Citation: Xin Zhao, Lei Huang, Hongrui Li, Hang Hu, Jin Han, Liyi Shi, Dengsong Zhang. Highly dispersed V₂O₅/TiO₂ modified with transition metals (Cu, Fe, Mn, Co) as efficient catalysts for the selective reduction of NO with NH₃[J]. Chinese Journal of Catalysis, ;2015, 36(11): 1886-1899. doi: 10.1016/S1872-2067(15)60958-5 shu

Highly dispersed V₂O₅/TiO₂ modified with transition metals (Cu, Fe, Mn, Co) as efficient catalysts for the selective reduction of NO with NH₃

Xin Zhao ^a ,
Lei Huang ^a,, ,
Hongrui Li ^a ,
Hang Hu ^a ,
Jin Han ^a ,
Liyi Shi ^b,, ,
Dengsong Zhang ^a,,

1.
a Research Center of Nano Science and Technology, Shanghai University, Shanghai 200444, China;

Corresponding author: Lei Huang, Liyi Shi, Dengsong Zhang,
Received Date: 18 June 2015
Available Online: 25 July 2015
Fund Project: 国家自然科学基金(21303099) (21303099) 国家重点基础研究发展计划(973计划, 2014CB660803) (973计划, 2014CB660803) 上海市教委项目(14ZZ097, B.3704713001) (14ZZ097, B.3704713001) 上海大学创新基金(K.10040713003). (K.10040713003)

Different transition metals were used to modify V₂O₅-based catalysts (M-V, M = Cu, Fe, Mn, Co) on TiO₂ via impregnation, for the selective reduction of NO with NH₃. The introduced metals induced high dispersion in the vanadium species and the formation of vanadates on the TiO₂ support, and increased the amount of surface acid sites and the strength of these acids. The strong acid sites might be responsible for the high N₂ selectivity at higher temperatures. Among these catalysts, Cu-V/TiO₂ showed the highest activity and N₂ selectivity at 225-375 ℃. The results of X-ray photoelectron spectroscopy, NH₃-temperature-programmed desorption, and in-situ diffuse reflectance infrared Fourier transform spectroscopy suggested that the improved performance was probably due to more active surface oxygen species and increased strong surface acid sites. The outstanding activity, stability, and SO₂/H₂O durability of Cu-V/TiO₂ make it a candidate to be a NO_x removal catalyst for stationary flue gas.
- deNO_x,
- Selective catalytic reduction,
- Vanadate,
- Transition metal
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通讯作者: 陈斌, bchen63@163.com

Highly dispersed V₂O₅/TiO₂ modified with transition metals (Cu, Fe, Mn, Co) as efficient catalysts for the selective reduction of NO with NH₃