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Citation: Larisha Cisneros, Pedro Serna, Avelino Corma. Selective reductive coupling of nitro aliphatic compounds with aldehydes in hydrogen using gold catalyst[J]. Chinese Journal of Catalysis, ;2016, 37(10): 1756-1763. doi: 10.1016/S1872-2067(16)62493-2 shu

Selective reductive coupling of nitro aliphatic compounds with aldehydes in hydrogen using gold catalyst

a Instituto de Tecnología Química, Universitat Politècnica de València-Consejo Superior de Investigaciones Científicas, Avda. de los Naranjos s/n, 46022 Valencia, Spain;
b Corporate Strategic Research, ExxonMobil Research & Engineering Co. Inc., 1545 Route 22 East, Annandale, New Jersey 08801, United States

Received Date: 16 May 2016
Revised Date: 28 June 2016

Fund Project: This work was supported by Consolider-Ingenio 2010 (project MULTICAT), Generalitat Valenciana (Prometeo program) and Severo Ochoa Program (SEV-2012-0267) and the CONACyT Program (3115621).

Nitrones were synthesized in good yields directly from nitro aliphatic compounds, aldehydes, and H₂ using highly dispersed gold nanoparticles on titania. The high selectivity for nitrone synthesis contrasts with the platinum supported on carbon and corresponds to an increase from roughly 50% to 90%. The catalytic performance is tuned by precise control of the struc-ture of the active sites, the characteristics of the support and reaction conditions.
- Gold catalyst,
- Nitro compound,
- Cascade-type reaction,
- Hydrogenation,
- Nitrone
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
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