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Citation: Yong Yang, Guojun Lan, Xiaolong Wang, Ying Li. Direct synthesis of nitrogen-doped mesoporous carbons for acetylene hydrochlorination[J]. Chinese Journal of Catalysis, ;2016, 37(8): 1242-1248. doi: 10.1016/S1872-2067(16)62459-2 shu

Direct synthesis of nitrogen-doped mesoporous carbons for acetylene hydrochlorination

Institute of Industrial Catalysis, Zhejiang University of Technology, Hangzhou 310014, Zhejiang, China

Received Date: 5 March 2016
Revised Date: 8 May 2016

Fund Project: This work was supported by the National Natural Science Foundation of China (20803064) and the Natural Science Foundation of Zhejiang Province (Y4090348).

Nitrogen-doped ordered mesoporous carbon (N-OMC) catalysts were directly synthesized using SBA-15 as a hard template and sucrose as a carbon source. Urea, which was used as the nitrogen source, was carbonized with sucrose. A 3.6 wt% nitrogen doping of the carbon framework was achieved, with more than 70% of the nitrogen incorporated as quaternary nitrogen species. Only 0.2 wt% nitrogen doping, with only 32.7% quaternary nitrogen incorporation was obtained in an N-OMC catalyst (N-OMC-T) prepared using a two-step post-synthesis method. The acetylene hydrochlorination activities of N-OMC catalysts prepared via the one-step method were higher than that of the N-OMC-T catalyst because of the higher nitrogen loadings.
- Acetylene,
- Hydrochlorination,
- Vinyl chloride,
- Mercury-free,
- N-doped carbon
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
24. [24]
25. [25]
26. [26]
27. [27]
28. [28]
29. [29]
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