Citation: Ni Wang, Haoquan Zheng, Wei Zhang, Rui Cao. Mononuclear first-row transition-metal complexes as molecular catalysts for water oxidation[J]. Chinese Journal of Catalysis, ;2018, 39(2): 228-244. doi: 10.1016/S1872-2067(17)63001-8 shu

Mononuclear first-row transition-metal complexes as molecular catalysts for water oxidation

Ni Wang ^a, ,
Haoquan Zheng ^a ,
Wei Zhang ^a ,
Rui Cao ^a,b

a Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710119, Shaanxi, China;
b Department of Chemistry, Renmin University of China, Beijing 100872, China

Received Date: 6 November 2017
Revised Date: 15 December 2017

Fund Project: This work was supported by Thousand Talents Program of China, the National Natural Science Foundation of China (21101170, 21573139, and 21773146), the Fundamental Research Funds for the Central Universities, and the Research Funds of Shaanxi Normal University.

Water oxidation is significant in both natural and artificial photosynthesis. In nature, water oxidation occurs at the oxygen-evolving center of photosystem Ⅱ, and leads to the generation of oxygen, protons, and electrons. The last two are used for fixation of carbon dioxide to give carbohydrates. In artificial processes, the coupling of water oxidation to evolve O₂ and water reduction to evolve H₂ is known as water splitting, which is an attractive method for solar energy conversion and storage. Because water oxidation is a thermodynamically uphill reaction and is kinetically slow, this reaction causes a bottleneck in large-scale water splitting. As a consequence, the development of new and efficient water oxidation catalysts (WOCs) has attracted extensive attention. Recent efforts have identified a variety of mononuclear earth-abundant transition-metal complexes as active and stable molecular WOCs. This review article summarizes recent progress in research on mononuclear catalysts that are based on first-row transition-metal elements, namely manganese, iron, cobalt, nickel, and copper. Particular attention is paid to catalytic mechanisms and the key O-O bond formation steps. This information is critical for designing new catalysts that are highly efficient and stable.
- Water oxidation,
- O-O bond formation,
- Oxygen evolution,
- First-row transition metal,
- Electrocatalysis
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