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Citation: Yanpeng Pei, Yunjie Ding, Hejun Zhu, Hong Du. One-step production of C1-C18 alcohols via Fischer-Tropsch reaction over activated carbon-supported cobalt catalysts: Promotional effect of modification by SiO2[J]. Chinese Journal of Catalysis, ;2015, 36(3): 355-361. doi: 10.1016/S1872-2067(14)60252-7 shu

One-step production of C1-C18 alcohols via Fischer-Tropsch reaction over activated carbon-supported cobalt catalysts: Promotional effect of modification by SiO2

  • 1.

    a Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;

  • Corresponding author: Yunjie Ding, 
  • Received Date: 13 September 2014
    Available Online: 12 November 2014

  • The promotional effect of SiO2 on the catalytic synthesis of mixed C1-C18 alcohols from syngas using the Fischer-Tropsch reaction over activated carbon-supported cobalt catalysts was investigated. X-ray diffraction, H2 temperature-programmed reduction, pulsed CO chemisorption and N2 physisorption techniques were all employed to assess the catalyst. Although the addition of SiO2 decreased the reducibility of the Co component, Co dispersion was significantly increased and its aggregation during reaction was inhibited, resulting in greatly enhanced reaction activity. Appropriate amounts of SiO2 also promoted the formation of Co2C, leading to an increased selectivity for C1-C18 alcohols. More importantly, the addition of SiO2 favored the formation of higher molecular mass alcohols (C6-C18) by suppressing Co reduction, thus producing an abundance of Co(II) species capable of facilitating CO insertion.
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