Citation: WANG Ying-wen, ZHANG Ya-jing, WANG Kang-jun, TAN Li-mei, CHEN Shu-ying. Preparation of Ni/SiO₂ by ammonia evaporation method for synthesis of 2-MTHF from 2-MF hydrogenation[J]. Journal of Fuel Chemistry and Technology, ;2021, 49(1): 97-103. doi: 10.1016/S1872-5813(21)60007-5 shu

Preparation of Ni/SiO₂ by ammonia evaporation method for synthesis of 2-MTHF from 2-MF hydrogenation

College of Chemical Engineering, Shenyang University of Chemical Technology, Shenyang 110142, China

Corresponding author: ZHANG Ya-jing, yjzhang2009@163.com WANG Kang-jun, angle_79@163.com
Received Date: 18 February 2020
Revised Date: 11 November 2020

Fund Project: The project was supported by National Natural Science Foundation of Liaoning Province (2019-ZD-0077), Liaoning Revitalization Talents Program (XLYC1907029), Science Research Foundation of Education Department of Liaoning Province (LQ2020026, LZ2019003), and Liaoning Innovation Talents Program in University

Figures(8)

The Ni/SiO₂ catalysts were prepared by ammonia evaporation method, with nickel nitrate as Ni source and silica sol as the SiO₂ source, for synthesis of 2-MTHF from 2-MF hydrogenation. The catalytic performance of catalysts prepared at different calcination temperatures were tested on a fixed-bed reactor. XRD, N₂ adsorption-desorption, H₂-TPR, NH₃-TPD, XPS and TG were employed to characterize the structure and surface properties of these catalysts. The effect of calcination temperature on the structure, surface property and catalytic performance of catalysts were investigated. The result indicated that all the catalysts had a phyllosilicate structure after calcination, and maintained the structure after reduction. Ni particles dispersed well with smaller size and strong metal support interaction showed high activity. The surface acidity of catalysts was influenced by the calcination temperature. The maximum catalytic activity and selectivity were obtained on the catalyst calcined by at 500 ℃, which exhibited a 2-MF conversion of 100% and the 2-MTHF selectivity of 93.5% at the optimized condition, due to smaller particle size and suitable surface acidity.
- 2-methylfuran,
- 2-methyltetrahydrofuran,
- ammonia evaporation,
- hydrogenation,
- Ni/SiO₂ catalysts
1. [1]
  GUO Qing-quan, CHEN Huan-qin. Development on prepartion of levulinic acid and its derivatives[J]. Spec Petrochem,2003,20(3):45−48. doi: 10.3969/j.issn.1003-9384.2003.03.016
2. [2]
  RAGAN J A, ENDE D J, BRENEK S J, EISENBEIS S A, SINGER R A, TICKNER D L, TEIXEIRA J J, VANDERPLAS B C, WESTONET N. Safe execution of a large-scale ozonolysis: Preparation of the bisulfite adduct of 2-hydroxyindan-2-carboxaldehyde and its utility in a reductive amination[J]. Org Process Res Dev,2003,7(2):155−160. doi: 10.1021/op0202235
3. [3]
  YANG J, ZHENG H, ZHU Y, ZHAO G, ZHANG C, TENG B, XIANG H, LI Y. Effects of calcination temperature on performance of Cu-Zn-Al catalyst for synthesizing c-butyrolactone and 2-methylfuran through the coupling of dehydrogenation and hydrogenation[J]. Catal Commun,2004,5(9):505−510. doi: 10.1016/j.catcom.2004.06.005
4. [4]
  XIN Bing-wei, QU Li-qiang, SUN Chang-jun. Progress on synthesis of Effect of 2-methytetrahydrofuran[J]. Shangdong Chem Ind,2003,32:13−15.
5. [5]
  DONALD B D, DOROTHY Z D, JOHN J G. Cyclodehydration of 1, 4-butanediols by pentaethoxy-phosphorane[J]. J Org Chem,1984,49:2831−2832. doi: 10.1021/jo00189a044
6. [6]
  SANEO J, FUKUMOTO T, NAKAO K. Cyclic ethers from lactones, Japan: 7333745 [P].
7. [7]
  DONG F, ZHU Y, DING G. One-step conversion of furfural into 2-methyltetrahydrofuran under mild conditions[J]. Chem Sus Chem,2015,8(9):1534−1537. doi: 10.1002/cssc.201500178
8. [8]
  MASAAKI Y, RYOZI H. Preparation of dihydropyran from furfural[J]. Kôgakuin Daigaku Kenkyû Hôkoku,1954,1:76.
9. [9]
  PROSKURYAKOV V A, IVANOV P A, GENUSOV M L. Hydrogenation of furfural under pressure[J]. Trudy Leningrad Tekhnol Inst Im Lensoveta,1958,44:3−5.
10. [10]
  LI Zeng-jie, HUANG Yu-hui, ZHU Ming. Catalytic performance of Ni/Al₂O₃ catalyst for hydrogenation of 2-methylfuran to 2-methyltetrahydrofuran[J]. J Fuel Chem Technol,2018,46(1):54−58. doi: 10.3969/j.issn.0253-2409.2018.01.007
11. [11]
  DING F, ZHANG Y. Synthesis and catalytic performance of Ni/SiO₂ for hydrogenation of 2-methylfuran to 2-methyltetrahydrofuran[J]. J Nanomater,2015.
12. [12]
  ASHOK J, KATHIRASER Y, ANG M L, KAWI S. Ni and/or Ni-Cu alloys supported over SiO₂ catalysts synthesized via phyllosilicate structures for steam reforming of biomass tar reaction[J]. Catal Sci & Technol,2015, 5:4398−4409.
13. [13]
  ZHANG H, GAO X, MA Y, HAN X, NIU L, BAI G. A highly dispersed and stable Ni/mSiO₂-AE nanocatalyst for benzoic acid hydrogenation[J]. Catal Sci Technol,2017,7:5993−5999.
14. [14]
  THOMMES M, KANEKO K, NEIMARK A V. Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report)[J]. Pure Appl Chem,2015,87(9/10):1051−1069. doi: 10.1515/pac-2014-1117
15. [15]
  CYCHOSZ K A, NICOLAS R G, MARTNEZ J G. Recent advances in the textural characterization of hierarchically structured nanoporous materials[J]. Chem Soc Rev,2017,46:389−414. doi: 10.1039/C6CS00391E
16. [16]
  CHEN L, GUO P, QIAO M. Cu/SiO₂ catalysts prepared by the ammonia-evaporation method: Texture, structure, and catalytic performance in hydrogenation of dimethyl oxalate to ethylene glycol[J]. J Catal,2008,257(1):172−180. doi: 10.1016/j.jcat.2008.04.021
17. [17]
  KONG X, ZHU Y, ZHENG H. Ni Nanoparticles Inlaid Nickel Phyllosilicate as a metal-acid bifunctional catalyst for low-temperature hydrogenolysis reactions[J]. ACS Catal,2015,5:5914−5920. doi: 10.1021/acscatal.5b01080
18. [18]
  DONG F, DING G, ZHENG H. Highly dispersed Cu nanoparticles as an efficient catalyst for the synthesis of the biofuel 2-methylfuran[J]. Catal Sci Technol,2016,6:767−779. doi: 10.1039/C5CY00857C
19. [19]
  LI Z, MO L, KATHIRASER Y. Yolk-Satellite-Shell structured Ni-Yolk@Ni@SiO₂ nanocomposite: Superb catalyst toward methane CO₂ reforming reaction[J]. ACS Catal,2014,4(5):1526−1536. doi: 10.1021/cs401027p
20. [20]
  SUN K Q, MARCEAU E, CHE M. Evolution of nickel speciation during preparation of Ni-SiO₂ catalysts: Effect of the number of chelating ligands in [Ni(en)_x(H₂O)_6−2x]²⁺ precursor complexes[J]. Phys Chem Chem Phys,2006,8(14):1731−1738. doi: 10.1039/b513319j
21. [21]
  ZHANG C, ZHU W, LI S. Sintering-resistant Ni-based reforming catalysts obtained via the nanoconfinement effect[J]. Chem Commun,2013,49:9383−9385. doi: 10.1039/c3cc43895c
22. [22]
  BURATTIN P, CHE M, LOUIS C. Ni/SiO₂ Materials prepared by deposition-precipitation: Influence of the reduction conditions and mechanism of formation of metal particles[J]. J Phys Chem B,2000,104(45):10482−10489. doi: 10.1021/jp0003151
23. [23]
  LIU Ji, WANG Dong-xu, XIAO Xian-bin. Effect of calcination temperature on Ni/γ-Al₂O₃ reduction and catalytic steam reforming of toluene[J]. J Fuel Chem Technol,2014,42(10):1225−1232. doi: 10.3969/j.issn.0253-2409.2014.10.011
24. [24]
  GILKEY M J, PANAGIOTOPOULOU P, MIRONENKO A V, JENNESS G R, VALCHOS DG, XU B[J]. ACS Catal, 2015, 5: 3988-3994.
25. [25]
  SELVAM P, VISWANNATHAN B, SRINIVASAN V. XPS studies of the surface properties of CaNi₅[J]. J Electron Spectrosc Relat Phemon,1989,49:203−211. doi: 10.1016/0368-2048(89)85009-1
1. [1]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Fei Liu . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 100036-. doi: 10.3866/PKU.WHXB202408004
2. [2]
  Yifeng TAN , Ping CAO , Kai MA , Jingtong LI , Yuheng WANG . Synthesis of pentaerythritol tetra(2-ethylthylhexoate) catalyzed by h-MoO₃/SiO₂. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2155-2162. doi: 10.11862/CJIC.20240147
3. [3]
  Liuyun Chen , Wenju Wang , Tairong Lu , Xuan Luo , Xinling Xie , Kelin Huang , Shanli Qin , Tongming Su , Zuzeng Qin , Hongbing Ji . Soft template-induced deep pore structure of Cu/Al₂O₃ for promoting plasma-catalyzed CO₂ hydrogenation to DME. Acta Physico-Chimica Sinica, 2025, 41(6): 100054-. doi: 10.1016/j.actphy.2025.100054
4. [4]
  Aiyi Xin , Jiawei Li , Xinyang Ran , Chuanjiang Fu , Zhiguo Wang . Collaborative Science and Education Based Experimental Design in Organic Chemistry: A Case Study of the Nucleophilic Substitution Reaction of 2-Hydroxymethyl-4,6-Di-Tert-Butylphenol. University Chemistry, 2025, 40(5): 366-375. doi: 10.12461/PKU.DXHX202407031
5. [5]
  Guang-Xu Duan , Queting Chen , Rui-Rui Shao , Hui-Huang Sun , Tong Yuan , Dong-Hao Zhang . Encapsulating lipase on the surface of magnetic ZIF-8 nanosphers with mesoporous SiO₂ nano-membrane for enhancing catalytic performance. Chinese Chemical Letters, 2025, 36(2): 109751-. doi: 10.1016/j.cclet.2024.109751
6. [6]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
7. [7]
  Xinpin Pan , Yongjian Cui , Zhe Wang , Bowen Li , Hailong Wang , Jian Hao , Feng Li , Jing Li . Robust chemo-mechanical stability of additives-free SiO₂ anode realized by honeycomb nanolattice for high performance Li-ion batteries. Chinese Chemical Letters, 2024, 35(10): 109567-. doi: 10.1016/j.cclet.2024.109567
8. [8]
  Anqiu LIU , Long LIN , Dezhi ZHANG , Junyu LEI , Kefeng WANG , Wei ZHANG , Junpeng ZHUANG , Haijun HAO . Synthesis, structures, and catalytic activity of aluminum and zinc complexes chelated by 2-((2,6-dimethylphenyl)amino)ethanolate. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 791-798. doi: 10.11862/CJIC.20230424
9. [9]
  Kangmin Wang , Liqiu Wan , Jingyu Wang , Chunlin Zhou , Ke Yang , Liang Zhou , Bijin Li . Multifunctional 2-(2′-hydroxyphenyl)benzoxazoles: Ready synthesis, mechanochromism, fluorescence imaging, and OLEDs. Chinese Chemical Letters, 2024, 35(10): 109554-. doi: 10.1016/j.cclet.2024.109554
10. [10]
  Rui HUANG , Shengjie LIU , Qingyuan WU , Nanfeng ZHENG . Enhanced selectivity of catalytic hydrogenation of halogenated nitroaromatics by interfacial effects. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 201-212. doi: 10.11862/CJIC.20240356
11. [11]
  Yuexiang Liu , Xiangqiao Yang , Tong Lin , Guantian Yang , Xiaoyong Xu , Bubing Zeng , Zhong Li , Weiping Zhu , Xuhong Qian . Efficient continuous synthesis of 2-[3-(trifluoromethyl)phenyl]malonic acid, a key intermediate of Triflumezopyrim, coupling with esterification-condensation-hydrolysis. Chinese Chemical Letters, 2025, 36(1): 109747-. doi: 10.1016/j.cclet.2024.109747
12. [12]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
13. [13]
  Yue Li , Minghao Fan , Conghui Wang , Yanxun Li , Xiang Yu , Jun Ding , Lei Yan , Lele Qiu , Yongcai Zhang , Longlu Wang . 3D layer-by-layer amorphous MoS_x assembled from [Mo₃S₁₃]^2- clusters for efficient removal of tetracycline: Synergy of adsorption and photo-assisted PMS activation. Chinese Chemical Letters, 2024, 35(9): 109764-. doi: 10.1016/j.cclet.2024.109764
14. [14]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
15. [15]
  Maomao Liu , Guizeng Liang , Ningce Zhang , Tao Li , Lipeng Diao , Ping Lu , Xiaoliang Zhao , Daohao Li , Dongjiang Yang . Electron-rich Ni2+ in Ni3S2 boosting electrocatalytic CO2 reduction to formate and syngas. Chinese Journal of Structural Chemistry, 2024, 43(8): 100359-100359. doi: 10.1016/j.cjsc.2024.100359
16. [16]
  Fan Wu , Wenchang Tian , Jin Liu , Qiuting Zhang , YanHui Zhong , Zian Lin . Core-Shell Structured Covalent Organic Framework-Coated Silica Microspheres as Mixed-Mode Stationary Phase for High Performance Liquid Chromatography. University Chemistry, 2024, 39(11): 319-326. doi: 10.12461/PKU.DXHX202403031
17. [17]
  Xiangyuan Zhao , Jinjin Wang , Jinzhao Kang , Xiaomei Wang , Hong Yu , Cheng-Feng Du . Ni nanoparticles anchoring on vacuum treated Mo2TiC2Tx MXene for enhanced hydrogen evolution activity. Chinese Journal of Structural Chemistry, 2023, 42(10): 100159-100159. doi: 10.1016/j.cjsc.2023.100159
18. [18]
  Qin Hu , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Ni掺杂构建电子桥及激活MoS₂惰性基面增强光催化分解水产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-. doi: 10.3866/PKU.WHXB202406024
19. [19]
  Hao GUO , Tong WEI , Qingqing SHEN , Anqi HONG , Zeting DENG , Zheng FANG , Jichao SHI , Renhong LI . Electrocatalytic decoupling of urea solution for hydrogen production by nickel foam-supported Co₉S₈/Ni₃S₂ heterojunction. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2141-2154. doi: 10.11862/CJIC.20240085
20. [20]
  Hongye Bai , Lihao Yu , Jinfu Xu , Xuliang Pang , Yajie Bai , Jianguo Cui , Weiqiang Fan . Controllable Decoration of Ni-MOF on TiO2: Understanding the Role of Coordination State on Photoelectrochemical Performance. Chinese Journal of Structural Chemistry, 2023, 42(10): 100096-100096. doi: 10.1016/j.cjsc.2023.100096

Get Citation

PDF

XML

Metrics

PDF Downloads(14)
Abstract views(2931)
HTML views(735)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of Ni/SiO2 by ammonia evaporation method for synthesis of 2-MTHF from 2-MF hydrogenation

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation of Ni/SiO₂ by ammonia evaporation method for synthesis of 2-MTHF from 2-MF hydrogenation