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Citation: Yanmei Zhang, Jing Zhang, Miaomiao Tian, Gang Chu, Chunshan Quan. Fabrication of amino-functionalized Fe3O4@Cu3(BTC)2 for heterogeneous Knoevenagel condensation[J]. Chinese Journal of Catalysis, ;2016, 37(3): 420-427. doi: 10.1016/S1872-2067(15)61013-0 shu

Fabrication of amino-functionalized Fe3O4@Cu3(BTC)2 for heterogeneous Knoevenagel condensation

  • 1.

    a College of Life Science, Dalian Nationalities University, Dalian 116600, Liaoning, China;

  • 2.

    b School of Chemistry and Material Science, Liaoning Shihua University, Fushun 113001, Liaoning, China

  • Corresponding author: Yanmei Zhang,  Jing Zhang, 
  • Received Date: 15 October 2015
    Available Online: 3 November 2015

    Fund Project: 国家自然科学基金(21203017) (21203017)国家重点实验室开放基金(N-11-03) (N-11-03)中央高校基本科研业务费专项资金(DC201502020304). (DC201502020304)

  • Metal organic frameworks (MOFs) are an important platform for heterogeneous catalysts. Although MOFs with a smaller particle size exhibit better catalytic performance because of less diffusion limitations, their separation and recycling after catalytic reactions are difficult. The integration of MOFs with magnetic nanoparticles could facilitate their recovery and separation. Especially, the shell thickness of the core-shell structured composites is controllable. In this study, amino-functionalized Fe3O4@Cu3(BTC)2 was fabricated by a stepwise assembly method and its catalytic performance in Knoevenagel condensation was investigated. The results demonstrated that the magnetic hybrid material exhibited a core-shell structure, with a shell thickness of about 200 nm. Furthermore, it not only exhibited high catalytic activity, but remarkably, it could also be easily recovered magnetically and recycled without obvious loss of catalytic efficiency after three cycles.
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