ nanocomposites with enhanced visible-responsive photocatalytic properties[J]. RSC Adv,2016,6(108):106046. doi: 10.1039/C6RA22385K
17. [17]
  YANG P, WANG J C, YUE G Z, YANG R Z, ZHAO P X, YANG L J, ZHANG X C, ASTRUC D. Constructing mesoporous g-C₃N₄/ZnO nanosheets catalyst for enhanced visible-light driven photocatalytic activity[J]. J Photoch Photobio A,2020,388:112169. doi: 10.1016/j.jphotochem.2019.112169
18. [18]
  LI R, XIE F X, LIU J X, WANG Y W, WANG Y F, ZHANG X C, FAN C M. Synthesis of Bi₄O₅Br₂ from reorganization of BiOBr and its excellent visible light photocatalytic activity[J]. Dalton Trans,2016,45:9182−9186. doi: 10.1039/C6DT00997B
19. [19]
  KANAGARAI T, THIRIPURANTHAGAN S. Photocatalytic activities of novel SrTiO₃-BiOBr heterojunction catalysts towards the degradation of reactive dyes[J]. App Catal B: Environ,2017,207:218−232. doi: 10.1016/j.apcatb.2017.01.084
20. [20]
  AO Y H, WANG K D, WANG P F, WANG C, HOU J. Synthesis of novel 2D-2D p-n heterojunction BiOBr/La₂Ti₂O₇ composite photocatalyst with enhanced photocatalytic performance under both UV and visible light irradiation[J]. App Catal B: Environ,2016,194:157−168. doi: 10.1016/j.apcatb.2016.04.050
1. [1]
  Jie ZHAO , Huili ZHANG , Xiaoqing LU , Zhaojie WANG . Theoretical calculations of CO₂ capture and separation by functional groups modified 2D covalent organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 275-283. doi: 10.11862/CJIC.20240213
2. [2]
  Hao XU , Ruopeng LI , Peixia YANG , Anmin LIU , Jie BAI . Regulation mechanism of halogen axial coordination atoms on the oxygen reduction activity of Fe-N₄ site: A density functional theory study. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 695-701. doi: 10.11862/CJIC.20240302
3. [3]
  Qianqian Liu , Xing Du , Wanfei Li , Wei-Lin Dai , Bo Liu . Synergistic Effects of Internal Electric and Dipole Fields in SnNb₂O₆/Nitrogen-Enriched C₃N₅ S-Scheme Heterojunction for Boosting Photocatalytic Performance. Acta Physico-Chimica Sinica, 2024, 40(10): 2311016-0. doi: 10.3866/PKU.WHXB202311016
4. [4]
  Wei Sun , Yongjing Wang , Kun Xiang , Saishuai Bai , Haitao Wang , Jing Zou , Arramel , Jizhou Jiang . CoP Decorated on Ti₃C₂T_x MXene Nanocomposites as Robust Electrocatalyst for Hydrogen Evolution Reaction. Acta Physico-Chimica Sinica, 2024, 40(8): 2308015-0. doi: 10.3866/PKU.WHXB202308015
5. [5]
  Kaifu Zhang , Shan Gao , Bin Yang . Application of Theoretical Calculation with Fun Practice in Raman Spectroscopy Experimental Teaching. University Chemistry, 2025, 40(3): 62-67. doi: 10.12461/PKU.DXHX202404045
6. [6]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
7. [7]
  Weina Wang , Lixia Feng , Fengyi Liu , Wenliang Wang . Computational Chemistry Experiments in Facilitating the Study of Organic Reaction Mechanism: A Case Study of Electrophilic Addition of HCl to Asymmetric Alkenes. University Chemistry, 2025, 40(3): 206-214. doi: 10.12461/PKU.DXHX202407022
8. [8]
  Tongqi Ye , Yanqing Wang , Qi Wang , Huaiping Cong , Xianghua Kong , Yuewen Ye . Reform of Classical Thermodynamics Curriculum from the Perspective of Computational Chemistry. University Chemistry, 2025, 40(7): 387-392. doi: 10.12461/PKU.DXHX202409128
9. [9]
  Xiaochen Zhang , Fei Yu , Jie Ma . Cutting-Edge Applications of Multi-Angle Numerical Simulations for Capacitive Deionization. Acta Physico-Chimica Sinica, 2024, 40(11): 2311026-0. doi: 10.3866/PKU.WHXB202311026
10. [10]
  Meifeng Zhu , Jin Cheng , Kai Huang , Cheng Lian , Shouhong Xu , Honglai Liu . Classical Density Functional Theory for Understanding Electrochemical Interface. University Chemistry, 2025, 40(3): 148-152. doi: 10.12461/PKU.DXHX202405166
11. [11]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
12. [12]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
13. [13]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
14. [14]
  Xin Zhou , Zhi Zhang , Yun Yang , Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi₂MoO₆ Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008
15. [15]
  Yaping ZHANG , Tongchen WU , Yun ZHENG , Bizhou LIN . Z-scheme heterojunction β-Bi₂O₃ pillared CoAl layered double hydroxide nanohybrid: Fabrication and photocatalytic degradation property. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 531-539. doi: 10.11862/CJIC.20240256
16. [16]
  Maitri Bhattacharjee , Rekha Boruah Smriti , R. N. Dutta Purkayastha , Waldemar Maniukiewicz , Shubhamoy Chowdhury , Debasish Maiti , Tamanna Akhtar . Synthesis, structural characterization, bio-activity, and density functional theory calculation on Cu(Ⅱ) complexes with hydrazone-based Schiff base ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1409-1422. doi: 10.11862/CJIC.20240007
17. [17]
  Zhengkun QIN , Zicong PAN , Hui TIAN , Wanyi ZHANG , Mingxing SONG . A series of iridium(Ⅲ) complexes with fluorophenyl isoquinoline ligand and low-efficiency roll-off properties: A density functional theory study. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1235-1244. doi: 10.11862/CJIC.20240429
18. [18]
  Min WANG , Dehua XIN , Yaning SHI , Wenyao ZHU , Yuanqun ZHANG , Wei ZHANG . Construction and full-spectrum catalytic performance of multilevel Ag/Bi/nitrogen vacancy g-C₃N₄/Ti₃C₂T_x Schottky junction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1123-1134. doi: 10.11862/CJIC.20230477
19. [19]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
20. [20]
  Mingjie Lei , Wenting Hu , Kexin Lin , Xiujuan Sun , Haoshen Zhang , Ye Qian , Tongyue Kang , Xiulin Wu , Hailong Liao , Yuan Pan , Yuwei Zhang , Diye Wei , Ping Gao . Accelerating the reconstruction of NiSe₂ by Co/Mn/Mo doping for enhanced urea electrolysis. Acta Physico-Chimica Sinica, 2025, 41(8): 100083-0. doi: 10.1016/j.actphy.2025.100083

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(384)
HTML views(98)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142