Citation: Fangfang Wei, Weiguo Song, Fang Wei, Changyan Cao. Ordered mesoporous silcalite-1 zeolite assembled from colloidal nanocrystalline precursors[J]. Chinese Journal of Catalysis, ;2015, 36(6): 838-844. doi: 10.1016/S1872-2067(14)60255-2 shu

Ordered mesoporous silcalite-1 zeolite assembled from colloidal nanocrystalline precursors

1.
Beijing National Laboratory for Molecular Sciences, Laboratory for Molecular Nanostructures and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China

Corresponding author: Weiguo Song,
Received Date: 30 September 2014
Available Online: 20 November 2014
Fund Project: 国家自然科学基金(21273244, 21333009和21121063). (21273244, 21333009和21121063)

A series of ordered mesoporous silicalite-1 zeolites has been synthesized by the self-assembly of nanosized zeolite silicalite-1 seeds with different sizes using a two-step procedure. The nanosized silicalite-1 seeds were prepared with an alkali precursor solution that was heated for different periods, and then assembled into ordered mesoporous materials under strongly acidic conditions, similar to that of mesoporous silica SBA-15 which has well ordered hexagonal mesopores and amorphous walls. A significant change in synthesis conditions prevents the continued growth of zeolite seeds and induces assemblage into ordered mesoporous materials templated by triblock copolymers. The samples assembled by zeolite nanoclusters were investigated by X-ray diffraction, electron microscopy, infrared spectroscopy, and N₂ adsorption-desorption isotherms. This "bottom-up" approach yields porous materials that contain ordered micro- and mesopores. The mesoporous zeolite has a large surface area (> 730 m²/g).
- Ordered mesoporous zeolite,
- Self-assembly,
- Bottom-up method,
- Nanosized seed,
1. [1]
  [1] Davis M E. Nature, 2002, 417: 813
2. [2]
  [2] Möller K, Bein T. Chem Soc Rev, 2013, 42: 3689
3. [3]
  [3] Egeblad K, Christensen C H, Kustova M, Christensen C H. Chem Mater, 2008, 20: 946
4. [4]
  [4] Wei F F, Cui Z M, Meng X J, Cao C Y, Xiao F S, Song W G. ACS Catal, 2014, 4: 529
5. [5]
  [5] Mintova S, Gilson J P, Valtchev V. Nanoscale, 2013, 5: 6693
6. [6]
  [6] Serrano D P, Escola J M, Pizarro P. Chem Soc Rev, 2013, 42: 4004
7. [7]
  [7] Meng X J, Nawaz F, Xiao F S. Nano Today, 2009, 4: 292
8. [8]
  [8] Gu F N, Wei F, Yang J Y, Lin N, Lin W G, Wang Y, Zhu J H. Chem Mater, 2010, 22: 2442
9. [9]
  [9] Xiao F S, Wang L F, Yin C Y, Lin K F, Di Y, Li J X, Xu R R, Su D S, Schlögl R, Yokoi T, Tatsumi T. Angew Chem, 2006, 118: 3162
10. [10]
  [10] Choi M, Cho H S, Srivastava R, Venkatesan C, Choi D H, Ryoo R. Nat Mater, 2006, 5: 718
11. [11]
  [11] Mukti R R, Hirahara H, Sugawara A, Shimojima A, Okubo T. Langmuir, 2010, 26: 2731
12. [12]
  [12] Tao Y S, Kanoh H, Kaneko K. J Am Chem Soc, 2003, 125: 6044
13. [13]
  [13] Cho H S, Ryoo R. Micropor Mesopor Mater, 2012, 151: 107
14. [14]
  [14] Chen H Y, Wydra J, Zhang X Y, Lee P S, Wang Z P, Fan W, Tsapatsis M. J Am Chem Soc, 2011, 133: 12390
15. [15]
  [15] Wang L F, Yin C Y, Shan Z C, Liu S, Du Y C, Xiao F S. Colloids Surf A, 2009, 340: 126
16. [16]
  [16] Möller K, Bein T. Science, 2011, 333: 297
17. [17]
  [17] Na K, Jo C, Kim J, Cho K, Jung J, Seo Y, Messinger R J, Chmelka B F, Ryoo R. Science, 2011, 333: 328
18. [18]
  [18] Choi M, Na K, Kim J, Sakamoto Y, Terasaki O, Ryoo R. Nature, 2009, 461: 246
19. [19]
  [19] Möller K, Yilmaz B, Jacubinas R M, Müller U, Bein T. J Am Chem Soc, 2011, 133: 5284
20. [20]
  [20] Zhou J A, Hua Z L, Liu Z C, Wu W, Zhu Y, Shi J L. ACS Catal, 2011, 1: 287
21. [21]
  [21] Wang J, Groen J C, Yue W B, Zhou W Z, Coppens M O. Chem Commun, 2007, 44: 4653
22. [22]
  [22] Janssen A H, Koster A J, de Jong K P. Angew Chem Int Ed, 2001, 40: 1102
23. [23]
  [23] Ogura M, Shinomiya S Y, Tateno J, Nara Y, Kikuchi E, Matsukata M. Chem Lett, 2000, 29: 882
24. [24]
  [24] Liu Y, Zhang W Z, Pinnavaia T J. J Am Chem Soc, 2000, 122: 8791
25. [25]
  [25] Liu Y, Zhang W Z, Pinnavaia T J. Angew Chem Int Ed, 2001, 40: 1255
26. [26]
  [26] Carr C S, Kaskel S, Shantz D F. Chem Mater, 2004, 16: 3139
27. [27]
  [27] Jacobs P A, Derouane E G, Weitkamp J. J Chem Soc, Chem Commun, 1981, 591
28. [28]
  [28] de Moor P P E A, Beelen T P M, van Santen R A. J Phys Chem B, 1999, 103: 1639
29. [29]
  [29] Davis T M, Drews T O, Ramanan H, He C, Dong J S, Schnablegger H, Katsoulakis M A, Kokkoli E, McCormick A V, Penn R L, Tsapatsis M. Nat Mater, 2006, 5: 400
30. [30]
  [30] Wiersema G S, Thompson R W. J Mater Chem, 1996, 6: 1693
31. [31]
  [31] Li H, Wu H Z, Shi J L. J Alloys Compd, 2013, 556: 71
32. [32]
  [32] Zhu Y, Hua Z L, Zhou J, Wang L J, Zhao J J, Gong Y, Wu W, Ruan M L, Shi J L. Chem Eur J, 2011, 17: 14618
33. [33]
  [33] Han Y, Li N, Zhao L, Li D F, Xu X Z, Wu S, Di Y, Li C J, Zou Y C, Yu Y, Xiao F S. J Phys Chem B, 2003, 107: 7551
34. [34]
  [34] Sun Y Y, Han Y, Yuan L, Ma S Q, Jiang D H, Xiao F S. J Phys Chem B, 2003, 107: 1853
35. [35]
  [35] Han Y, Wu S, Sun Y Y, Li D S, Xiao F S, Liu J, Zhang X Z. Chem Mater, 2002, 14: 1144
36. [36]
  [36] Han Y, Xiao F S, Wu S, Sun Y Y, Meng X J, Li D S, Lin S, Deng F, Ai X J. J Phys Chem B, 2001, 105: 7963
37. [37]
  [37] Wang C L, Zhu G S, Shang T C, Cai X H, Liu C Z, Li N, Wei Y H, Li J, Zhang W W, Qiu S L. Solid State Commun, 2005, 135: 257
38. [38]
  [38] de Moor P-P E A, Beelen T P M, van Santen R A. J Phys Chem B, 1999, 103: 1639
39. [39]
  [39] Song J W, Ren L M, Yin C Y, Ji Y Y, Wu Z F, Li J X, Xiao F S. J Phys Chem C, 2008, 112: 8609
40. [40]
  [40] Song W G, Justice R E, Jones C A, Grassian V H, Larsen S C. Langmuir, 2004, 20: 4696
41. [41]
  [41] Kirschhock C E A, Kremer S P B, Vermant J, Van Tendeloo G, Jacobs P A, Martens J A. Chem Eur J, 2005, 11: 4306
42. [42]
  [42] Coronas J. Chem Eng J, 2010, 156: 236
43. [43]
  [43] Kirschhock C E A, Ravishankar R, Van Looveren L, Jacobs P A, Martens J A. J Phys Chem B, 1999, 103: 4972
44. [44]
  [44] Song W, Justice R, Jones C, Grassian V, Larsen S. Langmuir, 2004, 20: 4696
45. [45]
  [45] Linssen T, Cassiers K, Cool P, Vansant E F. Adv Colloid Interf Sci, 2003, 103: 121
46. [46]
  [46] Miyazawa K, Inagaki S. Chem Commun, 2000, 21: 2121
47. [47]
  [47] Göltner C G, Smarsly B, Berton B, Antonietti M. Chem Mater, 2001, 13: 1617
48. [48]
  [48] Kirschhock C E A, Ravishankar R, Verspeurt F, Grobet P J, Jacobs P A, Martens J A. J Phys Chem B, 1999, 103: 4965
49. [49]
  [49] Fang Y M, Hu H Q. J Am Chem Soc, 2006, 128: 10636
1. [1]
  Pei Li , Yuenan Zheng , Zhankai Liu , An-Hui Lu . Boron-Containing MFI Zeolite: Microstructure Control and Its Performance of Propane Oxidative Dehydrogenation. Acta Physico-Chimica Sinica, 2025, 41(4): 100034-. doi: 10.3866/PKU.WHXB202406012
2. [2]
  Jin Tong , Shuyan Yu . Crystal Engineering for Supramolecular Chirality. University Chemistry, 2024, 39(3): 86-93. doi: 10.3866/PKU.DXHX202308113
3. [3]
  Ruoxi Sun , Yiqian Xu , Shaoru Rong , Chunmiao Han , Hui Xu . The Enchanting Collision of Light and Time Magic: Exploring the Footprints of Long Afterglow Lifetime. University Chemistry, 2024, 39(5): 90-97. doi: 10.3866/PKU.DXHX202310001
4. [4]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
5. [5]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
6. [6]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
7. [7]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
8. [8]
  .
  南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积
  . CCS Chemistry, 2025, 7(0): -.
9. [9]
  Shihui Shi , Haoyu Li , Shaojie Han , Yifan Yao , Siqi Liu . Regioselectively Synthesis of Halogenated Arenes via Self-Assembly and Synergistic Catalysis Strategy. University Chemistry, 2024, 39(5): 336-344. doi: 10.3866/PKU.DXHX202312002
10. [10]
  Wenjian Zhang , Mengxin Fan , Wenwen Fei , Wei Bai . Cultivation of Critical Thinking Ability: Based on RAFT Polymerization-Induced Self-Assembly. University Chemistry, 2025, 40(4): 108-112. doi: 10.12461/PKU.DXHX202406099
11. [11]
  Jiali CHEN , Guoxiang ZHAO , Yayu YAN , Wanting XIA , Qiaohong LI , Jian ZHANG . Machine learning exploring the adsorption of electronic gases on zeolite molecular sieves. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 155-164. doi: 10.11862/CJIC.20240408
12. [12]
  Yiping HUANG , Liqin TANG , Yufan JI , Cheng CHEN , Shuangtao LI , Jingjing HUANG , Xuechao GAO , Xuehong GU . Hollow fiber NaA zeolite membrane for deep dehydration of ethanol solvent by vapor permeation. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 225-234. doi: 10.11862/CJIC.20240224
13. [13]
  Xiaofei NIU , Ke WANG , Fengyan SONG , Shuyan YU . Self-assembly of [Pd₆(L)₄]⁸⁺-type macrocyclic complexes for fluorescent sensing of HSO₃^-. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1233-1242. doi: 10.11862/CJIC.20240057
14. [14]
  Shanghua Li , Malin Li , Xiwen Chi , Xin Yin , Zhaodi Luo , Jihong Yu . 基于高离子迁移动力学的取向ZnQ分子筛保护层实现高稳定水系锌金属负极的构筑. Acta Physico-Chimica Sinica, 2025, 41(1): 2309003-. doi: 10.3866/PKU.WHXB202309003
15. [15]
  Hongwei Ma , Hui Li . Three Methods for Structure Determination from Powder Diffraction Data. University Chemistry, 2024, 39(3): 94-102. doi: 10.3866/PKU.DXHX202310035
16. [16]
  Haiping Wang . A Streamlined Method for Drawing Lewis Structures Using the Valence State of Outer Atoms. University Chemistry, 2024, 39(8): 383-388. doi: 10.12461/PKU.DXHX202401073
17. [17]
  Juan Yuan , Bin Zhang , Jinping Wu , Mengfan Wang . Design of a Comprehensive Experiment on Preparation and Characterization of Cu₂(Salen)₂ Nanomaterials with Two Distinct Morphologies. University Chemistry, 2024, 39(10): 420-425. doi: 10.3866/PKU.DXHX202402014
18. [18]
  Yinyin Qian , Rui Xu . Utilizing VESTA Software in the Context of Material Chemistry: Analyzing Twin Crystal Nanostructures in Indium Antimonide. University Chemistry, 2024, 39(3): 103-107. doi: 10.3866/PKU.DXHX202307051
19. [19]
  Chengyi Xiao , Xiaoli Sun , Chen Zhang , Weiwei Li . An In-Depth Analysis of the Scientific Connotations, Testing Methods, and Applications of Free Volume in Polymer Physics. University Chemistry, 2025, 40(4): 33-45. doi: 10.12461/PKU.DXHX202403069
20. [20]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(472)
HTML views(37)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Ordered mesoporous silcalite-1 zeolite assembled from colloidal nanocrystalline precursors

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

Metrics

通讯作者: 陈斌, bchen63@163.com