Citation: Xiao-sheng WANG, Tao YANG, Qin LI, Yu-xiang LIU, Yong-chuan DING. Phosphorous modified V-MCM-41 catalysts for propane dehydrogenation[J]. Journal of Fuel Chemistry and Technology, ;2022, 50(2): 227-236. doi: 10.1016/S1872-5813(21)60138-X shu

Phosphorous modified V-MCM-41 catalysts for propane dehydrogenation

1.
College of New Energy and Materials, China University of Petroleum-Beijing, Beijing 102249, China
2.
College of Chemical Engineering, Qingdao University of Science & Technology, Qingdao 266042, China
3.
Shandong Shida Shenghua Chemical Group Co. Ltd., Dongying 257061, China

Corresponding author: Xiao-sheng WANG, wxs880620@cup.edu.cn Yu-xiang LIU, liuyx@qust.edu.cn
Received Date: 31 May 2021
Revised Date: 6 July 2021

Figures(10)

The dehydrogenation performance of vanadyl catalysts was closely related to the form of surface vanadyl species. To enhance the vanadium dispersion, phosphorus was adopted to modify V-MCM-41 catalysts by using organic vanadium and phosphorus precursors. The influence of phosphorus introduction to the mesoporous structure and vanadyl species were investigated by various characterization techniques. The results showed that the catalysts could maintain ordered hexagonal mesoporous structures though the specific surface area slowly decreased along with the increase of phosphorus content. Both the reducibility and dispersion of the surface vanadyl species were improved. The proportion of polymerized vanadyl species obviously decreased due to the presence of phosphorus species. The propane dehydrogenation reaction results showed that both the catalytic performance and the catalyst stability were improved. Both the maximum surface vanadyl site density and optimum propane dehydrogenation performance were obtained over the sample with Si/P molar ratio of 30.
- phosphorous modification,
- MCM-41,
- vanadyl species,
- propane,
- dehydrogenation
1. [1]
  CAVANI F, BALLARINI N, CERICOLA A. Oxidative dehydrogenation of ethane and propane: How far from commercial implementation?[J]. Catal Today,2007,127(1/4):113−131. doi: 10.1016/j.cattod.2007.05.009
2. [2]
  GARTNER C A, VAN VEEN A, LERCHER J A. Oxidative dehydrogenation of ethane: Common principles and mechanistic Aspects[J]. ChemCatChem,2013,5(11):3196−3217. doi: 10.1002/cctc.201200966
3. [3]
  CARRERO C A, SCHLOEGL R, WACHS I E, SCHOMAECKER R. Critical literature review of the kinetics for the oxidative dehydrogenation of propane over well-defined supported vanadium oxide catalysts[J]. ACS Catal,2014,4(10):3357−3380. doi: 10.1021/cs5003417
4. [4]
  JAMES O O, MANDA S, ALELE N, CHOWDHURY B, MAITY S. Lower alkanes dehydrogenation: Strategies and reaction routes to corresponding alkenes[J]. Fuel Process Technol,2016,149:239−255. doi: 10.1016/j.fuproc.2016.04.016
5. [5]
  LONG L L, XIA K, LANG W Z, SHEN L L, YANG Q, YAN X, GUO Y J. The comparison and optimization of zirconia, alumina, and zirconia-alumina supported PtSnIn trimetallic catalysts for propane dehydrogenation reaction[J]. J Ind Eng Chem,2017,51:271−280. doi: 10.1016/j.jiec.2017.03.012
6. [6]
  SOKOLOV S, BYCHKOV V Y, STOYANOVA M, RODEMERCK U, BENTRUP U, LINKE D, TYULENIN Y P, KORCHAK V N, KONDRATENKO E V. Effect of VO_x species and support on coke formation and catalyst stability in nonoxidative propane dehydrogenation[J]. ChemCatChem,2015,7(11):1691−1700.
7. [7]
  WACHS I E. Catalysis science of supported vanadium oxide catalysts[J]. Dalton Trans,2013,42:11762−11769. doi: 10.1039/c3dt50692d
8. [8]
  DONG A H, WANG K, ZHU S Z, YANG G B, WANG X T. Facile preparation of PtSn-La/Al₂O₃ catalyst with large pore size and its improved catalytic performance for isobutane dehydrogenation[J]. Fuel Process Technol,2017,158:218−225. doi: 10.1016/j.fuproc.2017.01.004
9. [9]
  HARLIN M E, NIEMI V M, KRAUSE A O. Alumina-supported vanadium oxide in the dehydrogenation of butanes[J]. J Catal,2000,195(1):67−78. doi: 10.1006/jcat.2000.2969
10. [10]
  LIU Y M, CA Y, YI N, FENG W L, DAI W L, YAN S R, HE H Y, FAN K N. Vanadium oxide supported on mesoporous SBA-15 as highly selective catalysts in the oxidative dehydrogenation of propane[J]. J Catal,2004,224(2):417−428. doi: 10.1016/j.jcat.2004.03.010
11. [11]
  REDDY B M, LAKSHMANAN P, LORIDANT S, YAMADA Y, KOBAYASHI T, LÓPEZ-CARTES C, ROJAS T C, FERNÁNDEZ A. Structural characterization and oxidative dehydrogenation activity of V₂O₅/Ce_xZr_1-xO₂/SiO₂ catalysts[J]. J Phys Chem B,2006,110(18):9140−9147. doi: 10.1021/jp061018k
12. [12]
  RAJU G, REDDY B M, PARK S E. CO₂ promoted oxidative dehydrogenation of n-butane over VO_x/MO₂-ZrO₂ (M=Ce or Ti) catalysts[J]. J CO₂ Util,2014,5:41−46. doi: 10.1016/j.jcou.2013.12.003
13. [13]
  ZHOU R, CAO Y, YAN S R, FAN K N. Rare earth (Y, La, Ce)-promoted V-HMS mesoporous catalysts for oxidative dehydrogenation of propane[J]. Appl Catal A: Gen,2002,236(1/2):103−111.
14. [14]
  SASIKALA R, SUDARSAN V, KULSHRESHTHA S K. Studies on the interaction of vanadia with modified silica supports and catalytic activity for oxidative dehydrogenation of propane: Effect of support modification by Al³⁺, Zr⁴⁺ or Y³⁺[J]. Eur J Inorg Chem,2006,2006(20):4151−4156.
15. [15]
  YANG S, IGLESIA E, BELL A T. Oxidative Dehydrogenation of Propane over V₂O₅/MoO₃/Al₂O₃ and V₂O₅/Cr₂O₃/Al₂O₃: Structural characterization and catalytic function[J]. J Phys Chem B,2005,109(18):8987−9000. doi: 10.1021/jp040708q
16. [16]
  AJAYI B P, JERMY B R, OGUNRONBI K E, ABUSSAUD B A, AL-KHATTAF S. n-Butane dehydrogenation over mono and bimetallic MCM-41 catalysts under oxygen free atmosphere[J]. Catal Today,2013,204:189−196. doi: 10.1016/j.cattod.2012.07.013
17. [17]
  ASCOOP I, GALVITA V V, ALEXOPOULOS K, REYNIERS M F, VAN DER VOORT P, BLIZNUK V, MARIN G B. The role of CO₂ in the dehydrogenation of propane over WO_x-VO_x/SiO₂[J]. J Catal,2016,335:1−10. doi: 10.1016/j.jcat.2015.12.015
18. [18]
  OYAMA S T, WENT G T, LEWIS K B, BELL A T, SOMORJAI G A. Oxygen-chemisorption and Laser Raman-spectroscopy of unsupported and silica-supported vanadium-oxide catalysts[J]. J Phys Chem,1989,93(18):6786−6790.
19. [19]
  WANG X, ZHOU G, CHEN Z, LI Q, ZHOU H, XU C. Enhancing the vanadium dispersion on V-MCM-41 by boron modification for efficient iso-butane dehydrogenation[J]. Appl Catal A: Gen,2018,555:171−177. doi: 10.1016/j.apcata.2018.02.021
20. [20]
  SHYLESH S, SINGH A. Vanadium-containing ordered mesoporous silicates: Does the silica source really affect the catalytic activity, structural stability, and nature of vanadium sites in V-MCM-41[J]? J Catal, 2005, 233(2): 359−371.
21. [21]
  WANG C B, DEO G, WACHS I E. Characterization of vanadia sites in V-silicalite, vanadia-silica cogel, and silica-supported Vanadia catalysts: X-ray powder diffraction, Raman Spectroscopy, Solid-State ⁵¹V NMR, Temperature-Programmed Reduction, and Methanol Oxidation Studies[J]. J Catal, 1998,1998,178(2):640−648.
22. [22]
  SOLSONA B, BLASCO T, LÓPEZ NIETO J M, PEñA M L, REY F, VIDAL-MOYA A. Vanadium oxide supported on mesoporous MCM-41 as selective catalysts in the oxidative dehydrogenation of alkanes[J]. J Catal,2001,203(2):443−452.
23. [23]
  WANG X, ZHOU G, CHEN Z, JIANG W, ZHOU H. In-situ synthesis and characterization of V-MCM-41 for oxidative dehydrogenation of n-butane[J]. Microporous Mesoporous Mater,2016,223:261−267.
24. [24]
  LIU Q L, YANG Z, LUO M S, ZHAO Z, WANG J Y, XIE Z A, GUO L. Vanadium-containing dendritic mesoporous silica nanoparticles: Multifunctional catalysts for the oxidative and non-oxidative dehydrogenation of propane to propylene[J]. Microporous Mesoporous Mater,2019,282:133−145.
25. [25]
  LI X K, JI W J, ZHAO J, ZHANG Z, AU C T. A comparison study on the partial oxidation of n-butane and propane over VPO catalysts supported on SBA-15, MCM-41, and fumed SiO₂[J]. Appl Catal A: Gen, 2006, 306: 8−16.
26. [26]
  ARIAS-PÉREZ S, GARCÍA-ALAMILLA R, CÁRDENAS-GALINDO M G, HANDY B E, ROBLES-ANDRADE S, SANDOVAL-ROBLES G. Evaluation of vanadium-phosphorus oxide (VPO) catalysts for the oxidative dehydrogenation of propane[J]. Ind Eng Chem Res,2009,48(3):1215−1219.
27. [27]
  BULÁNEK R, KALUŽOVÁA, SETNIČKA M, ZUKAL A, ČIČMANEC P, MAYEROVÁ J. Study of vanadium based mesoporous silicas for oxidative dehydrogenation of propane and n-butane[J]. Catal Today,2012,179(1):149−158.
28. [28]
  SETNIČKA M, BULÁNEK R, ČAPEK L, ČIČMANEC P. n-Butane oxidative dehydrogenation over VO_x-HMS catalyst[J]. J Mol Catal A: Chem,2011,344(1/2):1−10.
29. [29]
  SANTRA C, SHAH S, MONDAL A, PANDEY J K, PANDA A B, MAITY S, CHOWDHURY B. Synthesis, characterization of VPO catalyst dispersed on mesoporous silica surface and catalytic activity for cyclohexane oxidation reaction[J]. Microporous Mesoporous Mater,2016,223:121−128.
30. [30]
  PUTLURU S, RIISAGER A, FEHRMANN R. The effect of acidic and redox properties of V₂O₅/CeO₂-ZrO₂ catalysts in selective catalytic reduction of NO by NH₃[J]. Catal Lett,2009,133:370−375.
31. [31]
  HU P, LANG W Z, YAN X, CHU L F, GUO Y J. Influence of gelation and calcination temperature on the structure-performance of porous VO_x-SiO₂ solids in non-oxidative propane dehydrogenation[J]. J Catal,2018,358:108−117.
32. [32]
  ROSTOM S, DE LASA H I. Propane oxidative dehydrogenation using consecutive feed injections and fluidizable VO_x/gamma Al₂O₃ and VO_x/ZrO₂-gamma Al₂O₃ catalysts[J]. Ind Eng Chem Res,2017,56:13110−13125.
33. [33]
  WACHS I E, WECKHUYSEN B M. Vanadia catalysts for selective oxidation of hydrocarbons and their derivatives structure and reactivity of surface vanadium oxide species on oxide supports[J]. Appl Catal A: Gen,1997,157(1/2):67−90.
34. [34]
  CARRERO C A, KETURAKIS C J, ORREGO A, SCHOMACKER R, WACHS I E. Anomalous reactivity of supported V₂O₅ nanoparticles for propane oxidative dehydrogenation: Influence of the vanadium oxide precursor[J]. Dalton Trans,2013,42:12644−12653.
35. [35]
  MURGIA V, TORRES E, GOTTIFREDI J, SHAM E. Sol-gel synthesis of V₂O₅-SiO₂ catalyst in the oxidative dehydrogenation of n-butane[J]. Appl Catal A: Gen,2006,312:134−143.
36. [36]
  ARENA F, FRUSTERI F, MARTRA G, COLUCCIA S, PARMALIANA A. Surface structures, reduction pattern and oxygen chemisorption of V₂O₅/SiO₂catalysts[J]. J Chem Soc Faraday Trans,1997,93:3849−3854.
37. [37]
  FUKUDOME K, IKENAGA N, MIYAKE T, SUZUKI T. Oxidative dehydrogenation of propane using lattice oxygen of vanadium oxides on silica[J]. Catal Sci Technol,2011,1:987−998.
38. [38]
  BAI P, MA Z, LI T, TIAN Y, ZHANG Z, ZHONG Z, XING W, WU P, LIU X, YAN Z. Relationship between surface chemistry and catalytic performance of mesoporous γ-Al₂O₃ supported VO_x catalyst in catalytic dehydrogenation of propane[J]. ACS Appl Mater Interfaces,2016,8(39):25979−25990.
39. [39]
  TIAN Y P, BAI P, LIU S M, LIU X M, YAN Z F. VO_x-K₂O/γ-Al₂O₃ catalyst for nonoxidative dehydrogenation of isobutane[J]. Fuel Process Technol,2016,151:31−39.
40. [40]
  CHEN C, SUN M L, HU Z P, LIU Y P, ZHANG S M, YUAN Z Y. Nature of active phase of VO_x catalysts supported on SiBeta for direct dehydrogenation of propane propylene[J]. Chin J Catal,2020,41(2):276−285.
41. [41]
  CASALETTO M P, LISI L, MATTOGNO G, PATRONO P, RUOPPOLO G. An XPS study of titania-supported vanadyl phosphate catalysts for the oxidative dehydrogenation of ethane[J]. Appl Catal A: Gen,2004,267(1/2):157−164.
42. [42]
  HASHA D, SIERRA DE SALDARRIAGA L, SALDARRIAGA C, HATHAWAY P E, COX D F, DAVIS M E. Studies of silicoaluminophosphates with the sodalite structure[J]. J Am Chem Soc,1988,110:2127−2135.
43. [43]
  EBERHARDT M A, PROCTOR A, HOUALLA M, HERCULES D M. Investigation of V oxidation states in reduced V/Al₂O₃ catalysts by XPS[J]. J Catal,1996,160(1):27−34.
44. [44]
  GAO X, JEHNG J M, WACHS I E. In situ UV-vis-NIR diffuse reflectance and Raman spectroscopic studies of propane oxidation over ZrO₂-supported vanadium oxide catalysts[J]. J Catal,2002,209(1):43−50.
45. [45]
  RESINI C, MONTANARI T, BUSCA G, JEHNG J M, WACHS I E. Comparison of alcohol and alkane oxidative dehydrogenation reactions over supported vanadium oxide catalysts: in situ infrared, Raman and UV-vis spectroscopic studies of surface alkoxide intermediates and of their surface chemistry[J]. Catal Today,2005,99(1/2):105−114.
46. [46]
  DZWIGAJ S. Recent advances in the incorporation and identification of vanadium species in microporous materials[J]. Curr Opin Solid State Mater Sci,2003,7(6):461−470.
47. [47]
  PIUMETTI M, BONELLI B, MASSIANI P, DZWIGAJ S, ROSSETTI I, CASALE S, GABEROVA L, ARMANDI M, GARRONE E. Effect of vanadium dispersion and support properties on the catalytic activity of V-SBA-15 and V-MCF mesoporous materials prepared by direct synthesis[J]. Catal Today,2011,176(1):458−464.
48. [48]
  CHRISTODOULAKIS A. Molecular structure and reactivity of vanadia-based catalysts for propane oxidative dehydrogenation studied by in situ Raman spectroscopy and catalytic activity measurements[J]. J Catal,2004,222(2):293−306.
49. [49]
  RODEMERCK U, SOKOLOV S, STOYANOVA M, BENTRUP U, LINKE D, KONDRATENKO E V. Influence of support and kind of VO_x species on isobutene selectivity and coke deposition in non-oxidative dehydrogenation of isobutane[J]. J Catal,2016,338:174−183.
50. [50]
  OVSITSER O, SCHOMAECKER R, KONDRATENKO E V, WOLFRAM T, TRUNSCHKE A. Highly selective and stable propane dehydrogenation to propene over dispersed VO_x-species under oxygen-free and oxygen-lean conditions[J]. Catal Today,2012,192(1):16−19.
1. [1]
  Tianyi Yang , Fangxi Su , Dehuan Shi , Shenghong Zhong , Yalin Guo , Zhaohui Liu , Jianfeng Huang . Efficient propane dehydrogenation catalyzed by Ru nanoparticles anchored on a porous nitrogen-doped carbon matrix. Chinese Chemical Letters, 2025, 36(2): 110444-. doi: 10.1016/j.cclet.2024.110444
2. [2]
  Kun Yang , Anhui Li , Peng Zhang , Guilin Liu , Liusai Huang , Yumeng Fo , Luyuan Yang , Xiangyang Ji , Jian Liu , Weiyu Song . Hierarchical zeolites stabilized cobalt(Ⅱ) as propane dehydrogenation catalyst: Enhanced activity and coke tolerance via alkaline post-treatment. Chinese Chemical Letters, 2025, 36(5): 110663-. doi: 10.1016/j.cclet.2024.110663
3. [3]
  Naihong Wang , Longkang Zhang , Yejun Guan , Peng Wu , Hao Xu . Pt confined in Sn-ECNU-46 zeolite for efficient alkane dehydrogenation. Chinese Journal of Structural Chemistry, 2024, 43(4): 100248-100248. doi: 10.1016/j.cjsc.2024.100248
4. [4]
  Yixin Lu , Minghan Qin , Shixian Zhang , Zhen Liu , Wang Sun , Zhenhua Wang , Jinshuo Qiao , Kening Sun . Triple-conducting heterostructure anodes for electrochemical ethane nonoxidative dehydrogenation by protonic ceramic electrolysis cells. Chinese Chemical Letters, 2025, 36(4): 110567-. doi: 10.1016/j.cclet.2024.110567
5. [5]
  Xiangyang Ji , Yishuang Chen , Peng Zhang , Shaojia Song , Jian Liu , Weiyu Song . Boosting the first C–H bond activation of propane on rod-like V/CeO₂ catalyst by photo-assisted thermal catalysis. Chinese Chemical Letters, 2025, 36(5): 110719-. doi: 10.1016/j.cclet.2024.110719
6. [6]
  Yiyue Ding , Qiuxiang Zhang , Lei Zhang , Qilu Yao , Gang Feng , Zhang-Hui Lu . Exceptional activity of amino-modified rGO-immobilized PdAu nanoclusters for visible light-promoted dehydrogenation of formic acid. Chinese Chemical Letters, 2024, 35(7): 109593-. doi: 10.1016/j.cclet.2024.109593
7. [7]
  Yu-Hui Zhang , Ye Tian , Xianliang Sheng , Chen-Shuang Liu , Lu-Qiang Wei , Jie Wang , Yong Chen . Construction of a black phosphorous-based noncovalent multiple nanosupramolecular assembly for synergistic targeted photothermal and chemodynamic therapy. Chinese Chemical Letters, 2025, 36(4): 110193-. doi: 10.1016/j.cclet.2024.110193
8. [8]
  Guoliang Liu , Zhiqiang Liu , Anmin Zheng . Modulation of zeolite surface realizes dynamic copper species redispersion. Chinese Journal of Structural Chemistry, 2024, 43(6): 100308-100308. doi: 10.1016/j.cjsc.2024.100308
9. [9]
  Zhongyu Wang , Lijun Wang , Huaixin Zhao . DNA-based nanosystems to generate reactive oxygen species for nanomedicine. Chinese Chemical Letters, 2024, 35(11): 109637-. doi: 10.1016/j.cclet.2024.109637
10. [10]
  Wenbi Wu , Yinchu Dong , Haofan Liu , Xuebing Jiang , Li Li , Yi Zhang , Maling Gou . Modification of plasma protein for bioprinting via photopolymerization. Chinese Chemical Letters, 2024, 35(8): 109260-. doi: 10.1016/j.cclet.2023.109260
11. [11]
  Ji Zhang , Tong Zhang , Qiao An , Peng Zhang , Cai-Yan Tian , Chun-Mao Yuan , Ping Yi , Zhan-Xing Hu , Xiao-Jiang Hao . Five quinolizidine alkaloids with anti-tobacco mosaic virus activities from two species of Sophora. Chinese Chemical Letters, 2024, 35(6): 108927-. doi: 10.1016/j.cclet.2023.108927
12. [12]
  Yuanyi Zhou , Ke Ma , Jinfeng Liu , Zirun Zheng , Bo Hu , Yu Meng , Zhizhong Li , Mingshan Zhu . Is reactive oxygen species the only way for cancer inhibition over single atom nanomedicine? Autophagy regulation also works. Chinese Chemical Letters, 2024, 35(6): 109056-. doi: 10.1016/j.cclet.2023.109056
13. [13]
  Li Li , Fanpeng Chen , Bohang Zhao , Yifu Yu . Understanding of the structural evolution of catalysts and identification of active species during CO₂ conversion. Chinese Chemical Letters, 2024, 35(4): 109240-. doi: 10.1016/j.cclet.2023.109240
14. [14]
  Chi Zhang , Ning Ding , Yuwei Pan , Lichun Fu , Ying Zhang . The degradation pathways of contaminants by reactive oxygen species generated in the Fenton/Fenton-like systems. Chinese Chemical Letters, 2024, 35(10): 109579-. doi: 10.1016/j.cclet.2024.109579
15. [15]
  Haixian Ren , Yuting Du , Xiaojing Yang , Fangjun Huo , Le Zhang , Caixia Yin . Development of ESIPT-based specific fluorescent probes for bioactive species based on the protection-deprotection of the hydroxyl. Chinese Chemical Letters, 2025, 36(2): 109867-. doi: 10.1016/j.cclet.2024.109867
16. [16]
  Hui Zhang , Rong Feng , Wanyi Yu , Hongbei Wei , Tianhong Wu , Peng Zhang , Wenhai Bian , Xin Li , Di Gao , Guojun Weng , Zhe Yang , Tony D. James , Xiaolong Sun . Evaluating the global thiols redox state in living cells using a reducing sulfur species responsive fluorescence switching platform. Chinese Chemical Letters, 2025, 36(4): 110528-. doi: 10.1016/j.cclet.2024.110528
17. [17]
  Lijun Mao , Shuo Li , Xin Zhang , Zhan-Ting Li , Da Ma . Cucurbit[n]uril-based nanostructure construction and modification. Chinese Chemical Letters, 2024, 35(8): 109363-. doi: 10.1016/j.cclet.2023.109363
18. [18]
  Fangling Cui , Zongjie Hu , Jiayu Huang , Xiaoju Li , Ruihu Wang . MXene-based materials for separator modification of lithium-sulfur batteries. Chinese Journal of Structural Chemistry, 2024, 43(7): 100337-100337. doi: 10.1016/j.cjsc.2024.100337
19. [19]
  Chenghao Ge , Peng Wang , Pei Yuan , Tai Wu , Rongjun Zhao , Rong Huang , Lin Xie , Yong Hua . Tuning hot carrier transfer dynamics by perovskite surface modification. Chinese Chemical Letters, 2024, 35(10): 109352-. doi: 10.1016/j.cclet.2023.109352
20. [20]
  Yue Pan , Wenping Si , Yahao Li , Haotian Tan , Ji Liang , Feng Hou . Promoting exciton dissociation by metal ion modification in polymeric carbon nitride for photocatalysis. Chinese Chemical Letters, 2024, 35(12): 109877-. doi: 10.1016/j.cclet.2024.109877

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(112)
HTML views(3)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142