Citation: Tingting Lu, Pan Gao, Jun Xu, Yongrui Wang, Wenfu Yan, Jihong Yu, Feng Deng, Xuhong Mu, Ruren Xu. Influence of Al³⁺ on polymorph A enrichment in the crystallization of beta zeolite[J]. Chinese Journal of Catalysis, ;2015, 36(6): 889-896. doi: 10.1016/S1872-2067(14)60300-4 shu

Influence of Al³⁺ on polymorph A enrichment in the crystallization of beta zeolite

Tingting Lu ^a ,
Pan Gao ^b ,
Jun Xu ^b ,
Yongrui Wang ^c ,
Wenfu Yan ^a,, ,
Jihong Yu ^a ,
Feng Deng ^b ,
Xuhong Mu ^c ,
Ruren Xu ^a

1.
a State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, Jilin, China;

Corresponding author: Wenfu Yan,
Received Date: 25 December 2014
Available Online: 26 January 2015
Fund Project: 国家自然科学基金(21171063) (21171063) 优秀青年科学基金(21222103) (21222103) 国家重点基础研究发展计划(2011CB808703) (2011CB808703) 石油化工催化材料与反应工程国家重点实验室(中国石化石油化工科学研究院)开放课题基金 (中国石化石油化工科学研究院) 长江学者和创新团队发展计划(IRT101713018). (IRT101713018)

Using tetraethylammonium hydroxide as the organic structure-directing agent and in the presence of fluoride, polymorph A-enriched silica beta zeolite was synthesized under concentrated hydrothermal conditions. The introduction of Al species into the same starting mixture resulted in a decrease in the degree of enrichment of polymorph A in beta zeolite and an Al-incorporated beta zeolite resulted. The crystallized polymorph A-enriched silica beta zeolite and the Al-incorporated beta zeolite and their crystallization processes were investigated by X-ray diffractometry, elemental analysis, thermogravimetric analysis-differential thermal analysis, nitrogen adsorption, scanning electron microscopy, and solid-state magic angle spinning nuclear magnetic resonance. The introduction of Al species accelerated crystallization and reduced the crystal size of Al-incorporated beta zeolite. The intermediate of five-coordinated Al species accounted for a decrease in the degree of enrichment of polymorph A in the crystallization of Al-incorporated beta zeolite.
- Beta zeolite,
- Chirality,
- Polymorph A,
- Enrichment
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沈阳化工大学材料科学与工程学院沈阳 110142

Influence of Al3+ on polymorph A enrichment in the crystallization of beta zeolite

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通讯作者: 陈斌, bchen63@163.com

Influence of Al³⁺ on polymorph A enrichment in the crystallization of beta zeolite