Citation: Zhongkui Zhao, Guifang Ge, Weizuo Li, Xinwen Guo, Guiru Wang. Modulating the microstructure and surface chemistry of carbocatalysts for oxidative and direct dehydrogenation: A review[J]. Chinese Journal of Catalysis, ;2016, 37(5): 644-670. doi: 10.1016/S1872-2067(15)61065-8 shu

Modulating the microstructure and surface chemistry of carbocatalysts for oxidative and direct dehydrogenation: A review

1.
State Key Laboratory of Fine Chemicals, Department of Catalysis Chemistry and Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, Liaoning, China

Corresponding author: Zhongkui Zhao,
Received Date: 13 January 2016
Available Online: 22 February 2016
Fund Project: 国家自然科学基金(21276041) (21276041)教育部新世纪优秀人才支持计划(NCET-12-0079) (NCET-12-0079)辽宁省自然科学基金(2015020200) (2015020200)中央高校基本科研业务费专项资金(DUT15LK41). (DUT15LK41)

The catalytic performance of solid catalysts depends on the properties of the catalytically active sites and their accessibility to reactants, which are significantly affected by the microstructure (morphology, shape, size, texture, and surface structure) and surface chemistry (elemental components and chemical states). The development of facile and efficient methods for tailoring the microstructure and surface chemistry is a hot topic in catalysis. This contribution reviews the state of the art in modulating the microstructure and surface chemistry of carbocatalysts by both bottom-up and top-down strategies and their use in the oxidative dehydrogenation (ODH) and direct dehydrogenation (DDH) of hydrocarbons including light alkanes and ethylbenzene to their corresponding olefins, important building blocks and chemicals like oxygenates. A concept of microstructure and surface chemistry tuning of the carbocatalyst for optimized catalytic performance and also for the fundamental understanding of the structure-performance relationship is discussed. We also highlight the importance and challenges in modulating the microstructure and surface chemistry of carbocatalysts in ODH and DDH reactions of hydrocarbons for the highly-efficient, energy-saving, and clean production of their corresponding olefins.
- Carbocatalysis,
- Microstructure,
- Surface chemistry,
- Modulation,
- Dehydrogenation,
- Olefin
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