Citation: WANG Ying-wen, ZHANG Ya-jing, WANG Kang-jun, TAN Li-mei, CHEN Shu-ying. Preparation of Ni/SiO₂ by ammonia evaporation method for synthesis of 2-MTHF from 2-MF hydrogenation[J]. Journal of Fuel Chemistry and Technology, ;2021, 49(1): 97-103. doi: 10.1016/S1872-5813(21)60007-5 shu

Preparation of Ni/SiO₂ by ammonia evaporation method for synthesis of 2-MTHF from 2-MF hydrogenation

College of Chemical Engineering, Shenyang University of Chemical Technology, Shenyang 110142, China

Corresponding author: ZHANG Ya-jing, yjzhang2009@163.com WANG Kang-jun, angle_79@163.com
Received Date: 18 February 2020
Revised Date: 11 November 2020

Fund Project: The project was supported by National Natural Science Foundation of Liaoning Province (2019-ZD-0077), Liaoning Revitalization Talents Program (XLYC1907029), Science Research Foundation of Education Department of Liaoning Province (LQ2020026, LZ2019003), and Liaoning Innovation Talents Program in University

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The Ni/SiO₂ catalysts were prepared by ammonia evaporation method, with nickel nitrate as Ni source and silica sol as the SiO₂ source, for synthesis of 2-MTHF from 2-MF hydrogenation. The catalytic performance of catalysts prepared at different calcination temperatures were tested on a fixed-bed reactor. XRD, N₂ adsorption-desorption, H₂-TPR, NH₃-TPD, XPS and TG were employed to characterize the structure and surface properties of these catalysts. The effect of calcination temperature on the structure, surface property and catalytic performance of catalysts were investigated. The result indicated that all the catalysts had a phyllosilicate structure after calcination, and maintained the structure after reduction. Ni particles dispersed well with smaller size and strong metal support interaction showed high activity. The surface acidity of catalysts was influenced by the calcination temperature. The maximum catalytic activity and selectivity were obtained on the catalyst calcined by at 500 ℃, which exhibited a 2-MF conversion of 100% and the 2-MTHF selectivity of 93.5% at the optimized condition, due to smaller particle size and suitable surface acidity.
- 2-methylfuran,
- 2-methyltetrahydrofuran,
- ammonia evaporation,
- hydrogenation,
- Ni/SiO₂ catalysts
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of Ni/SiO2 by ammonia evaporation method for synthesis of 2-MTHF from 2-MF hydrogenation

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通讯作者: 陈斌, bchen63@163.com

Preparation of Ni/SiO₂ by ammonia evaporation method for synthesis of 2-MTHF from 2-MF hydrogenation