Citation: Weixing Liu, Zhe Zhao, Baofeng Tu, Daan Cui, Dingrong Ou, Mojie Cheng. TiO₂-modified La_0.6Sr_0.4Co_0.2Fe_0.8O_3-δ cathode for intermediate temperature solid oxide fuel cells[J]. Chinese Journal of Catalysis, ;2015, 36(4): 502-508. doi: 10.1016/S1872-2067(14)60235-7 shu

TiO₂-modified La_0.6Sr_0.4Co_0.2Fe_0.8O_3-δ cathode for intermediate temperature solid oxide fuel cells

Weixing Liu ^a,b ,
Zhe Zhao ^a ,
Baofeng Tu ^a ,
Daan Cui ^a ,
Dingrong Ou ^a ,
Mojie Cheng ^a,,

1.
a Division of Fuel Cells, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;

Corresponding author: Mojie Cheng,
Received Date: 18 July 2014
Available Online: 22 September 2014
Fund Project: 国家高技术研究发展计划(863计划, 2011AA050704) (863计划, 2011AA050704) 国家重点基础研究发展计划(973计划, 2010CB732302, 2012CB215500) (973计划, 2010CB732302, 2012CB215500) 国家自然科学基金(21376238, 21306189, 51101146). (21376238, 21306189, 51101146)

A La_0.6Sr_0.4Co_0.2Fe_0.8O_3-δ(LSCF) cathode modified using nanosized TiO₂was direct prepared on the yttria stabilized zirconia (YSZ) electrolyte in an intermediate temperature solid oxide fuel cell. TiO₂ prevents reaction between LSCF and YSZ, which would have formed a SrZrO₃ phase. The cell with a LSCF-0.25 wt% TiO₂ cathode exhibited a current density that was 1.6 times larger than that with a pure LSCF cathode at 0.7 V and 600 ℃. Electrochemical impedance spectra showed the accelerated incorporation of oxygen anions into the YSZ electrolyte with the TiO₂-modified LSCF cathode. The improvement was attributed to the suppressed formation of a non-conductive SrZrO₃ layer at the cathode/electrolyte interface.
- Intermediate temperature solid oxide fuel cell,
- Cathode,
- Titanium oxide,
- Interfacial reaction,
- Zirconia-based electrolyte
1. [1]
  [1] Stambouli A B, Traversa E. Renew Sustain Energy Rev, 2002, 6: 433
2. [2]
  [2] Tsai T, Barnett S A. Solid State Ionics, 1997, 93: 207
3. [3]
  [3] Jiang Y, Virkar A V, Zhao F. J Electrochem Soc, 2001, 148: A1091
4. [4]
  [4] Mai A, Haanappel V A C, Uhlenbruck S, Tietz F, Stöver D. Solid State Ionics, 2005, 176: 1341
5. [5]
  [5] Mai A, Becker M, Assenmacher W, Tietz F, Hathiramani D, Ivers-Tiffée E, Stöver D, Mader W. Solid State Ionics, 2006, 177: 1965
6. [6]
  [6] Jordan N, Assenmacher W, Uhlenbruck S, Haanappel V A C, Buchkremer H P, Stöver D, Mader W. Solid State Ionics, 2008, 179: 919
7. [7]
  [7] Constantin G, Rossignol C, Briois P, Billard A, Dessemond L, Djurado E. Solid State Ionics, 2013, 249-250: 98
8. [8]
  [8] Wu W M, Liu Z B, Zhao Z, Zhang X M, Ou D R, Tu B F, Cui D A, Cheng M J. Chin J Catal (武卫明, 刘中波, 赵哲, 张小敏, 区定容, 涂宝峰, 崔大安, 程谟杰. 催化学报), 2014, 35: 1376
9. [9]
  [9] Chen J, Liang F L, Liu L N, Jiang S P, Chi B, Pu J, Li J. J Power Sources, 2008, 183: 586
10. [10]
  [10] Chen D J, Wang F C, Shao Z P. Int J Hydrogen Energy, 2012, 37: 11946
11. [11]
  [11] Bannier E, Darut G, Sánchez E, Denoirjean A, Bordes M C, Salvador M D, Rayón E, Ageorges H. Surf Coatings Technol, 2011, 206: 378
12. [12]
  [12] Erdogan D A, Polat M, Garifullin R, Guler M O, Ozensoy E. Appl Surf Sci, 2014, 308: 50
13. [13]
  [13] Liu Y P, Deng D G, Xu S Q, Zhao S L, Wang H P, Huang L H, Hua Y J. J Non-Cryst Solids, 2013, 360: 26
14. [14]
  [14] Khan M A, Raza R, Lima R B, Chaudhry M A, Ahmed E, Khalid N R, Abbas G, Zhu B, Nasir N. Ceram Int, 2014, 40: 9775
15. [15]
  [15] Zhao Z, Liu L, Zhang X M, Wu W M, Tu B F, Ou D R, Cheng M J. J Power Sources, 2013, 222: 542
16. [16]
  [16] Simner S P, Anderson M D, Engelhard M H, Stevenson J W. Electrochem Solid-State Lett, 2006, 9: A478
17. [17]
  [17] Ding H P, Virkar A V, Liu M L, Liu F. Phys Chem Chem Phys, 2013, 15: 489
18. [18]
  [18] Zhao Z, Liu L, Zhang X M, Wu W M, Tu B F, Cui D A, Ou D R, Cheng M J. Int J Hydrogen Energy, 2013, 38: 15361
19. [19]
  [19] Finsterbusch M, Lussier A, Schaefer J A, Idzerda Y U. Solid State Ionics, 2012, 212: 77
20. [20]
  [20] Crumlin E J, Mutoro E, Liu Z, Grass M E, Biegalski M D, Lee Y L, Morgan D, Christen H M, Bluhm H, Yang S H. Energy Environ Sci, 2012, 5: 6081
21. [21]
  [21] Roy P K, Bera J. Mater Res Bull, 2005, 40: 599
22. [22]
  [22] Sirikanda N, Matsumoto H, Ishihara T. Solid State Ionics, 2010, 181: 315
23. [23]
  [23] Liu B, Muroyama H, Matsui T, Tomida K, Kabata T, Eguchi K. J Electrochem Soc, 2010, 157: B1858
24. [24]
  [2] Kournoutis V Ch, Tietz F, Bebelis S. Fuel Cells, 2009, 9: 852
1. [1]
  Shengjuan Huo , Xiaoyan Zhang , Xiangheng Li , Xiangning Li , Tianfang Chen , Yuting Shen . Unveiling the Marvels of Titanium: Popularizing Multifunctional Colored Titanium Product Films. University Chemistry, 2024, 39(5): 184-192. doi: 10.3866/PKU.DXHX202310127
2. [2]
  Ruiqing LIU , Wenxiu LIU , Kun XIE , Yiran LIU , Hui CHENG , Xiaoyu WANG , Chenxu TIAN , Xiujing LIN , Xiaomiao FENG . Three-dimensional porous titanium nitride as a highly efficient sulfur host. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 867-876. doi: 10.11862/CJIC.20230441
3. [3]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
4. [4]
  Jianan Hong , Chenyu Xu , Yan Liu , Changqi Li , Menglin Wang , Yanwei Zhang . Decoding the interfacial competition between hydrogen evolution and CO₂ reduction via edge-active-site modulation in photothermal catalysis. Acta Physico-Chimica Sinica, 2025, 41(9): 100099-0. doi: 10.1016/j.actphy.2025.100099
5. [5]
  Yan Kong , Wei Wei , Lekai Xu , Chen Chen . Electrochemical Synthesis of Organonitrogen Compounds from N-integrated CO₂ Reduction Reaction. Acta Physico-Chimica Sinica, 2024, 40(8): 2307049-0. doi: 10.3866/PKU.WHXB202307049
6. [6]
  Xiaofei Liu , He Wang , Li Tao , Weimin Ren , Xiaobing Lu , Wenzhen Zhang . Electrocarboxylation of Benzylic Phosphates and Phosphinates with Carbon Dioxide. Acta Physico-Chimica Sinica, 2024, 40(9): 2307008-0. doi: 10.3866/PKU.WHXB202307008
7. [7]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-Based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-0. doi: 10.3866/PKU.WHXB202406029
8. [8]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
9. [9]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
10. [10]
  Hui-Ying Chen , Hao-Lin Zhu , Pei-Qin Liao , Xiao-Ming Chen . Integration of Ru(Ⅱ)-Bipyridyl and Zinc(Ⅱ)-Porphyrin Moieties in a Metal-Organic Framework for Efficient Overall CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2306046-0. doi: 10.3866/PKU.WHXB202306046
11. [11]
  Huasen Lu , Shixu Song , Qisen Jia , Guangbo Liu , Luhua Jiang . Advances in Cu₂O-based Photocathodes for Photoelectrochemical Water Splitting. Acta Physico-Chimica Sinica, 2024, 40(2): 2304035-0. doi: 10.3866/PKU.WHXB202304035
12. [12]
  Yikai Wang , Xiaolin Jiang , Haoming Song , Nan Wei , Yifan Wang , Xinjun Xu , Cuihong Li , Hao Lu , Yahui Liu , Zhishan Bo . Thickness-Insensitive, Cyano-Modified Perylene Diimide Derivative as a Cathode Interlayer Material for High-Efficiency Organic Solar Cells. Acta Physico-Chimica Sinica, 2025, 41(3): 100027-0. doi: 10.3866/PKU.WHXB202406007
13. [13]
  Qiang Zhang , Yuanbiao Huang , Rong Cao . Imidazolium-Based Materials for CO₂ Electroreduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2306040-0. doi: 10.3866/PKU.WHXB202306040
14. [14]
  Yanhui Guo , Li Wei , Zhonglin Wen , Chaorong Qi , Huanfeng Jiang . Recent Progress on Conversion of Carbon Dioxide into Carbamates. Acta Physico-Chimica Sinica, 2024, 40(4): 2307004-0. doi: 10.3866/PKU.WHXB202307004
15. [15]
  Hailang JIA , Pengcheng JI , Hongcheng LI . Preparation and performance of nickel doped ruthenium dioxide electrocatalyst for oxygen evolution. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1632-1640. doi: 10.11862/CJIC.20240398
16. [16]
  Yuying JIANG , Jia LUO , Zhan GAO . Development status and prospects of solid oxide cell high entropy electrode catalysts. Chinese Journal of Inorganic Chemistry, 2025, 41(9): 1719-1730. doi: 10.11862/CJIC.20250124
17. [17]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
18. [18]
  Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260
19. [19]
  Ruifeng CHEN , Chao XU , Jianting JIANG , Tianshe YANG . Gold nanorod/zinc oxide/mesoporous silica nanoplatform: A triple-modal platform for synergistic anticancer therapy. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2272-2282. doi: 10.11862/CJIC.20250117
20. [20]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201

Get Citation

PDF

XML

Metrics

PDF Downloads(398)
Abstract views(710)
HTML views(22)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

TiO2-modified La0.6Sr0.4Co0.2Fe0.8O3-δ cathode for intermediate temperature solid oxide fuel cells

Metrics

通讯作者: 陈斌, bchen63@163.com

TiO₂-modified La_0.6Sr_0.4Co_0.2Fe_0.8O_3-δ cathode for intermediate temperature solid oxide fuel cells