Citation: Liang Li, Jianghong Ding, Jin-Gang Jiang, Zhiguo Zhu, Peng Wu. One-pot synthesis of 5-hydroxymethylfurfural from glucose using bifunctional [Sn,Al]-Beta catalysts[J]. Chinese Journal of Catalysis, ;2015, 36(6): 820-828. doi: 10.1016/S1872-2067(14)60287-4 shu

One-pot synthesis of 5-hydroxymethylfurfural from glucose using bifunctional [Sn,Al]-Beta catalysts

1.
Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai 200062, China

Corresponding author: Peng Wu,
Received Date: 28 November 2014
Available Online: 13 January 2015
Fund Project: 国家自然科学基金(21373089, U1162102) (21373089, U1162102) 教育部博士学科点专项科研基金(2012007613000) (2012007613000) 国家科技支撑计划(2012BAE05B02) (2012BAE05B02) 上海市重点学科建设项目资助(B409). (B409)

The one-pot synthesis of 5-hydroxymethylfurfural (5-HMF) from glucose was investigated, using [Sn,Al]-Beta catalysts prepared by a combination of partial dealumination and isomorphous substitution of Sn into the zeolite framework. The amount of Al in [Sn,Al]-Beta was adjusted by changing the concentration and acid treatment time, and the Sn content was varied by changing the SnCl₄ vapor treatment time. [Sn,Al]-Beta contains framework Al-related Brönsted acid sites and tetrahedral Sn-related Lewis acid sites, and is therefore a bifunctional solid acid catalyst. The reaction parameters for the [Sn,Al]-Beta-catalyzed one-pot conversion of glucose to 5-HMF were optimized. [Sn,Al]-Beta with a suitable Sn/Al molar ratio gave a glucose conversion of 60.0% and 5-HMF selectivity of 62.1%.
- [Sn,Al]-Beta,
- Aldose-Ketose Isomerization,
- Bifunctional Catalysis,
- Hydroxymethyl furfural,
- Biomass,
- Isomorphous substitution
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