Citation: Sanjay Srivastava, G.C.Jadeja, Jigisha Parikh. Influence of supports for selective production of 2,5-dimethylfuran via bimetallic copper-cobalt catalyzed 5-hydroxymethylfurfural hydrogenolysis[J]. Chinese Journal of Catalysis, ;2017, 38(4): 699-709. doi: 10.1016/S1872-2067(17)62789-X shu

Influence of supports for selective production of 2,5-dimethylfuran via bimetallic copper-cobalt catalyzed 5-hydroxymethylfurfural hydrogenolysis

Department of Chemical Engineering, Sardar Vallabhbhai National Institute of Technology, Surat-395007, Gujarat, India

Received Date: 16 December 2016
Revised Date: 10 January 2017

The hydrogenolysis of carbon-oxygen bonds is an important model reaction in upgrading biomass-derived furanic compounds to transportation fuels. One of these model reactions, namely conversion of 5-hydroxymethylfurfural (HMF) to the gasoline additive 2,5-dimethylfuran (DMF), is especially attractive. In this study, bimetallic Cu-Co catalysts supported on CeO₂, ZrO₂, and Al₂O₃were used for the selective hydrogenolysis of HMF to DMF. The structures of the fresh and used catalysts were studied using X-ray diffraction, the Brunauer-Emmett-Teller method, transmission electron microscopy, temperature-programmed reduction by H₂, temperature-programmed desorption of NH₃, and CHNS analysis. The structures were correlated with the catalytic activities. The Cu-Co/CeO₂ catalyst produced mainly 2,5-bis(hydroxymethyl)furan via reduction of C=O bonds on large Cu particles. The Cu-Co/Al₂O₃ catalyst gave the best selectivity for DMF, as a result of a combination of highly dispersed Cu, mixed copper-cobalt oxides, and suitable weak acidic sites. Cu-Co/ZrO₂ had low selectivity for DMF and produced a combination of various over-hydrogenolysis products, including 2,5-dimethyltetrahydrofuran and 5,5-oxybis(methylene)-bis(2-methylfuran), because of the presence of strong acidic sites. The reaction pathways and effects of various operating parameters, namely temperature, H₂ pressure, and time, were studied to enable optimization of the selective conversion of HMF to DMF over the Cu-Co/Al₂O₃ catalyst.
- Hydroxymethylfurfural,
- Hydrogenation,
- Hydrogenolysis,
- Copper-cobalt,
- Bimetallic,
- Biofuels
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