Citation: Ying-jian SONG, Xiao-jing CUI, Tian-sheng DENG, Zhang-feng QIN, Wei-bin FAN. Solvent effect on the activity of Ru-Co₃O₄ catalyst for liquid-phase hydrogenation of CO₂ into methane[J]. Journal of Fuel Chemistry and Technology, ;2021, 49(2): 178-185. doi: 10.1016/S1872-5813(21)60013-0 shu

Solvent effect on the activity of Ru-Co₃O₄ catalyst for liquid-phase hydrogenation of CO₂ into methane

1.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China
3.
Department of Chemistry and Chemical Engineering, Taiyuan Institute of Technology, Taiyuan 030008, China

Corresponding author: Xiao-jing CUI, cuixj@sxicc.ac.cn Wei-bin FAN, fanwb@sxicc.ac.cn
Received Date: 14 August 2020
Revised Date: 2 November 2020

Figures(7)

Ru-Co₃O₄ catalyst was prepared by the co-precipitation method. Its catalytic performance in liquid-phase hydrogenation of CO₂into methane was investigated, and compared with those of the conventional Ru-based catalysts (Ru/SiO₂, Ru/CeO₂, Ru/ZrO₂, Ru/TiO₂) prepared by impregnation method. The solvents including H₂O, n-butanol, 1,4-butyrolactone, DMF, n-nonane, decalin, cyclohexane and isooctane had significant solvent effects on the catalytic performance. Compared with other solvents, the catalyst showed higher activity and selectivity catalytic performance when decalin and isooctane was applied as the solvent. At 200 °C and H₂/CO₂=3:1 (v/v, 4 MPa) and with decalin as the solvent, the conversion of CO₂ and the selectivity of CH₄reached 45.6% and 97%, respectively. The isotope labeling experiments and in-situ diffuse reflectance infrared spectra showed that the hydrogen atoms of the tertiary carbon in decalin and isooctane were active for CO₂ hydrogenation reaction, thus improving the catalytic activity.
- carbon dioxide,
- liquid-phase hydrogenation,
- methane,
- solvent effect,
- hydrogen supply
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沈阳化工大学材料科学与工程学院沈阳 110142

Solvent effect on the activity of Ru-Co3O4 catalyst for liquid-phase hydrogenation of CO2 into methane

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通讯作者: 陈斌, bchen63@163.com

Solvent effect on the activity of Ru-Co₃O₄ catalyst for liquid-phase hydrogenation of CO₂ into methane