Citation: Bing Xue, Ye Chen, Yin Hong, Ding-Yang Ma, Jie Xu, Yong-Xin Li. Facile synthesis of Fe-containing graphitic carbon nitride materials and their catalytic application in direct hydroxylation of benzene to phenol[J]. Chinese Journal of Catalysis, ;2018, 39(7): 1263-1271. doi: 10.1016/S1872-2067(18)63063-3 shu

Facile synthesis of Fe-containing graphitic carbon nitride materials and their catalytic application in direct hydroxylation of benzene to phenol

Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, School of Petrochemical Engineering, Changzhou University, Changzhou 213164, Jiangsu, China

Received Date: 19 January 2018
Revised Date: 19 March 2018

Fund Project: This work was supported by the National Natural Science Foundation of China (21673024), Advanced Catalysis and Green Manufacturing Collabora-tive Innovation Center (ACGM2016-06-28), Foundation of State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering (2017-K28), and the Top-notch Academic Programs Project of Jiangsu Higher Education Institutions (PPZY2015B145).

Fe-containing graphitic carbon nitride (Fe-g-C₃N₄) materials were synthesized via one-step pyrolysis of FeCl₃ and dicyandiamide. The physicochemical properties of the synthesized Fe-g-C₃N₄ samples were characterized by N₂ adsorption-desorption, X-ray diffraction, thermal gravimetric, Fourier transform infrared, UV-vis diffuse reflectance, X-ray photoelectron spectroscopy, and transmission electron microscopy. The Fe cations were anchored by nitrogen-rich g-C₃N₄, whereas the graphitic structures of g-C₃N₄ were retained after the introduction of Fe. As heterogeneous catalysts, Fe-g-C₃N₄ exhibited good catalytic activity in the direct hydroxylation of benzene to phenol with H₂O₂, affording a maximum yield of phenol of up to 17.5%. Compared with other Fe-and V-containing g-C₃N₄ materials, Fe-g-C₃N₄ features a more convenient preparation procedure and higher catalytic productivity of phenol.
- Benzene,
- Hydroxylation,
- Graphitic carbon nitride,
- Phenol
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