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Citation: Tiejing Hu, Jian Liu, Changyan Cao, Weiguo Song. Synthesis of ZSM-5 monoliths with hierarchical porosity through a steam-assisted crystallization method using sponges as scaffolds[J]. Chinese Journal of Catalysis, ;2017, 38(5): 872-878. doi: 10.1016/S1872-2067(17)62828-6 shu

Synthesis of ZSM-5 monoliths with hierarchical porosity through a steam-assisted crystallization method using sponges as scaffolds

Beijing National Laboratory for Molecular Sciences, Laboratory for Molecular Nanostructures and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China;University of Chinese Academy of Sciences, Beijing 100049, China

Received Date: 24 February 2017
Revised Date: 27 March 2017

Fund Project: This work was supported by the National Natural Science Foundation of China (21333009) and the Youth Innovation Promotion Association of CAS (2017049).

Self-supporting ZSM-5 crystals with hierarchical porosity were prepared through a steam-assisted crystallization method using sponges as rigid scaffolds. The synthesized materials were characterized by X-ray diffraction, nitrogen sorption, scanning electron microscopy, transmission electron microscopy, solid-state nuclear magnetic resonance spectroscopy and ammonia temperature-programmed desorption. The ZSM-5 monoliths exhibited high crystallinities, hierarchical porous structures and strong acidities. They showed superior catalytic performance in the liquid-phase esterification reaction between benzyl alcohol and hexanoic acid.
- Hierarchically porous structure,
- Zeolite,
- Steam-assisted crystallization,
- Acidity
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