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Citation: Yanpeng Pei, Yunjie Ding, Hejun Zhu, Hong Du. One-step production of C1-C18 alcohols via Fischer-Tropsch reaction over activated carbon-supported cobalt catalysts: Promotional effect of modification by SiO2[J]. Chinese Journal of Catalysis, ;2015, 36(3): 355-361. doi: 10.1016/S1872-2067(14)60252-7 shu

One-step production of C1-C18 alcohols via Fischer-Tropsch reaction over activated carbon-supported cobalt catalysts: Promotional effect of modification by SiO2

  • 1.

    a Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;

  • Corresponding author: Yunjie Ding, 
  • Received Date: 13 September 2014
    Available Online: 12 November 2014

  • The promotional effect of SiO2 on the catalytic synthesis of mixed C1-C18 alcohols from syngas using the Fischer-Tropsch reaction over activated carbon-supported cobalt catalysts was investigated. X-ray diffraction, H2 temperature-programmed reduction, pulsed CO chemisorption and N2 physisorption techniques were all employed to assess the catalyst. Although the addition of SiO2 decreased the reducibility of the Co component, Co dispersion was significantly increased and its aggregation during reaction was inhibited, resulting in greatly enhanced reaction activity. Appropriate amounts of SiO2 also promoted the formation of Co2C, leading to an increased selectivity for C1-C18 alcohols. More importantly, the addition of SiO2 favored the formation of higher molecular mass alcohols (C6-C18) by suppressing Co reduction, thus producing an abundance of Co(II) species capable of facilitating CO insertion.
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    1. [1]

      [1] Khodakov A Y, Chu W, Fongarland P. Chem Rev, 2007, 107: 1692

    2. [2]

      [2] Torres Galvis H M, Bitter J H, Khare C B, Ruitenbeek M, Dugulan A I, de Jong K P. Science, 2012, 335: 835

    3. [3]

      [3] Fischer F, Tropsch H. Brennst Chem, 1923, 18: 274

    4. [4]

      [4] Li H L, Wang S G, Ling F X, Li J L. J Mol Catal A, 2006, 244: 33

    5. [5]

      [5] Anderson R B, Kölbel H, Ralek M. The Fischer-Tropsch Synthesis. Orland: Academic Press, 1984. 122

    6. [6]

      [6] Forzatti P, Tronconi E, Pasquon I. Catal Rev-Sci Eng, 1991, 33: 109

    7. [7]

      [7] Baker J E, Burch R, Hibble S J, Loader P K. Appl Catal A, 1990, 65: 281

    8. [8]

      [8] Yang X M, Wei Y, Su Y L, Zhou L P. Fuel Process Technol, 2010, 91: 1168

    9. [9]

      [9] Jiao G P, Ding Y J, Zhu H J, Li X M, Li J W, Lin R H, Dong W D, Gong L F, Pei Y P, Lu Y. Appl Catal A, 2009, 364: 137

    10. [10]

      [10] Pei Y P, Ding Y J, Zang J, Song X G, Dong W D, Zhu H J, Wang T, Chen W M. Chin J Catal (裴彦鹏, 丁云杰, 臧娟, 宋宪根, 董文达, 朱何俊, 王涛, 陈维苗. 催化学报), 2012, 33: 808

    11. [11]

      [11] Pei Y P, Ding Y J, Zang J, Song X G, Dong W D, Zhu H J, Wang T, Chen W M. Chin J Catal(裴彦鹏, 丁云杰, 臧娟, 宋宪根, 董文达, 朱何俊, 王涛, 陈维苗. 催化学报), 2013, 34: 1570

    12. [12]

      [12] Pei Y P, Ding Y J, Zhu H J, Zang J, Song X G, Dong W D, Wang T, Lu Y. Catal Lett, 2014, 144: 1433

    13. [13]

      [13] Dlamini H, Motjope T, Joorst G, Stegeter G, Mdleleni M. Catal Lett, 2002,78: 201

    14. [14]

      [14] Sun X Y, Zhang X J, Zhang Y, Tsubaki N. Appl Catal A, 2010, 377: 134

    15. [15]

      [15] Ma W P, Kugler E L, Dadyburjor D B. Energy Fuels, 2010, 24: 4099

    16. [16]

      [16] Bechara R, Balloy D, Dauphin J Y, Grimblot J. Chem Mater, 1999, 11: 1703

    17. [17]

      [17] Dimitrova P G, Mehandjiev D R. J Catal, 1994, 145: 356

    18. [18]

      [18] de Miguel S R, Romon-Martinez M C, Jablonski E L, Fierro J L G, Cazorla-Amoros D, Scelza O A. J Catal, 1999, 184: 514

    19. [19]

      [19] Díaz K, García V, Matos J. Fuel, 2007, 86: 1337

    20. [20]

      [20] Fan L, Yokota K, Fujimoto K. AIChE J, 1992, 38: 1639

    21. [21]

      [21] Xiong J M, Ding Y J, Wang T, Yan L, Chen W M, Zhu H J, Lu Y. Catal Lett, 2005, 102: 265

    22. [22]

      [22] Lebarbier V M, Mei D H, Kim D H, Andersen A, Male J L, Holladay J E, Rousseau R, Wang Y. J Phys Chem C, 2011, 115: 17440

    23. [23]

      [23] Lü Z P, Tang H D, Liu C L, Liu H Z. Chin J Catal (吕兆坡, 唐浩东, 刘采来, 刘化章. 催化学报), 2011, 32: 1250

    24. [24]

      [24] Visconti C G, Tronconi E, Lietti L, Zennaro R, Forzatti P. Chem Eng Sci, 2007, 62: 5338

    25. [25]

      [25] Kuipers E W, Scheper C, Wilson J H, Vinkenburg I H, Oosterbeek H. J Catal, 1996, 158: 288

    26. [26]

      [26] Bezemer G L, Bitter J H, Kuipers H P C E, Oosterbeek H, Holewijn J E, Xu X D, Kapteijn F, van Dillen A J, de Jong K P. J Am Chem Soc, 2006, 128: 3956

    27. [27]

      [27] den Breejen J P, Radstake P B, Bezemer G L, Bitter J H, Frøseth V, Holmen A, de Jong K P. J Am Chem Soc, 2009, 131: 7197

    28. [28]

      [28] Song D C, Li J L. J Mol Catal A, 2006, 247: 206

    29. [29]

      [29] Lögdberg S, Lualdi M, Järås S, Walmsley J C, Blekkan E A, Rytter E, Holmen A. J Catal, 2010, 274: 84

    30. [30]

      [30] Pei Y P, Ding Y J, Zhu H J, Zang J, Song X G, Dong W D, Wang T, Yan L, Lu Y. Reac Kinet Mech Catal, 2014, 111: 505

    31. [31]

      [31] de Aquino A D, Cobo A J G. Catal Today, 2001, 65: 209

    32. [32]

      [32] Balonek C M, Lillebo A H, Rane S, Rytter E, Schmidt L D, Holmen A. Catal Lett, 2010, 138: 8

    33. [33]

      [33] Ishida T, Yanagihara T, Liu X H, Ohashi H, Hamasaki A, Honma T, Oji H, Yokoyama T, Tokunaga M. Appl Catal A, 2013, 458: 145

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