Citation: Hossein Eshghi, Ali Javid, Amir Khojastehnezhad, Farid Moeinpour, Fatemeh F. Bamoharram d, Mehdi Bakavoli, Masoud Mirzaei. Preyssler heteropolyacid supported on silica coated NiFe₂O₄ nanoparticles for the catalytic synthesis of bis(dihydropyrimidinone)benzene and 3,4-dihydropyrimidin-2(1H)-ones[J]. Chinese Journal of Catalysis, ;2015, 36(3): 299-307. doi: 10.1016/S1872-2067(14)60265-5 shu

Preyssler heteropolyacid supported on silica coated NiFe₂O₄ nanoparticles for the catalytic synthesis of bis(dihydropyrimidinone)benzene and 3,4-dihydropyrimidin-2(1H)-ones

1.
a Department of Chemistry, Faculty of Sciences, Ferdowsi University of Mashhad, Mashhad, Iran;

Corresponding author: Ali Javid, Amir Khojastehnezhad,
Received Date: 19 October 2014
Available Online: 12 December 2014

A novel magnetic acidic catalyst comprising Preyssler (H₁₄[NaP₅W₃₀O₁₁₀]) heteropoly acid supported on silica coated nickel ferrite nanoparticles (NiFe₂O₄@SiO₂) was prepared. The catalyst was characterized by Fourier transform infrared, scanning electron microscopy, transmission electron microscopy, X-ray diffraction, energy dispersive spectrum, VSM and particle size neasurement. Its catalytic activity was investigated for the synthesis of bis(dihydropyrimidinone)benzene and 3,4-dihydropyrimidin-2(1H)-ones derivatives by the Biginelli reaction. With the catalyst, the reactions occurred in less than 1 h with good to excel-lent yields. More importantly, the catalyst was easily separated from the reaction mixture by an external magnet and reused at least five times without degradation in the activity.
- Preyssler,
- Nickel ferrite nanoparticles,
- Magnetically green catalyst,
- Bis(dihydropyrimidinone)benzene,
- 3,4-Dihydropyrimidin-2(1H)-ones
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Preyssler heteropolyacid supported on silica coated NiFe2O4 nanoparticles for the catalytic synthesis of bis(dihydropyrimidinone)benzene and 3,4-dihydropyrimidin-2(1H)-ones

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通讯作者: 陈斌, bchen63@163.com

Preyssler heteropolyacid supported on silica coated NiFe₂O₄ nanoparticles for the catalytic synthesis of bis(dihydropyrimidinone)benzene and 3,4-dihydropyrimidin-2(1H)-ones