Citation: Xinhua Gao, Jianli Zhang, Ning Chen, Qingxiang Ma, Subing Fan, Tiansheng Zhao, Noritatsu Tsubaki. Effects of zinc on Fe-based catalysts during the synthesis of light olefins from the Fischer-Tropsch process[J]. Chinese Journal of Catalysis, ;2016, 37(4): 510-516. doi: 10.1016/S1872-2067(15)61051-8 shu

Effects of zinc on Fe-based catalysts during the synthesis of light olefins from the Fischer-Tropsch process

a.
a State Key Laboratory Cultivation Base of Natural Gas Conversion, College of Chemistry & Chemical Engineering, Ningxia University, Yinchuan 750021, Ningxia, China;
b.
b Department of Applied Chemistry, School of Engineering, University of Toyama, Toyama 930-8555, Japan

Corresponding author: Jianli Zhang, Tiansheng Zhao,
Received Date: 31 December 2015
Available Online: 15 February 2016
Fund Project: 宁夏自然科学基金重点项目(NZ13010) (NZ13010) 国家自然科学基金(21366025). (21366025)

Fe-based catalysts for the production of light olefins via the Fischer-Tropsch synthesis were modified by adding a Zn promoter using both microwave-hydrothermal and impregnation methods. The physicochemical properties of the resulting catalysts were determined by scanning electron microscopy, the Brunauer-Emmett-Teller method, X-ray diffraction, H₂ temperature-programed reduction and X-ray photoelectron spectroscopy. The results demonstrate that the addition of a Zn promoter improves both the light olefin selectivity over the catalyst and the catalyst stability. The catalysts prepared via the impregnation method, which contain greater quantities of surface ZnO, exhibit severe carbon deposition following activity trials. In contrast, those materials synthesized using the microwave-hydrothermal approach show improved dispersion of Zn and Fe phases and decreased carbon deposition, and so exhibit better CO conversion and stability.
- Zn promoter,
- Fe-based catalyst,
- Light olefin,
- Fischer-Tropsch synthesis,
- Microwave-hydrothermal method
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沈阳化工大学材料科学与工程学院沈阳 110142