Citation: Kamlesh N.Tayade, Lianyue Wang, Sensen Shang, Wen Dai, Manish Mishra, Shuang Gao. Zirconium triflate grafted on SBA-15 as a highly efficient solid acid catalyst for ring opening of epoxides by amines and alcohols[J]. Chinese Journal of Catalysis, ;2017, 38(4): 758-766. doi: 10.1016/S1872-2067(17)62794-3 shu

Zirconium triflate grafted on SBA-15 as a highly efficient solid acid catalyst for ring opening of epoxides by amines and alcohols

a Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
b Department of Chemical Engineering And Shah-Schulman Center for Surface Science and Nanotechnology, Faculty of Technology, Dharmsinh Desai University, Nadiad 387001, Gujarat, India

Received Date: 21 November 2016
Revised Date: 6 January 2017

Fund Project: This work was supported by the CAS President's International Fellowship Initiative (2016PT028) and the National Natural Science Foundation of China (21273225 and 21403219).

Metal (Al, Ti, Zr) triflate grafted mesoporous SBA-15 (AlTf/S, TiTf/S, ZrTf/S) samples were synthesized as inexpensive solid acid materials by a simple one-pot-two-step synthesis methodology. These materials were characterized by X-ray diffraction, N₂-sorption, thermogravimetric analysis, Fourier transform infrared spectroscopy (FT-IR), in-situ pyridine FT-IR spectroscopy, and elemental analysis. ZrTf/S was found to be a highly efficient and reusable solid acid catalyst for ring opening of epoxides with amines and alcohols and produced β-amino alcohols and β-alkoxy alcohols respectively under ambient reaction conditions. The ZrTf/S catalyst showed the highest activity, which was attributed to its high acidity compared with that of the Ti and Al containing samples.
- Epoxide ring opening,
- Acid catalysis,
- Metal triflate,
- Grafted catalyst,
- Mesoporous silica
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